US4788098A
Expired / Lapsed
US
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Aromatic polyimide laminate sheet
Assignee: Ube Corp
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Filing: 1986-12-15
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Granted: 1988-11-29
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Expires: 2006-12-15
Abstract
Abstract An aromatic polyimide laminate sheet having a relatively large thickness of 50 μm or more comprises (1) at least one first film layer comprising a polymerization-imidization product of an acid component containing 80 to 100 molar % of at least one biphenyltetracarboxylic acid with an amine component containing 80 to 100 molar % of at least one aromatic diamine having two or more benzene rings, and having a glass transition point of 250° C. to 350° C.; and (2) at least one second film layer comprising an aromatic imide polymer, the first and second film layers being alternately laminated on and directly bonded to each other without using bonding material.
Inventors
- 👤 Takahiko Sado
- 👤 Hiroaki Mori
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 12:58
CPC Classifications
B; B32; B32B; B32B27/00; B32B27/06; B32B27/08; B32B27/28; B32B27/281; B32B2307/00; B32B2307/30; B32B2307/306; B32B2379/00; B32B2379/08; Y; Y10; Y10T; Y10T428/00; Y10T428/24; Y10T428/24942; Y10T428/2495; Y10T428/24967; Y10T428/31504; Y10T428/31721
Claims Analysis
Total Claims: 15
Claim 1
Independent Claim
149 words
An aromatic polyimide laminate sheet having a thickness of 50 μm or more and comprising: (1) at least one first film layer comprising an aromatic imide polymer consisting essentially of a polymerization-imidization product of an aromatic tetracarboxylic acid component containing 80 to 100 molar % of a principal acid ingredient consisting of at least one biphenyltetracarboxylic acid compound with an aromatic diamine component containing 80 to 100 molar % of a principal diamine ingredient consisting of at least one aromatic diamine compound having two or more benzene rings, and having a glass transition temperature of from 250° C. to 350° C.; and (2) at least one second film layer comprising an aromatic imide polymer, the at least one first film layer and the at least one second film layer being alternately laminated on and directly heat-press-bonded to each other without in any way arranging a bonding material layer therebetween.
Claim 2
Dependent Claim
149 words
An aromatic polyimide laminate sheet having a thickness of 50 μm or more and comprising: (1) at least one first film layer comprising an aromatic imide polymer consisting essentially of a polymerization-imidization product of an aromatic tetracarboxylic acid component containing 80 to 100 molar % of a principal acid ingredient consisting of at least one biphenyltetracarboxylic acid compound with an aromatic diamine component containing 80 to 100 molar % of a principal diamine ingredient consisting of at least one aromatic diamine compound having two or more benzene rings, and having a glass transition temperature of from 250° C. to 350° C.; and (2) at least one second film layer comprising an aromatic imide polymer, the at least one first film layer and the at least one second film layer being alternately laminated on and directly heat-press-bonded to each other without in any way arranging a bonding material layer therebetween.
Claim 3
Dependent Claim
34 words
The laminate sheet as claimed in claim 1, wherein the biphenyltetracarboxylic acid compound is selected from the group consisting of 3,3',4,4'-biphenyltetracarboxylic acid, 2,3,3',4'-biphenyltetracarboxylic acid and dianhydrides and lower alkyl esters of the above-mentioned acids.
Claim 4
Dependent Claim
61 words
The laminate sheet as claimed in claim 1, wherein the aromatic tetracarboxylic acid component contains, in addition to the principal acid ingredient, 20 molar % or less of an additional ingredient consisting of at least one member selected from the group consisting of pyromellitic acid, benzophenone tetracarboxylic acids, 2,2-bis(3,4-dicarboxyphenyl)propane, bis(3,4-dicarboxyphenyl)methane, bis(3,4-dicarboxyphenyl)phosphine and dianhydrides and lower alkyl esters of the abovementioned acids.
Claim 5
Dependent Claim
34 words
The laminate sheet as claimed in claim 1, wherein the aromatic diamine compound having two or more benzene rings is selected from the group consisting of diaminodiphenylethers, dialkyl-diaminodiphenylethers, dialkoxydiaminodiphenylethers, diaminodiphenylthioethers, diaminobenzophenones, diaminodiphenylphosphines, and diaminodiphenylmethanes.
Claim 6
Dependent Claim
30 words
The laminate sheet as claimed in claim 1, wherein the principal diamine ingredient contains at least 60 molar % of at least one member selected from diaminodiphenylethers, dialkyl-diaminodiphenylethers and dialkoxydiaminodiphenylethers.
Claim 7
Dependent Claim
43 words
The laminate sheet as claimed in claim 1, wherein the aromatic diamine component contains, in addition to the principal diamine ingredient, 20 molar % or less of an additional diamine ingredient consisting of at least one aromatic diamine having a single benzene ring.
Claim 8
Dependent Claim
47 words
The laminate sheet as claimed in claim 1, wherein the aromatic imide polymer of the first film layer has a logarithmic viscosity number of 0.2 to 7.0, determined at a concentration of 0.5 g/100 m in a solvent consisting of p-chlorophenol at a temperature of 50° C.
Claim 9
Dependent Claim
21 words
The laminate sheet as claimed in claim 1, wherein the second film layer is the same as the first film layer.
Claim 10
Dependent Claim
28 words
The laminate sheet as claimed in claim 1, wherein the aromatic imide polymer of the second film layer is the same as that of the first film layer.
Claim 11
Dependent Claim
20 words
The laminate sheet as claimed in claim 1, wherein the second sheet layer is different from the first film layer.
Claim 12
Dependent Claim
27 words
The laminate sheet as claimed in claim 1, wherein the aromatic imide polymer of the second film layer is different from that of the first film layer.
Claim 13
Dependent Claim
28 words
The laminate sheet as claimed in claim 1, wherein the first and second film layers respectively have, independently from each other, a thickness of 10 to 200 μm.
Claim 14
Dependent Claim
17 words
The laminate sheet as claimed in claim 1, which has a thickness of 100 to 2000 μm.
Claim 15
Dependent Claim
63 words
The laminate sheet as claimed in claim 1, wherein the second film layer comprises an aromatic imide polymer consisting essentially of a polymerization-imidization product of an aromatic carboxylic acid component consisting of at least one member selected from aromatic biphenyltetracarboxylic acids and dianhydrides and lower alkyl esters of the above-mentioned acids, with an aromatic diamine component consisting of at least one aromatic diamine.
References Cited (Backward Citations)
US4543295A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1991-11-29 | 1992-05-30 | 1992-11-29 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1995-11-29 | 1996-05-30 | 1996-11-29 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1999-11-29 | 2000-05-30 | 2000-11-29 | $7700.00 | Window Closed / Lapsed |