US4786587A
Expired / Lapsed
US
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Silver halide photographic material comprising two kinds of monodisperse emulsions differing in mean grain size
Assignee: Fujifilm Holdings Corp
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Filing: 1987-10-26
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Granted: 1988-11-22
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Expires: 2007-10-26
Abstract
Abstract A silver halide photographic material comprising at least one negative type silver halide emulsion layer coated on a support, said emulsion comprising two kinds of monodisperse emulsions each having a means grain sizes of not more than 0.5 micron and, differing in mean grain size from each other at least by 0.1 micron, and said photographic material further comprising a hydrazine derivative in at least one photographic layer, whereby negative images of high density and very high contrast can be obtained with a high photographic speed and without black spots.
Inventors
- 👤 Ken-ichi Kuwabara
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-31 06:05
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/005; G03C1/06; G03C1/061; G03C1/015; G03C1/035; G03C2001/03564; G03C2001/0357; G03C2200/00; G03C2200/06; Y; Y10; Y10S; Y10S430/00; Y10S430/149
Claims Analysis
Total Claims: 21
Claim 1
Independent Claim
290 words
A silver halide photographic material comprising at least one negative type silver halide emulsion layer coated on a support, said emulsion comprising two kinds of monodisperse emulsions each having a mean grain size of not more than 0.5 micron and, differing in mean grain size from each other at least by 0.1 micron, and said photographic material further comprising a hydrazine derivative in at least one photographic layer, wherein one of said monodisperse emulsions has a mean grain size of not more than 0.3 micron and the other has a mean grain size of at least 0.3 micron, wherein the fraction of the finer-grained silver halide ranges from 40 to 90% by weight based on the weight of the total amount of silver halide in the monodisperse emulsions, wherein said hydrazine derivative is a compound selected from the group consisting of compounds represented by formulae (I) and (II): R.sub.1 --NHNH--G--R.sub.2 (I) wherein R 1 represents an aliphatic group, an aromatic group or a saturated heterocyclic group; R 2 represents a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted aralkyl group, a substituted or unsubstituted alkoxy group, or a substituted or unsubstituted aryloxy group; and G represents a carbonyl group, a sulfonyl group, a sulfoxy group, a phosphoryl group, or a N-substituted or unsubstituted iminomethylene group, and ##STR6## wherein; "Acyl" is an acyl group, "Ar" is an aryl group, R 1 represents a hydrogen atom and sulfinic acid radical substituent, and R 2 is chosen to be a sulfinic acid radical substituent when R 1 is a hydrogen atom and a hydrogen atom when R 1 is a sulfonic acid radical, wherein said hydrazine derivative is present in a contrast-enhancing amount.
Claim 2
Dependent Claim
290 words
A silver halide photographic material comprising at least one negative type silver halide emulsion layer coated on a support, said emulsion comprising two kinds of monodisperse emulsions each having a mean grain size of not more than 0.5 micron and, differing in mean grain size from each other at least by 0.1 micron, and said photographic material further comprising a hydrazine derivative in at least one photographic layer, wherein one of said monodisperse emulsions has a mean grain size of not more than 0.3 micron and the other has a mean grain size of at least 0.3 micron, wherein the fraction of the finer-grained silver halide ranges from 40 to 90% by weight based on the weight of the total amount of silver halide in the monodisperse emulsions, wherein said hydrazine derivative is a compound selected from the group consisting of compounds represented by formulae (I) and (II): R.sub.1 --NHNH--G--R.sub.2 (I) wherein R 1 represents an aliphatic group, an aromatic group or a saturated heterocyclic group; R 2 represents a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted aralkyl group, a substituted or unsubstituted alkoxy group, or a substituted or unsubstituted aryloxy group; and G represents a carbonyl group, a sulfonyl group, a sulfoxy group, a phosphoryl group, or a N-substituted or unsubstituted iminomethylene group, and ##STR6## wherein; "Acyl" is an acyl group, "Ar" is an aryl group, R 1 represents a hydrogen atom and sulfinic acid radical substituent, and R 2 is chosen to be a sulfinic acid radical substituent when R 1 is a hydrogen atom and a hydrogen atom when R 1 is a sulfonic acid radical, wherein said hydrazine derivative is present in a contrast-enhancing amount.
Claim 3
Dependent Claim
30 words
A silver halide photographic material as in claim 1, wherein said two kinds of monodisperse emulsions differ in mean grain size from each other by from 0.1 to 0.3 micron.
Claim 4
Dependent Claim
28 words
A silver halide photographic material as in claim 1, wherein the mean grain size of the monodisperse emulsion of finer-grained silver halide is not less than 0.1 micron.
Claim 5
Dependent Claim
48 words
A silver halide photographic material as in claim 1, wherein an emulsion other than the monodisperse emulsion is contained in said silver halide emulsion in an amount of not more than 10% by weight based on the weight of the total amount of silver halide in the emulsion.
Claim 6
Dependent Claim
28 words
A silver halide photographic material as in claim 1, wherein said hydrazine derivative is one which is able to increase speed and contrast of a silver halide emulsion.
Claim 7
Dependent Claim
29 words
A silver halide photographic material as in claim 1, wherein said photographic layer is selected from the group consisting of a silver halide emulsion layer and an auxiliary layer.
Claim 8
Dependent Claim
19 words
A silver halide photographic material as in claim 1, wherein said hydrazine derivative is incorporated in said emulsion layer.
Claim 9
Dependent Claim
24 words
A silver halide photographic material as in claim 1, wherein the hydrazine derivative is incorporated in an auxiliary layer adjacent to said emulsion layer.
Claim 10
Dependent Claim
41 words
A silver halide photographic material as in claim 1, wherein the hydrazine derivative is incorporated in at least one photographic layer in an amount of from 1×10 -6 to 5×10 -2 mole per mole of silver halide in the photographic material.
Claim 11
Dependent Claim
114 words
A silver halide photographic material as in claim 1, wherein R 1 represents a substituted or unsubstituted straight or branched chain or cyclic alkyl group having from 1 to 20 carbon atoms in alkyl moiety, a substituted or unsubstituted saturated 3 to 10 membered heterocyclic group containing at least one of O, N and S atoms in the heterocyclic ring, a substituted or unsubstituted mono- or bicyclic aryl group, a substituted of unsubstituted 5 to 6 membered unsaturated heterocyclic group having at least one O, N and S atoms in the heterocyclic ring, and a heteroaryl group formed by fusing said 5 to 6 membered heterocyclic group with a mono- or bicyclic aryl group.
Claim 12
Dependent Claim
46 words
A silver halide photographic material as in claim 1, wherein G is a carbonyl group and R 2 is a group selected from the group consisting of a hydrogen atom, a methyl group, a methoxy group, an ethoxy group and a substituted or unsubstituted penyl group.
Claim 13
Dependent Claim
40 words
A silver halide photographic material as in claim 1, wherein G is a sulfonyl group and R 2 is a group selected from the group consisting of a methyl group, an ethyl group, a phenyl group or a 4-methylphenyl group.
Claim 14
Dependent Claim
42 words
A silver halide photographic material as in claim 1, wherein G is a phosphoryl group and R 2 is a group selected from the group consisting of a methoxy group, ethoxy group, a butoxy group, a phenoxy group, and a phenyl group.
Claim 15
Dependent Claim
34 words
A silver halide photographic material as in claim 1, wherein G is a sulfoxy group and R 2 is a group selected from the group consisting of a cyanobenzyl group and a methylthiobenzyl group.
Claim 16
Dependent Claim
43 words
A silver halide photographic material as in claim 1, wherein G is a substituted or unsubstituted iminomethylene group and R 2 is a group selected from the group consisting of a methyl group, an ethyl group and a substituted or unsubstituted phenyl group.
Claim 17
Dependent Claim
91 words
A silver halide photographic material as in claim 1, wherein one of said monodisperse emulsions has a mean grain size of not less than 0.1 micron to not more than 0.3 micron and the other has a mean grain size of at least 0.3 micron, wherein the fraction of the monodispersed emulsion having a mean grain size of not less than 0.1 micron to not more than 0.3 micron ranges from 40 to 90% by weight based on the weight of the total amount of silver halide in the monodisperse emulsions.
Claim 18
Dependent Claim
124 words
A silver halide photographic material as in claim 1, wherein one of said monodisperse emulsions has a mean grain size of not less than 0.1 micron to not more than 0.3 micron and the other has a mean grain size of at least 0.3 micron, wherein the fraction of the monodispersed emulsion having a mean grain size of not less than 0.1 micron to not more than 0.3 micron ranges from 40 to 90% by weight based on the weight of the total amount of silver halide in the monodisperse emulsions, further wherein the hydrazine derivative is incorporated in at least one photographic layer in an amount of from 1×10 -6 to 5×10 -2 mol per mol of silver halide in the photographic material.
Claim 19
Dependent Claim
82 words
A silver halide photographic material as in claim 1, wherein said two kinds of monodisperse emulsions meet the following emulsion grain size and amount limitations where the larger grain size is represented by S1 and the finer grain size is represented by S2, where all percents by weight are based on the weight of the total amount of silver halide in the monodisperse emulsions: ______________________________________
0.4 μm < S1 ≦ 0.5 μm
10-30%
0.1 μm ≦ S2 ≦ 0.3 μm
90-70%.
______________________________________
Claim 20
Dependent Claim
78 words
A silver halide photographic material as in claim 1, wherein said two kinds of monodisperse emulsions meet the following emulsion grain size and amount limitations where the larger grain size is represented by S1 and the finer grain size is represented by S2, where all percents by weight are based on the weight of the total amount of silver halide in the monodisperse emulsions: ______________________________________
S1 < 0.4 μm 10-60%
S2 ≦ S1 - 0.1 μm
90-40%.
______________________________________
Claim 21
Dependent Claim
82 words
A silver halide photographic material as in claim 1, wherein said two kinds of monodisperse emulsions meet the following emulsion grain size and amount limitations where the larger grain size is represented by S1 and the finer grain size is represented by S2, where all percents by weight are based on the weight of the total amount of silver halide in the monodisperse emulsions: ______________________________________
0.3 μm ≦ S1 ≦ 0.4 μm
10-50%
0.1 μm ≦ S2 ≦ 0.3 μm
90-50%.
______________________________________
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1991-11-22 | 1992-05-23 | 1992-11-22 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1995-11-22 | 1996-05-23 | 1996-11-22 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1999-11-22 | 2000-05-23 | 2000-11-22 | $7700.00 | Window Closed / Lapsed |