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US4782101A Expired / Lapsed US ⏱️ 0.0 years remaining

Prevention of outgassing in polyvinylsiloxane elastomers by the use of finely divided platinum black

Assignee: Manufacturers Hanover Trust Co
•
Filing: 1987-03-25
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Granted: 1988-11-01
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Expires: 2007-03-25
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Abstract

Abstract A polyvinylsolixane catalyst paste which comprises up to 20,000 ppm of finely divided platinum black which functions to adsorb hydrogen gas generated in the reaction of said catalyst paste when mixed with a base paste containing hydrofunctional polydimethylsiloxane, said base paste further containing a hydrophilic surfactant.

Inventors

  • 👤 Duncan E. Waller
  • 👤 Laurie D. Lovshe

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 12:05
CPC Classifications
A; A61; A61K; A61K6/00; A61K6/90

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 80 words
A two component dental impression material which comprises the following: ______________________________________ CATALYST BASE PASTE WT % PASTE WT % ______________________________________ Vinyl Polydimethyl- 10-60 Vinyl Polydi- 10-60 siloxane methylsiloxane Hydropolydimethyl 1-10 Cyclic Vinyl 0-2 Siloxane Siloxane Silica Filler 20-80 Chloroplatinic 0.1-5.0 Acid Complex Liquid Petroleum 0-15 Platinum Black 0.2-20,000 ppm Plasticizer 0-15 Filler 20-80 ______________________________________ and wherein said platinum black has a surface area of about 24 M 2 /gram and a size range of about 18 to 28 Angstrom Units.
Claim 2
Dependent Claim 80 words
A two component dental impression material which comprises the following: ______________________________________ CATALYST BASE PASTE WT % PASTE WT % ______________________________________ Vinyl Polydimethyl- 10-60 Vinyl Polydi- 10-60 siloxane methylsiloxane Hydropolydimethyl 1-10 Cyclic Vinyl 0-2 Siloxane Siloxane Silica Filler 20-80 Chloroplatinic 0.1-5.0 Acid Complex Liquid Petroleum 0-15 Platinum Black 0.2-20,000 ppm Plasticizer 0-15 Filler 20-80 ______________________________________ and wherein said platinum black has a surface area of about 24 M 2 /gram and a size range of about 18 to 28 Angstrom Units.
Claim 3
Dependent Claim 23 words
The impression material of claim 1 in which the surfactant is selected from the family of polyol fatty acid esters and ethoxylated esters.
Claim 4
Dependent Claim 12 words
The impression material of claim 1 in which the surfactant comprises nonylphenoxypoly(ethyleneoxy)ethanol.
Claim 5
Dependent Claim 76 words
The impression material of claim 1 in which the surfactant comprises at least one compound selected from the group comprising: n-Dodecyl, Tetradecyl, Hexadecyl Alcohol Ethoxylate Polyethylene Glycol Monolaurate Polyethylene Glycol Dilaurate Polyethylene Glycol Monoleate Polyethylene Glycol Dioleate Polyethylene Glycol Monotallate Polyethylene Glycol Ditallate Sorbitan Monolaurate Sorbitan Monoleate Sorbitan Trioleate Sorbitan Monotallate Sorbitan Tritallate Polyethylene Glycol Glycerol Cocoeate Caprylic Triglyceride Polyoxyethylene Tridecyl Alcohol24938-91-8 Polyoxyethylene Lauryl Ether5274-68-0 Nonylphenoxypoly(ethyleneoxy)ethanol9016-45-9 Polyoxyethylene Sorbitan Monolaurate Sorbitan Monolaurate Polyoxyethylene Polysorbate Polyoxyethylene Oleyl Alcohol.
Claim 6
Dependent Claim 64 words
A cured dental impression which comprises the following composition: ______________________________________ WT % ______________________________________ Vinyl Polydimethylsiloxane 10-60 Cyclic Vinyl Siloxane 0-1 Hydropolydimethyl Siloxane 0.5-5.0 Filler 20-80 Chloroplatinic Acid Complex 0.05-2.5 Platinum Black 0.1-10,000 ppm Plasticizer 0-15 Surfactant 1-10 ______________________________________ and wherein said platinum black has a surface area of about 24 M 2 /gram and a size range of about 18 to 28 Angstrom Units.
Claim 7
Dependent Claim 64 words
A cured dental impression which comprises the following composition: ______________________________________ WT % ______________________________________ Vinyl Polydimethylsiloxane 10-60 Cyclic Vinyl Siloxane 0-1 Hydropolydimethyl Siloxane 0.5-5.0 Filler 20-80 Chloroplatinic Acid Complex 0.05-2.5 Platinum Black 0.1-10,000 ppm Plasticizer 0-15 Surfactant 1-10 ______________________________________ and wherein said platinum black has a surface area of about 24 M 2 /gram and a size range of about 18 to 28 Angstrom Units.
Claim 8
Dependent Claim 84 words
A polyvinylsiloxane catalyst paste which comprises up to 20,000 ppm of finely divided platinum black which functions to absorb hydrogen gas generated in the reaction of said catalyst paste when mixed with a base paste containing hydrofunctional polydimethylsiloxane, said base paste further containing a hydrophilic surfactant selected from the family of polyol fatty acid esters and ethoxylated esters and wherein said platinum black has a surface area of about 24 M 2 /gram and a size range of about 18 to 28 Angstrom Units.
Claim 9
Dependent Claim 84 words
A polyvinylsiloxane catalyst paste which comprises up to 20,000 ppm of finely divided platinum black which functions to absorb hydrogen gas generated in the reaction of said catalyst paste when mixed with a base paste containing hydrofunctional polydimethylsiloxane, said base paste further containing a hydrophilic surfactant selected from the family of polyol fatty acid esters and ethoxylated esters and wherein said platinum black has a surface area of about 24 M 2 /gram and a size range of about 18 to 28 Angstrom Units.
Claim 10
Dependent Claim 76 words
The composition of claim 6 in which the surfactant comprises at least one compound selected from the group consisting of: n-Dodecyl, Tetradecyl, Hexadecyl Alcohol Ethoxylate Polyethylene Glycol Monolaurate Polyethylene Glycol Dilaurate Polyethylene Glycol Monoleate Polyethylene Glycol Dioleate Polyethylene Glycol Monotallate Polyethylene Glycol Ditallate Sorbitan Monolaurate Sorbitan Monoleate Sorbitan Trioleate Sorbitan Monotallate Sorbitan Tritallate Polyethylene Glycol Glycerol Cocoeate Caprylic Triglyceride Polyoxyethylene Tridecyl Alcohol24938-91-8 Polyoxyethylene Lauryl Ether5274-68-0 Nonylphenoxypoly(ethyleneoxy)ethanol9016-45-9 Polyoxyethylene Sorbitan Monolaurate Sorbitan Monolaurate Polyoxyethylene Polysorbate Polyoxyethylene Oleyl Alcohol.

References Cited (Backward Citations)

US4020014A Cited
EP0046907A2 Cited
EP0117056A2 Cited
US4657959A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-11-01 1992-05-02 1992-11-01 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-11-01 1996-05-02 1996-11-01 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-11-01 2000-05-02 2000-11-01 $7700.00 Window Closed / Lapsed

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