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US4778866A Expired / Lapsed US ⏱️ 0.0 years remaining

Ethylene copolymer

Assignee: Mitsubishi Chemical Corp
•
Filing: 1986-07-07
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Granted: 1988-10-18
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Expires: 2006-07-07
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Abstract

Abstract An ethylene copolymer comprising an ethylene unit and an ester unit selected from ethylenically alpha , beta -unsaturated acid esters represented by the formula (I) or (II): <IMAGE> (I) wherein R1 represents a hydrogen atom or a methyl group; and R2 represents a halogenated alkyl group having from 1 to 15 carbon atoms; <IMAGE> (II) wherein R3 represents a hydrogen atom or a methyl group; and n represents 0 or 1, wherein said ester unit is present in a total amount of from 0.001 to 10 mol %. The copolymer has excellent dielectric breakdown characteristics, such as electricity treeing property, water treeing property, etc., and is useful as an insulating material for high-voltage cables.

Inventors

  • 👤 Takeo Shimada
  • 👤 Iwao Ishino
  • 👤 Noriyuki Okada
  • 👤 Tsutomu Isaka
  • 👤 Akiyoshi Oonishi
  • 👤 Masaki Saito
  • 👤 Shuhei Doi

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 10:20
CPC Classifications
C; C08; C08F; C08F255/00; C08F255/02; C08F210/00; C08F210/02

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 63 words
An ethylene copolymer for use as electrical insulation comprised of ethylene monomer and an ethylenically α,β-unsaturated ester monomer of the formula: ##STR5## wherein R 1 is hydrogen or methyl and R 2 is a fluorinated alkyl group having from 1 to 15 carbon atoms, said ester monomer unit being present in the copolymer in an amount of from 0.1 to 1.6% by weight.
Claim 2
Dependent Claim 63 words
An ethylene copolymer for use as electrical insulation comprised of ethylene monomer and an ethylenically α,β-unsaturated ester monomer of the formula: ##STR5## wherein R 1 is hydrogen or methyl and R 2 is a fluorinated alkyl group having from 1 to 15 carbon atoms, said ester monomer unit being present in the copolymer in an amount of from 0.1 to 1.6% by weight.
Claim 3
Dependent Claim 40 words
The ethylene copolymer of claim 1, wherein said copolymer has a density ranging from 0.88 to 1.00 g/cm 2 , a degree of crystallinity of from 25 to 70% and a number average molecular weight ranging from 1,000 to 100,000.
Claim 4
Dependent Claim 32 words
The ethylene copolymer of claim 1, wherein said copolymer further contains a monomer unit selected from the group consisting of vinyl esters, alkyl acrylic esters, alkyl methacrylic esters and ethylenically α,β-unsaturated acids.
Claim 5
Dependent Claim 24 words
The ethylene copolymer of claim 1, wherein said fluorinated alkyl group is trifluoroethyl, difluoromethyl, monofluoroethyl, monofluoromethyl, trifluoromethyl, tetrafluoroethyl, pentafluoroethyl, pentafluoropentadecanyl, heptafluorodecanyl, heptadecylfluorodecanyl or hexafluorononyl.

References Cited (Backward Citations)

FR1274761A Cited
US3162676A Cited
US3173893A Cited
US3384628A Cited
US3418301A Cited
US3520863A Cited
GB1168396A Cited
US4158097A Cited
US4310650A Cited
US4474982A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-10-18 1992-04-18 1992-10-18 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-10-18 1996-04-18 1996-10-18 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-10-18 2000-04-18 2000-10-18 $7700.00 Window Closed / Lapsed

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