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US4778619A Expired / Lapsed US ⏱️ 0.0 years remaining

Liquid crystal compositions

Assignee: Panasonic Holdings Corp
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Filing: 1986-03-21
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Granted: 1988-10-18
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Expires: 2006-03-21
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Abstract

Abstract Liquid crystal compositions comprising indigo dyes which have a benzene ring having a branched alkyl group introduced thereinto. The indigo dyes have improved solubilities in host liquid crystal materials and are suitable for guest-host liquid crystal display.

Inventors

  • 👤 Hirofumi Wakemoto
  • 👤 Shoichi Ishihara
  • 👤 Yoshihiro Matsuo

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 04:14
CPC Classifications
C; C09; C09K; C09K19/00; C09K19/52; C09K19/60; C09B; C09B23/00; C09B23/10; C09B23/102; C09B7/00

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 197 words
A liquid crystal composition comprising, in combination with a host liquid crystal material, at least one guest indigo dye of the following general formula ##STR24## in which A and B independently represent S or N-Y in which Y represents an alkyl group having from 1 to 3 carbon atoms, an acyl group having from 2 to 4 carbon atoms or a hydrogen atom, R 2 represents an alkyl group having from 4 to 10 carbon atoms and branched at the alpha carbon, R 6 represents a hydrogen atom, a branched or linear alkyl group, a 4-substituted phenyl group, a 4-substituted cyclohexyl group or a 4-substituted phenyloxy group, R 1 , R 3 , R 4 , R 5 , R 7 and R 8 independently represent a hydrogen atom, a halogen atom, an alkyl group having from 1 to 3 carbon atoms, an alkoxy group having from 1 to 3 carbon atoms, a nitro group, an amino group, or --NR 9 R 10 , in which R 9 represents an alkyl group having from 1 to 3 carbon atoms and R 10 represents a hydrogen atom or an alkyl group having from 1 to 3 carbon atoms.
Claim 2
Dependent Claim 197 words
A liquid crystal composition comprising, in combination with a host liquid crystal material, at least one guest indigo dye of the following general formula ##STR24## in which A and B independently represent S or N-Y in which Y represents an alkyl group having from 1 to 3 carbon atoms, an acyl group having from 2 to 4 carbon atoms or a hydrogen atom, R 2 represents an alkyl group having from 4 to 10 carbon atoms and branched at the alpha carbon, R 6 represents a hydrogen atom, a branched or linear alkyl group, a 4-substituted phenyl group, a 4-substituted cyclohexyl group or a 4-substituted phenyloxy group, R 1 , R 3 , R 4 , R 5 , R 7 and R 8 independently represent a hydrogen atom, a halogen atom, an alkyl group having from 1 to 3 carbon atoms, an alkoxy group having from 1 to 3 carbon atoms, a nitro group, an amino group, or --NR 9 R 10 , in which R 9 represents an alkyl group having from 1 to 3 carbon atoms and R 10 represents a hydrogen atom or an alkyl group having from 1 to 3 carbon atoms.
Claim 3
Dependent Claim 22 words
A liquid crystal composition according to claim 1, wherein at least one of A and B in the formula (I) is S.
Claim 4
Dependent Claim 15 words
A liquid crystal composition according to claim 2, wherein A and B are both S.
Claim 5
Dependent Claim 18 words
A liquid crystal composition according to claim 1, wherein said R 2 group is a tertiary alkyl group.
Claim 6
Dependent Claim 94 words
A liquid crystal composition according to claim 1, wherein R 1 , R 3 , R 4 , R 5 , R 7 and R 8 are independently hydrogen, an alkyl group having from 1 to 3 carbon atoms, an alkoxy group having from 1 to 3 carbon atoms, a nitro group, Cl, Br, an amino group, or a NR 9 R 10 in which R 9 is an alkyl group having from 1 to 3 carbon atoms and R 10 represents hydrogen or an alkyl group having from 1 to 3 carbon atoms.
Claim 7
Dependent Claim 19 words
A liquid crystal composition according to claim 1, wherein R 6 is the same substituent as R 2 .
Claim 8
Dependent Claim 28 words
A liquid crystal composition according to claim 1, wherein R 6 is a 4-substituted phenyl group or 4-substituted cyclohexyl group and R 2 is a tertiary alkyl group.
Claim 9
Dependent Claim 15 words
A liquid crystal composition according to claim 7, wherein A and B are both S.
Claim 10
Dependent Claim 46 words
A liquid crystal composition according to claim 1, wherein said host liquid crystal material comprises a member selected from the group consisting of cyclohexylcyclohexanes, phenylcyclohexanes, biphenyls, terphenyls, cyclohexylcyclohexanoates, aromatic esters, aromatic diesters, biphenylcyclohexylcarboxylates, biphenyl esters, aromatic thioesters, Schiff bases, pyrimidines, cyclohexyl methyl ethers and mixtures thereof.

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Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-10-18 1992-04-18 1992-10-18 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-10-18 1996-04-18 1996-10-18 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-10-18 2000-04-18 2000-10-18 $7700.00 Window Closed / Lapsed

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