US4778619A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Liquid crystal compositions
Assignee: Panasonic Holdings Corp
•
Filing: 1986-03-21
•
Granted: 1988-10-18
•
Expires: 2006-03-21
Abstract
Abstract Liquid crystal compositions comprising indigo dyes which have a benzene ring having a branched alkyl group introduced thereinto. The indigo dyes have improved solubilities in host liquid crystal materials and are suitable for guest-host liquid crystal display.
Inventors
- 👤 Hirofumi Wakemoto
- 👤 Shoichi Ishihara
- 👤 Yoshihiro Matsuo
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 04:14
CPC Classifications
C; C09; C09K; C09K19/00; C09K19/52; C09K19/60; C09B; C09B23/00; C09B23/10; C09B23/102; C09B7/00
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
197 words
A liquid crystal composition comprising, in combination with a host liquid crystal material, at least one guest indigo dye of the following general formula ##STR24## in which A and B independently represent S or N-Y in which Y represents an alkyl group having from 1 to 3 carbon atoms, an acyl group having from 2 to 4 carbon atoms or a hydrogen atom, R 2 represents an alkyl group having from 4 to 10 carbon atoms and branched at the alpha carbon, R 6 represents a hydrogen atom, a branched or linear alkyl group, a 4-substituted phenyl group, a 4-substituted cyclohexyl group or a 4-substituted phenyloxy group, R 1 , R 3 , R 4 , R 5 , R 7 and R 8 independently represent a hydrogen atom, a halogen atom, an alkyl group having from 1 to 3 carbon atoms, an alkoxy group having from 1 to 3 carbon atoms, a nitro group, an amino group, or --NR 9 R 10 , in which R 9 represents an alkyl group having from 1 to 3 carbon atoms and R 10 represents a hydrogen atom or an alkyl group having from 1 to 3 carbon atoms.
Claim 2
Dependent Claim
197 words
A liquid crystal composition comprising, in combination with a host liquid crystal material, at least one guest indigo dye of the following general formula ##STR24## in which A and B independently represent S or N-Y in which Y represents an alkyl group having from 1 to 3 carbon atoms, an acyl group having from 2 to 4 carbon atoms or a hydrogen atom, R 2 represents an alkyl group having from 4 to 10 carbon atoms and branched at the alpha carbon, R 6 represents a hydrogen atom, a branched or linear alkyl group, a 4-substituted phenyl group, a 4-substituted cyclohexyl group or a 4-substituted phenyloxy group, R 1 , R 3 , R 4 , R 5 , R 7 and R 8 independently represent a hydrogen atom, a halogen atom, an alkyl group having from 1 to 3 carbon atoms, an alkoxy group having from 1 to 3 carbon atoms, a nitro group, an amino group, or --NR 9 R 10 , in which R 9 represents an alkyl group having from 1 to 3 carbon atoms and R 10 represents a hydrogen atom or an alkyl group having from 1 to 3 carbon atoms.
Claim 3
Dependent Claim
22 words
A liquid crystal composition according to claim 1, wherein at least one of A and B in the formula (I) is S.
Claim 4
Dependent Claim
15 words
A liquid crystal composition according to claim 2, wherein A and B are both S.
Claim 5
Dependent Claim
18 words
A liquid crystal composition according to claim 1, wherein said R 2 group is a tertiary alkyl group.
Claim 6
Dependent Claim
94 words
A liquid crystal composition according to claim 1, wherein R 1 , R 3 , R 4 , R 5 , R 7 and R 8 are independently hydrogen, an alkyl group having from 1 to 3 carbon atoms, an alkoxy group having from 1 to 3 carbon atoms, a nitro group, Cl, Br, an amino group, or a NR 9 R 10 in which R 9 is an alkyl group having from 1 to 3 carbon atoms and R 10 represents hydrogen or an alkyl group having from 1 to 3 carbon atoms.
Claim 7
Dependent Claim
19 words
A liquid crystal composition according to claim 1, wherein R 6 is the same substituent as R 2 .
Claim 8
Dependent Claim
28 words
A liquid crystal composition according to claim 1, wherein R 6 is a 4-substituted phenyl group or 4-substituted cyclohexyl group and R 2 is a tertiary alkyl group.
Claim 9
Dependent Claim
15 words
A liquid crystal composition according to claim 7, wherein A and B are both S.
Claim 10
Dependent Claim
46 words
A liquid crystal composition according to claim 1, wherein said host liquid crystal material comprises a member selected from the group consisting of cyclohexylcyclohexanes, phenylcyclohexanes, biphenyls, terphenyls, cyclohexylcyclohexanoates, aromatic esters, aromatic diesters, biphenylcyclohexylcarboxylates, biphenyl esters, aromatic thioesters, Schiff bases, pyrimidines, cyclohexyl methyl ethers and mixtures thereof.
References Cited (Backward Citations)
FR1282232A
Cited
US3597044A
Cited
US4145114A
Cited
FR2336450A1
Cited
US4151170A
Cited
GB1554192A
Cited
FR2370242A1
Cited
US4394070A
Cited
EP0076633A1
Cited
US4588517A
Cited
DE3300587A1
Cited
JPS59182878A
Cited
JPS59182877A
Cited
JPS61162580A
Cited
JPS61162581A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1991-10-18 | 1992-04-18 | 1992-10-18 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1995-10-18 | 1996-04-18 | 1996-10-18 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1999-10-18 | 2000-04-18 | 2000-10-18 | $7700.00 | Window Closed / Lapsed |