Abstract A process for producing a bisphenol compound useful as deterioration preventor capable of stabilizing organic substances against the decompositions caused by heat, light and oxygen, represented by the following general formula: <IMAGE> wherein R1 represents alkyl group having 1 to 3 carbon atoms, alkenyl group having 2 to 4 carbon atoms, phenyl group or 2-phenylethenyl group; R2 represents alkyl group having 1 to 5 carbon atoms, or cyclohexyl group; R3 represents alkyl group having 1 to 9 carbon atoms, cyclohexyl group or phenyl group; and R4 represents alkyl group having 1 to 11 carbon atoms or phenyl group, which comprises reacting a carboxylic acid represented by the following general formula: <IMAGE> wherein R1 is as defined above, with a bisphenol compound represented by the following general formula: <IMAGE> wherein R2, R3 and R4 are as defined above, by the use of a halogenating agent in the presence of a dehydrohalogenating agent, as well as butadiene polymer compositions containing said bisphenol compounds.
A butadiene polymer composition containing a bisphenol compound represented by the following formula: ##STR28## wherein R 5 represents alkyl group having 1 to 4 carbon atoms; R 6 represents --C(CH 3 ) 2 --R' (R' is alkyl group having 1 to 5 carbon atoms or phenyl group) or phenyl group; and R 7 represents acrylate residue or methacrylate residue, in an amount of 0.05 to 2 parts by weight per 100 parts by weight of butadiene polymer.
Claim 2
Dependent Claim
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A butadiene polymer composition containing a bisphenol compound represented by the following formula: ##STR28## wherein R 5 represents alkyl group having 1 to 4 carbon atoms; R 6 represents --C(CH 3 ) 2 --R' (R' is alkyl group having 1 to 5 carbon atoms or phenyl group) or phenyl group; and R 7 represents acrylate residue or methacrylate residue, in an amount of 0.05 to 2 parts by weight per 100 parts by weight of butadiene polymer.
Claim 3
Dependent Claim
17 words
A butadiene polymer composition according to claim 1, wherein R 5 in the formula is methyl group.
Claim 4
Dependent Claim
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A butadiene polymer composition according to claim 1, wherein R 6 in the formula is t-butyl group, t-amyl group, t-octyl group or phenyl group.
Claim 5
Dependent Claim
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A butadiene polymer composition according to claim 1, wherein said butadiene polymer is a solution-polymerized butadiene rubber, a solution-polymerized styrene-butadiene copolymer rubber or a styrene-butadiene block copolymer.
Claim 6
Dependent Claim
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A butadiene polymer composition according to claim 1, wherein the content of said bisphenol compound is 0.1 to 1 part by weight per 100 parts by weight of butadiene polymer.
Claim 7
Dependent Claim
24 words
A butadiene polymer composition according to claim 2, wherein R 6 in the formula is t-butyl group, t-amyl group, t-octyl group or phenyl group.