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US4774160A Expired / Lapsed US ⏱️ 0.0 years remaining

Toner compositions with amorphous ternary copolycarbonates

Assignee: Xerox Corp
•
Filing: 1987-02-24
•
Granted: 1988-09-27
•
Expires: 2007-02-24
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Abstract

Abstract Disclosed is an improved toner composition comprised of pigment particles and amorphous ternary copolycarbonate resin particles of the formula ##STR1## wherein R is an aliphatic hydrocarbon, n is a number of from about 4 to about 8, x is a number of from about 0.8 to about 0.95, y is a number of from about 0.05 to about 2, z represents the degree of polymerization, Ar 1 is an aromatic substituent, and Ar 2 is an aromatic substituent.

Inventors

  • 👤 Hadi-Khan Mahabadi
  • 👤 Lupu Alexandru

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 11:15
CPC Classifications
G; G03; G03G; G03G9/00; G03G9/08; G03G9/087; G03G9/08742; G03G9/08757; C; C08; C08G; C08G64/00; C08G64/16; C08G64/1608

Claims Analysis

Total Claims: 36
Claim 1
Independent Claim 65 words
An improved toner composition comprised of pigment particles and amorphous ternary copolycarbonate resin particles of the formula ##STR7## wherein R is an aliphatic hydrocarbon, x is a number of from about 0.8 to about 0.95, y is a number of from about 0.05 to about 2, z represents the degree of polymerization, Ar 1 is an aromatic substituent, and Ar 2 is an aromatic substituent.
Claim 2
Dependent Claim 65 words
An improved toner composition comprised of pigment particles and amorphous ternary copolycarbonate resin particles of the formula ##STR7## wherein R is an aliphatic hydrocarbon, x is a number of from about 0.8 to about 0.95, y is a number of from about 0.05 to about 2, z represents the degree of polymerization, Ar 1 is an aromatic substituent, and Ar 2 is an aromatic substituent.
Claim 3
Dependent Claim 23 words
A toner composition in accordance with claim 1 wherein R is an aliphatic hydrocarbon with from about 1 to about 25 carbon atoms.
Claim 4
Dependent Claim 33 words
A toner composition in accordance with claim 1 wherein R is an aliphatic hydrocarbon of the formula (CH 2 ) n wherein n is a number of from about 4 to about 8.
Claim 5
Dependent Claim 20 words
A toner composition in accordance with claim 1 wherein R is (CH 2 ) 2 --O--(CH 2 ) 2 .
Claim 6
Dependent Claim 19 words
A toner composition in accordance with claim 1 wherein Ar 1 is selected from the group consisting of ##STR8##
Claim 7
Dependent Claim 19 words
A toner composition in accordance with claim 1 wherein Ar 2 is selected from the group consisting of ##STR9##
Claim 8
Dependent Claim 26 words
A toner composition in accordance with claim 1 wherein the ternary copolycarbonate has a single thermal transition of from about 50° C. to about 55° C.
Claim 9
Dependent Claim 25 words
A toner composition in accordance with claim 1 wherein the ternary copolycarbonate results from the condensation reaction of p, p'-biphenol, bisphenol A and aliphatic bischloroformates.
Claim 10
Dependent Claim 25 words
A toner composition in accordance with claim 1 wherein the number average molecular weight of the ternary copolycarbonate is from about 1,200 to about 3,500.
Claim 11
Dependent Claim 15 words
A toner composition in accordance with claim 1 wherein the pigment particles are carbon black.
Claim 12
Dependent Claim 14 words
A toner composition in accordance with claim 1 wherein the pigment particles are magnetite.
Claim 13
Dependent Claim 15 words
A toner composition in accordance with claim 1 further including therein charge enhancing additive components.
Claim 14
Dependent Claim 30 words
A toner composition in accordance with claim 12 wherein the charge enhancing component is an alkyl pyridinium halide, an organic sulfate, an organic sulfonate, or distearyl dimethyl ammonium methyl sulfate.
Claim 15
Dependent Claim 28 words
A toner composition in accordance with claim 8 wherein the amorphous ternary copolycarbonate has a single thermal transition temperature of from about 50° C. to about 55° C.
Claim 16
Dependent Claim 14 words
A developer composition comprised of the toner composition of claim 1, and carrier components.
Claim 17
Dependent Claim 21 words
A developer composition in accordance with claim 15 wherein the carrier particles are comprised of a core with a coating thereover.
Claim 18
Dependent Claim 21 words
A developer composition in accordance with claim 16 wherein the core is selected from the group consisting of steel and ferrite.
Claim 19
Dependent Claim 15 words
A developer composition in accordance with claim 15 wherein the coating is a polymeric composition.
Claim 20
Dependent Claim 27 words
A developer composition in accordance with claim 15 wherein the ternary copolycarbonate has a single thermal transition temperature of from about 50° C. to about 55° C.
Claim 21
Dependent Claim 28 words
A developer composition in accordance with claim 16 wherein the amorphous ternary copolycarbonate has a single thermal transition temperature of from about 50° C. to about 55° C.
Claim 22
Dependent Claim 47 words
A method for affecting development of electrostatic latent images which comprises the generation of a latent image on a photoresponsive imaging member, subsequently developing this image with the toner composition of claim 1, thereafter transferring the image to a suitable substrate, and permanently affixing the image thereto.
Claim 23
Dependent Claim 21 words
A method of imaging in accordance with claim 21 wherein there is selected for fixing the image a flash fusing process.
Claim 24
Dependent Claim 20 words
A method of imaging in accordance with claim 22 wherein subsequent to flash fusing no effluent or odor is detected.
Claim 25
Dependent Claim 56 words
An amorphous ternary copolycarbonate resin of the formula ##STR10## wherein R is an aliphatic hydrocarbon, x is a number of from about 0.8 to about 0.95, y is a number of from about 0.05 to about 2, z represents the degree of polymerization, Ar 1 is an aromatic substituent, and Ar 2 is an aromatic substituent.
Claim 26
Dependent Claim 56 words
An amorphous ternary copolycarbonate resin of the formula ##STR10## wherein R is an aliphatic hydrocarbon, x is a number of from about 0.8 to about 0.95, y is a number of from about 0.05 to about 2, z represents the degree of polymerization, Ar 1 is an aromatic substituent, and Ar 2 is an aromatic substituent.
Claim 27
Dependent Claim 23 words
A copolycarbonate resin in accordance with claim 24 wherein R is a aliphatic hydrocarbon with from about 1 to about 25 carbon atoms.
Claim 28
Dependent Claim 33 words
A copolycarbonate resin in accordance with claim 24 wherein R is an aliphatic hydrocarbon of the formula (CH 2 ) n wherein n is a number of from about 4 to about 8.
Claim 29
Dependent Claim 20 words
A copolycarbonate resin in accordance with claim 24 wherein R is (CH 2 ) 2 --O--(CH 2 ) 2 .
Claim 30
Dependent Claim 19 words
A copolycarbonate resin in accordance with claim 24 wherein Ar 1 is selected from the group consisting of ##STR11##
Claim 31
Dependent Claim 19 words
A copolycarbonate resin in accordance with claim 24 wherein Ar 2 is selected from the group consisting of ##STR12##
Claim 32
Dependent Claim 26 words
A copolycarbonate resin in accordance with claim 24 wherein the ternary copolycarbonate has a single thermal transition of from about 50° C. to about 55° C.
Claim 33
Dependent Claim 24 words
A copolycarbonate resin in accordance with claim 24 wherein the ternary copolycarbonate results from the condensation reaction of p,p'-biphenol, bisphenol A and aliphatic bischloroformates.
Claim 34
Dependent Claim 25 words
A copolycarbonate resin in accordance with claim 24 wherein the number average molecular weight of the ternary copolycarbonate is from about 1,200 to about 3,500.
Claim 35
Dependent Claim 20 words
A toner composition in accordance with claim 1 wherein z is a number of from about 2 to about 30.
Claim 36
Dependent Claim 21 words
A ternary copolycarbonate resin in accordance with claim 24 wherein z is a number of from about 2 to about 30.

References Cited (Backward Citations)

US3694359A Cited
US3879347A Cited
US4196276A Cited
US4318974A Cited
US4457998A Cited
US4543313A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-09-27 1992-03-28 1992-09-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-09-27 1996-03-28 1996-09-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-09-27 2000-03-28 2000-09-27 $7700.00 Window Closed / Lapsed

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