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US4774075A Expired / Lapsed US ⏱️ 0.0 years remaining

Compositions containing bis-(quaternary ammonium) derivatives for the treatment of keratin materials and natural non-keratin materials or synthetic textile materials

Assignee: L'Oréal SA
•
Filing: 1985-07-02
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Granted: 1988-09-27
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Expires: 2005-07-02
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Abstract

Abstract The composition of the invention comprises, in a medium suitable for the treatment of keratin materials, and natural non-keratin or synthetic textile materials, at least one bis-(quaternary ammonium) derivatives having the formula: <IMAGE> (I) in which R1, R2, R4 and R5 are identical or different and denote lower alkyl or lower hydroxyalkyl radicals, R3 is an alkyl, cycloalkyl, alkenyl, hydroxyalkyl or optionally substituted aralkyl radical containing a maximum of 20 carbon atoms, A1 and A2, which are identical or different, represent optionally substituted alkylene or arylene radicals which can contain up to 20 carbon atoms, Z=-SO2- or -CO-p, in which p=1 or 2, R6 and R7, which are identical or different, are hydrogen atoms or lower alkyl radicals, or alternatively , if Z=-CO-p in which p=1, R6 and R7 can together form a group: <IMAGE> R8 and R9 being hydrogen atoms or lower alkyl radicals, and X(-) denotes an inorganic or organic anion derived from low molecular weight acids.

Inventors

  • 👤 Gerard Lang
  • 👤 Serge Forestier

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 11:15
CPC Classifications
A; A61; A61Q; A61Q5/00; A61Q5/12; A61K; A61K8/00; A61K8/18; A61K8/30; A61K8/40; A61K8/41; A61K8/416; A61Q5/02; C; C07; C07C; C07C275/00; C07C275/04; C07C275/06; C07C275/14; C07D; C07D273/00; C07D273/02; C07D273/04; D; D06; D06M; D06M13/00; D06M13/322; D06M13/46; D06M13/467; A61Q5/04; A61Q5/06; A61Q5/08; A61Q5/10; Y; Y10; Y10S; Y10S424/00; Y10S424/01; Y10S424/04

Claims Analysis

Total Claims: 25
Claim 1
Independent Claim 231 words
A composition suitable for treating hair, skin and nails which comprises at least one bis-(quaternary ammonium) derivative having the formula: ##STR24## in which R 1 , R 2 , R 4 and R 5 are indentical or different and denote lower alkyl or lower hydroxylalkyl radicals, R 3 denotes an alkyl, cycloalkyl, alkenyl, hydroxylalkyl or aralkyl radical containing a maximum of 20 carbon atoms, A 1 and A 2 , which are identical or different, denote alkylene or arylene radicals containing a maximum of 20 carbon atoms, Z denotes --CO-- p , in which p=1 or 2, R 6 and R 7 , which are identical or different, represent hydrogen atoms or lower alkyl radicals, or alternatively, if Z=--CO-- p in which p=1, R 6 and R 7 can together form a group: ##STR25## R 8 and R 9 being hydrogen atoms or lower alkyl radicals, and X.sup.⊖ denotes an inorganic or organic anion of a low molecular weight acid, and at least one cosmetic adjuvant selected from non-ionic, anionic, catioinic or amphoteric surface-active agents, animal, mineral, vegetable or synthetic oils or waxes, fatty alcohols, anionic, cationic, non-ionic or amphoteric resins, emulsifiers, organic solvents, thickeners, opacifiers, preservatives, perfumes, agents for imparting pearlescence, sequestering agents, antioxidants, pH modifiers, or electrolytes, and hair restructuring agents said bis-(quaternary ammonium) derivative being present in an amount of 0.01 to 10% by weight of said composition.
Claim 2
Dependent Claim 231 words
A composition suitable for treating hair, skin and nails which comprises at least one bis-(quaternary ammonium) derivative having the formula: ##STR24## in which R 1 , R 2 , R 4 and R 5 are indentical or different and denote lower alkyl or lower hydroxylalkyl radicals, R 3 denotes an alkyl, cycloalkyl, alkenyl, hydroxylalkyl or aralkyl radical containing a maximum of 20 carbon atoms, A 1 and A 2 , which are identical or different, denote alkylene or arylene radicals containing a maximum of 20 carbon atoms, Z denotes --CO-- p , in which p=1 or 2, R 6 and R 7 , which are identical or different, represent hydrogen atoms or lower alkyl radicals, or alternatively, if Z=--CO-- p in which p=1, R 6 and R 7 can together form a group: ##STR25## R 8 and R 9 being hydrogen atoms or lower alkyl radicals, and X.sup.⊖ denotes an inorganic or organic anion of a low molecular weight acid, and at least one cosmetic adjuvant selected from non-ionic, anionic, catioinic or amphoteric surface-active agents, animal, mineral, vegetable or synthetic oils or waxes, fatty alcohols, anionic, cationic, non-ionic or amphoteric resins, emulsifiers, organic solvents, thickeners, opacifiers, preservatives, perfumes, agents for imparting pearlescence, sequestering agents, antioxidants, pH modifiers, or electrolytes, and hair restructuring agents said bis-(quaternary ammonium) derivative being present in an amount of 0.01 to 10% by weight of said composition.
Claim 3
Dependent Claim 25 words
A composition according to claim 1, in which R 1 , R 2 , R 4 and R 5 denote a methyl or ethyl radical.
Claim 4
Dependent Claim 19 words
A composition according to claim 1 in which R 3 denotes a C 8 to C 18 alkyl radical.
Claim 5
Dependent Claim 19 words
A composition according to claim 1 in which A 1 and A 2 denote an ethylene or trimethylene radical.
Claim 6
Dependent Claim 46 words
A composition according to claim 1 for use in the treatment of the hair which is in a form selected from the group consisting of an aqueous, alcoholic or aqueous-alcoholic solution, a cream, a gel, an emulsion, a powder and a product packaged in an aerosol.
Claim 7
Dependent Claim 18 words
A composition according to claim 1 which contains 0.1 to 5% by weight of compound of formula (I).
Claim 8
Dependent Claim 239 words
A shampoo composition which facilitates the combing out of the hair when wet or dry and which imparts hold, softeness, shine, suppleness, manageability and antistatic properties to the hair when dry, said composition comprising, in an aqueous medium, at least one bis-(quaternary ammonium) derivative having the formula: ##STR26## in which R 1 , R 2 , R 4 and R 5 are identical or different and denote lower alkyl or lower hydroxyalkyl radicals, R 3 denotes an alkyl, cycloalkyl, alkenyl, hydroxyalkyl or aralkyl radical containing a maximum of 20 carbon atoms, A 1 and A 2 , which are identical or different, denote alkylene or arylene radicals containing a maximum of 20 carbon atoms, Z denotes --CO-- p , in which p=1 or 2, R 6 and R 7 , which are identical or different, represent hydrogen atoms or lower alkyl radicals, or alternatively, if Z=--CO-- p in which p=1, R 6 and R 7 can together form a group: ##STR27## R 8 and R 9 being hydrogen atoms or lower alkyl radicals, and X.sup.⊖ denotes an inorganic or organic anion of a low molecular weight acid, said bis-(quaternary ammonium) derivative being present in an amount of 0.01 to 10% by weight of said composition; and at least one anionic, non-ionic or amphoteric surface active agent or a mixture thereof, said surface-active agent being present in an amount ranging from 2 to 50% by weight of said shampoo composition.
Claim 9
Dependent Claim 239 words
A shampoo composition which facilitates the combing out of the hair when wet or dry and which imparts hold, softeness, shine, suppleness, manageability and antistatic properties to the hair when dry, said composition comprising, in an aqueous medium, at least one bis-(quaternary ammonium) derivative having the formula: ##STR26## in which R 1 , R 2 , R 4 and R 5 are identical or different and denote lower alkyl or lower hydroxyalkyl radicals, R 3 denotes an alkyl, cycloalkyl, alkenyl, hydroxyalkyl or aralkyl radical containing a maximum of 20 carbon atoms, A 1 and A 2 , which are identical or different, denote alkylene or arylene radicals containing a maximum of 20 carbon atoms, Z denotes --CO-- p , in which p=1 or 2, R 6 and R 7 , which are identical or different, represent hydrogen atoms or lower alkyl radicals, or alternatively, if Z=--CO-- p in which p=1, R 6 and R 7 can together form a group: ##STR27## R 8 and R 9 being hydrogen atoms or lower alkyl radicals, and X.sup.⊖ denotes an inorganic or organic anion of a low molecular weight acid, said bis-(quaternary ammonium) derivative being present in an amount of 0.01 to 10% by weight of said composition; and at least one anionic, non-ionic or amphoteric surface active agent or a mixture thereof, said surface-active agent being present in an amount ranging from 2 to 50% by weight of said shampoo composition.
Claim 10
Dependent Claim 13 words
A composition according ot claim 7 which also contains a cationic surface-active agent.
Claim 11
Dependent Claim 25 words
A composition according to claim 7, in which R 1 , R 2 , R 4 and R 5 denote a methyl or ethyl radical.
Claim 12
Dependent Claim 19 words
A composition according to claim 7 in which R 3 denotes a C 8 to C 18 alkyl radical.
Claim 13
Dependent Claim 19 words
A composition according to claim 7 in which A 1 and A 2 denote an ethylene or trimethylene radical.
Claim 14
Dependent Claim 15 words
A composition according to claim 5 which is in the form of an aqueous solution.
Claim 15
Dependent Claim 14 words
A composition according to claim 1 wherein Z=--CO-- p in which p=1 or 2.
Claim 16
Dependent Claim 14 words
A composition according to claim 13 in which Z is (CO) p and p=1.
Claim 17
Dependent Claim 226 words
A rinsing composition which facilitates the combing out of the hair when wet or dry and imparts hold, softness, shine, suppleness, manageability and antistatic properties to the hair when dry, which comprises, in an aqueous, alcoholic, or aqueous-alcoholic medium, at least one bis-(quaternary) ammonium) derivative having the formula: ##STR28## in which R 1 , R 2 , R 4 and R 5 are identical or different and denote lower alkyl or lower hydroxyalkyl radicals, R 3 denotes an alkyl, cycloalkyl, alkenyl, hydroxyalkyl or aralkyl radical containing a maximum of 20 carbon atoms, A 1 and A 2 , which are identical or different, denote alkylene or arylene radicals containing a maximum of 20 carbon atoms, Z denotes --CO-- p , in which p=1 or 2, R 6 and R 7 , which are identical or different, represent hydrogen atoms or lower alkyl radicals, or alternatively, if Z=--CO-- p in which p=1, R 6 and R 7 can together form a group: ##STR29## R 8 and R 9 being hydrogen atoms or lower alkyl radicals, and X.sup.⊖ denotes an inorganic or organic anion of a low molecular weight acid, said bis-(quaternary ammonium) derivative being present in amount of 0.01 to 10% by weight of said composition and said composition being in the form of a lotion, cream or gel having a pH ranging from 2 to 11.
Claim 18
Dependent Claim 226 words
A rinsing composition which facilitates the combing out of the hair when wet or dry and imparts hold, softness, shine, suppleness, manageability and antistatic properties to the hair when dry, which comprises, in an aqueous, alcoholic, or aqueous-alcoholic medium, at least one bis-(quaternary) ammonium) derivative having the formula: ##STR28## in which R 1 , R 2 , R 4 and R 5 are identical or different and denote lower alkyl or lower hydroxyalkyl radicals, R 3 denotes an alkyl, cycloalkyl, alkenyl, hydroxyalkyl or aralkyl radical containing a maximum of 20 carbon atoms, A 1 and A 2 , which are identical or different, denote alkylene or arylene radicals containing a maximum of 20 carbon atoms, Z denotes --CO-- p , in which p=1 or 2, R 6 and R 7 , which are identical or different, represent hydrogen atoms or lower alkyl radicals, or alternatively, if Z=--CO-- p in which p=1, R 6 and R 7 can together form a group: ##STR29## R 8 and R 9 being hydrogen atoms or lower alkyl radicals, and X.sup.⊖ denotes an inorganic or organic anion of a low molecular weight acid, said bis-(quaternary ammonium) derivative being present in amount of 0.01 to 10% by weight of said composition and said composition being in the form of a lotion, cream or gel having a pH ranging from 2 to 11.
Claim 19
Dependent Claim 18 words
A composition according to claim 15 which further contains an animal, mineral, vegetable or synthetic oil or wax.
Claim 20
Dependent Claim 16 words
A composition according to claim 15 which further contains an anionic, cationic, non-ionic or amphoteric resin.
Claim 21
Dependent Claim 12 words
A composition according to claim 15 which further contains a fatty alcohol.
Claim 22
Dependent Claim 14 words
A composition according to claim 15 which further contains a polyethyleneglycol or derivative thereof.
Claim 23
Dependent Claim 17 words
A composition according to claim 15 which further contains an effective amount of a hair restructuring agent.
Claim 24
Dependent Claim 18 words
Process for treating hair, skin or nails which comprises applying thereto a composition as defined in claim 1.
Claim 25
Dependent Claim 32 words
A process according to claim 21 which further comprises allowing said composition to remain on said hair, skin or nails for 1 to 30 minutes and rinsing said hair, skin or nails.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-09-27 1992-03-28 1992-09-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-09-27 1996-03-28 1996-09-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-09-27 2000-03-28 2000-09-27 $7700.00 Window Closed / Lapsed

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