US4772404A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Concentrated liquid fabric softener with whiteners
Assignee: Lever Brothers Co
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Filing: 1986-12-24
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Granted: 1988-09-20
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Expires: 2006-12-24
Abstract
Abstract A concentrated fabric softener having a dual cationic high active system, a sufficient level of fluorescent dye to whiten cotton garments, and a non-ionizing base. The dual active system is included at levels of greater than about 10% and preferably comprises a difatty amido ammonium methyl sulfate and a ditallow dimethyl ammonium chloride in a ratio of at least 1.5:1. Use of the concentrated softener results in reduced container size and greater manufacturing efficiencies. Inclusion of fluorescent dye restores whiteness/brightness to cotton garments yellowed by age.
Inventors
- 👤 Daniel J. Fox
- 👤 Mary E. Sullivan
- 👤 Anthony J. Cuomo
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 01:28
CPC Classifications
C; C11; C11D; C11D3/00; C11D3/40; C11D3/42; C11D1/00; C11D1/38; C11D1/645; C11D3/0005; C11D3/001; C11D3/0015
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
225 words
A liquid fabric softener comprising: (a) from about 10 to about 20 percent by weight of a quaternary active system including a first cationic surfactant having the formula ##STR8## wherein R 1 and R 2 are the same or different and are selected from the group consisting of C 8 to C 22 alkyl and alkenyl groups and R 3 is selected from the group consisting of H, methyl, ethyl and (C n H 2n O) x H wherein n is 2 or 3 and x is from 1 to about 5 and wherein X - is an anion, and a second cationic surfactant of the formula ##STR9## wherein R 4 and R 5 are the same or different and are selected from the group consisting of C 8 to C 22 alkyl and alkenyl and R 6 and R 7 are alkyl groups of from 1 to 3 carbon atoms and X is an anion, in a ratio of first to second surfactants of from at least 1.5:1, (b) a fluorescent whitening agent selected from the group consisting of (i) fluorescent dyes selected from the group consisting of (1) 4,4'bis[(4-phenylamino-6-N-bis(2-hydroxyethyl)amino-1,3,5-triazin-2-yl)amino]stilbene-2,2'disulfonic acid, (2) 4,4'-bis(4-anilino-6-hydroxyethylmethylamino-1,3,5 triazin-2-yl)amino stilbene-2,2'disulfonic acid, (3) 4,4'-bis[(4-anilino-6-(morpholino)-1,3,5-triazin-2-yl)amino stilbene 2,2'disulfonic acid, (4) 4,4'-bis[(4-anilino-6-(methylamino)-1,3,5-triazin-2-yl)amino]stilene-2,2'disulfonic acid (ii) 5-(2H-napthol[1,2d]triazol-2-yl)-2-(2-phenylethenyl)-benzene-sulfonic acid (iii) 4,4'-bis(4-phenyl-1,2,3-triazol-2-yl)-stilbene-2,2'-disulfonic acid disodium salt or their alkali metal or ammonium salts and (c) a nonionizable base.
Claim 2
Dependent Claim
225 words
A liquid fabric softener comprising: (a) from about 10 to about 20 percent by weight of a quaternary active system including a first cationic surfactant having the formula ##STR8## wherein R 1 and R 2 are the same or different and are selected from the group consisting of C 8 to C 22 alkyl and alkenyl groups and R 3 is selected from the group consisting of H, methyl, ethyl and (C n H 2n O) x H wherein n is 2 or 3 and x is from 1 to about 5 and wherein X - is an anion, and a second cationic surfactant of the formula ##STR9## wherein R 4 and R 5 are the same or different and are selected from the group consisting of C 8 to C 22 alkyl and alkenyl and R 6 and R 7 are alkyl groups of from 1 to 3 carbon atoms and X is an anion, in a ratio of first to second surfactants of from at least 1.5:1, (b) a fluorescent whitening agent selected from the group consisting of (i) fluorescent dyes selected from the group consisting of (1) 4,4'bis[(4-phenylamino-6-N-bis(2-hydroxyethyl)amino-1,3,5-triazin-2-yl)amino]stilbene-2,2'disulfonic acid, (2) 4,4'-bis(4-anilino-6-hydroxyethylmethylamino-1,3,5 triazin-2-yl)amino stilbene-2,2'disulfonic acid, (3) 4,4'-bis[(4-anilino-6-(morpholino)-1,3,5-triazin-2-yl)amino stilbene 2,2'disulfonic acid, (4) 4,4'-bis[(4-anilino-6-(methylamino)-1,3,5-triazin-2-yl)amino]stilene-2,2'disulfonic acid (ii) 5-(2H-napthol[1,2d]triazol-2-yl)-2-(2-phenylethenyl)-benzene-sulfonic acid (iii) 4,4'-bis(4-phenyl-1,2,3-triazol-2-yl)-stilbene-2,2'-disulfonic acid disodium salt or their alkali metal or ammonium salts and (c) a nonionizable base.
Claim 3
Dependent Claim
28 words
The liquid fabric softener of claim 1 wherein the first fabric softener is a methyl bis C 8 -C 22 alkyl or alkenyl amidoethyl hydroxyethyl ammonium methyl sulfate.
Claim 4
Dependent Claim
18 words
The liquid fabric softener of claim 1 wherein the second fabric softener is a ditallow dimethyl ammonium chloride.
Claim 5
Dependent Claim
21 words
The liquid fabric softener of claim 1 wherein the ratio of first actives to second actives is between 20:1 and 1.5:1.
Claim 6
Dependent Claim
22 words
The liquid fabric softener of claim 1 wherein the ratio of first surfactant to second surfactant ratio is between 10:1 and 2:1.
Claim 7
Dependent Claim
21 words
The liquid fabric softener of claim 1 wherein the ratio of first actives to second actives is between 1.5:1 and 5:1.
Claim 8
Dependent Claim
19 words
The liquid fabric softener of claim 1 wherein the ratio of first actives to second actives is about 2.75:1.
Claim 9
Dependent Claim
15 words
The liquid fabric softener of claim 1 wherein the fluorescent whitening agent is 4,4'-bis[4phenylamino-6-N-bis(2-hydroxyethyl)amino-1,3,5-triazin-2-yl)amino]stilbene-2,2'-disulfonic acid.
Claim 10
Dependent Claim
15 words
The liquid fabric softener of claim 1 wherein the fluorescent whitening agent is 4,4'bis[4-anilino-6-hydroxyethyl-methylamino-1,3,5-triazin-2-yl)]stilbene-2,2'-disulfonic acid.
Claim 11
Dependent Claim
25 words
The liquid fabric softener of claim 1 wherein R 1 is selected from the group consisting of C 16 -C 18 alkyl and alkenyl groups.
Claim 12
Dependent Claim
25 words
The liquid fabric softener of claim 1 wherein R 2 is selected from the group consisting of C 16 -C 18 alkyl and alkenyl groups.
Claim 13
Dependent Claim
43 words
The liquid fabric softener of claim 1 wherein the anion X - for the first and second surfactants are independently selected from the group consisting of halides, sulfates, acetates and alkyl sulfates having from 1 to 3 carbon atoms in the alkyl chain.
Claim 14
Dependent Claim
18 words
The liquid fabric softener of claim 1 wherein the cationic surfactants consist of first surfactant and second surfactants.
References Cited (Backward Citations)
US3904533A
Cited
US4134840A
Cited
US4439335A
Cited
US4497718A
Cited
US4562002A
Cited
US4460485A
Cited
US4675022A
Cited
US4661269A
Cited
US4654152A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1991-09-20 | 1992-03-21 | 1992-09-20 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1995-09-20 | 1996-03-21 | 1996-09-20 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1999-09-20 | 2000-03-21 | 2000-09-20 | $7700.00 | Window Closed / Lapsed |