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US4772404A Expired / Lapsed US ⏱️ 0.0 years remaining

Concentrated liquid fabric softener with whiteners

Assignee: Lever Brothers Co
•
Filing: 1986-12-24
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Granted: 1988-09-20
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Expires: 2006-12-24
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Abstract

Abstract A concentrated fabric softener having a dual cationic high active system, a sufficient level of fluorescent dye to whiten cotton garments, and a non-ionizing base. The dual active system is included at levels of greater than about 10% and preferably comprises a difatty amido ammonium methyl sulfate and a ditallow dimethyl ammonium chloride in a ratio of at least 1.5:1. Use of the concentrated softener results in reduced container size and greater manufacturing efficiencies. Inclusion of fluorescent dye restores whiteness/brightness to cotton garments yellowed by age.

Inventors

  • 👤 Daniel J. Fox
  • 👤 Mary E. Sullivan
  • 👤 Anthony J. Cuomo

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 01:28
CPC Classifications
C; C11; C11D; C11D3/00; C11D3/40; C11D3/42; C11D1/00; C11D1/38; C11D1/645; C11D3/0005; C11D3/001; C11D3/0015

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 225 words
A liquid fabric softener comprising: (a) from about 10 to about 20 percent by weight of a quaternary active system including a first cationic surfactant having the formula ##STR8## wherein R 1 and R 2 are the same or different and are selected from the group consisting of C 8 to C 22 alkyl and alkenyl groups and R 3 is selected from the group consisting of H, methyl, ethyl and (C n H 2n O) x H wherein n is 2 or 3 and x is from 1 to about 5 and wherein X - is an anion, and a second cationic surfactant of the formula ##STR9## wherein R 4 and R 5 are the same or different and are selected from the group consisting of C 8 to C 22 alkyl and alkenyl and R 6 and R 7 are alkyl groups of from 1 to 3 carbon atoms and X is an anion, in a ratio of first to second surfactants of from at least 1.5:1, (b) a fluorescent whitening agent selected from the group consisting of (i) fluorescent dyes selected from the group consisting of (1) 4,4'bis[(4-phenylamino-6-N-bis(2-hydroxyethyl)amino-1,3,5-triazin-2-yl)amino]stilbene-2,2'disulfonic acid, (2) 4,4'-bis(4-anilino-6-hydroxyethylmethylamino-1,3,5 triazin-2-yl)amino stilbene-2,2'disulfonic acid, (3) 4,4'-bis[(4-anilino-6-(morpholino)-1,3,5-triazin-2-yl)amino stilbene 2,2'disulfonic acid, (4) 4,4'-bis[(4-anilino-6-(methylamino)-1,3,5-triazin-2-yl)amino]stilene-2,2'disulfonic acid (ii) 5-(2H-napthol[1,2d]triazol-2-yl)-2-(2-phenylethenyl)-benzene-sulfonic acid (iii) 4,4'-bis(4-phenyl-1,2,3-triazol-2-yl)-stilbene-2,2'-disulfonic acid disodium salt or their alkali metal or ammonium salts and (c) a nonionizable base.
Claim 2
Dependent Claim 225 words
A liquid fabric softener comprising: (a) from about 10 to about 20 percent by weight of a quaternary active system including a first cationic surfactant having the formula ##STR8## wherein R 1 and R 2 are the same or different and are selected from the group consisting of C 8 to C 22 alkyl and alkenyl groups and R 3 is selected from the group consisting of H, methyl, ethyl and (C n H 2n O) x H wherein n is 2 or 3 and x is from 1 to about 5 and wherein X - is an anion, and a second cationic surfactant of the formula ##STR9## wherein R 4 and R 5 are the same or different and are selected from the group consisting of C 8 to C 22 alkyl and alkenyl and R 6 and R 7 are alkyl groups of from 1 to 3 carbon atoms and X is an anion, in a ratio of first to second surfactants of from at least 1.5:1, (b) a fluorescent whitening agent selected from the group consisting of (i) fluorescent dyes selected from the group consisting of (1) 4,4'bis[(4-phenylamino-6-N-bis(2-hydroxyethyl)amino-1,3,5-triazin-2-yl)amino]stilbene-2,2'disulfonic acid, (2) 4,4'-bis(4-anilino-6-hydroxyethylmethylamino-1,3,5 triazin-2-yl)amino stilbene-2,2'disulfonic acid, (3) 4,4'-bis[(4-anilino-6-(morpholino)-1,3,5-triazin-2-yl)amino stilbene 2,2'disulfonic acid, (4) 4,4'-bis[(4-anilino-6-(methylamino)-1,3,5-triazin-2-yl)amino]stilene-2,2'disulfonic acid (ii) 5-(2H-napthol[1,2d]triazol-2-yl)-2-(2-phenylethenyl)-benzene-sulfonic acid (iii) 4,4'-bis(4-phenyl-1,2,3-triazol-2-yl)-stilbene-2,2'-disulfonic acid disodium salt or their alkali metal or ammonium salts and (c) a nonionizable base.
Claim 3
Dependent Claim 28 words
The liquid fabric softener of claim 1 wherein the first fabric softener is a methyl bis C 8 -C 22 alkyl or alkenyl amidoethyl hydroxyethyl ammonium methyl sulfate.
Claim 4
Dependent Claim 18 words
The liquid fabric softener of claim 1 wherein the second fabric softener is a ditallow dimethyl ammonium chloride.
Claim 5
Dependent Claim 21 words
The liquid fabric softener of claim 1 wherein the ratio of first actives to second actives is between 20:1 and 1.5:1.
Claim 6
Dependent Claim 22 words
The liquid fabric softener of claim 1 wherein the ratio of first surfactant to second surfactant ratio is between 10:1 and 2:1.
Claim 7
Dependent Claim 21 words
The liquid fabric softener of claim 1 wherein the ratio of first actives to second actives is between 1.5:1 and 5:1.
Claim 8
Dependent Claim 19 words
The liquid fabric softener of claim 1 wherein the ratio of first actives to second actives is about 2.75:1.
Claim 9
Dependent Claim 15 words
The liquid fabric softener of claim 1 wherein the fluorescent whitening agent is 4,4'-bis[4phenylamino-6-N-bis(2-hydroxyethyl)amino-1,3,5-triazin-2-yl)amino]stilbene-2,2'-disulfonic acid.
Claim 10
Dependent Claim 15 words
The liquid fabric softener of claim 1 wherein the fluorescent whitening agent is 4,4'bis[4-anilino-6-hydroxyethyl-methylamino-1,3,5-triazin-2-yl)]stilbene-2,2'-disulfonic acid.
Claim 11
Dependent Claim 25 words
The liquid fabric softener of claim 1 wherein R 1 is selected from the group consisting of C 16 -C 18 alkyl and alkenyl groups.
Claim 12
Dependent Claim 25 words
The liquid fabric softener of claim 1 wherein R 2 is selected from the group consisting of C 16 -C 18 alkyl and alkenyl groups.
Claim 13
Dependent Claim 43 words
The liquid fabric softener of claim 1 wherein the anion X - for the first and second surfactants are independently selected from the group consisting of halides, sulfates, acetates and alkyl sulfates having from 1 to 3 carbon atoms in the alkyl chain.
Claim 14
Dependent Claim 18 words
The liquid fabric softener of claim 1 wherein the cationic surfactants consist of first surfactant and second surfactants.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-09-20 1992-03-21 1992-09-20 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-09-20 1996-03-21 1996-09-20 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-09-20 2000-03-21 2000-09-20 $7700.00 Window Closed / Lapsed

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