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US4770977A Expired / Lapsed US ⏱️ 0.0 years remaining

Silicon-containing polymer and its use as a masking resin in a lithography process

Assignee: Commissariat à l'Énergie Atomique et Aux Énergies Alternatives
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Filing: 1987-05-07
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Granted: 1988-09-13
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Expires: 2007-05-07
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Abstract

Abstract Photosensitive film which is photosensitive in a given wavelength range comprises at least one silicon-containing polymer, at least one salt which can be converted into a Brunsted acid by irradiation and optionally at least one photosensitizer. The silicon-containing polymer-based photosensitive film can be used as a masking resin in a lithography process for producing electronic components.

Inventors

  • 👤 Francois Buiguez
  • 👤 Louis Giral
  • 👤 Charles Rosilio
  • 👤 Francois Schue

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 16:56
CPC Classifications
C; C08; C08F; C08F30/00; C08F30/04; C08F30/08; G; G03; G03F; G03F7/00; G03F7/004; G03F7/075; G03F7/0757; G03F7/0758

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 244 words
A process for masking certain zones of a substrate, wherein it comprises the following successive stages: (a) depositing on said substrate a first resin layer having a thickness such that it constitutes a levelling layer for the substrate, (b) depositing on said first resin layer, a second photosensitive film layer which comprises (1) at least one silicon-containing polymer in accordance with the formula: ##STR24## in which R 1 represents H or an alkyl radical of one to four carbon atoms, R 2 , R 3 , and R 4 , being the same or different, represent an alkyl radical of one to four carbon atoms, Z represents --O--, (CH 2 ) n --O-- with n being an integer between 1 and 4, or ##STR25## with R 5 , R 6 and R 7 , being the same or different, representing an alkyl radical of one to four carbon atoms, and m being a number between 25 and 2000, and (2) at least one salt which is converted into a Brunsted acid upon irradiation at a wavelength in the given wavelength range, (c) irradiating the zones of the second layer corresponding to the substrate zones which are not to be masked, by means of radiation with a wavelength corresponding to the photosensitivity range of the photosensitive film, and (d) eliminating the second photosensitive film layer and the first resin layer at the points corresponding to the zones of the second layer which have been irradiated.
Claim 2
Dependent Claim 244 words
A process for masking certain zones of a substrate, wherein it comprises the following successive stages: (a) depositing on said substrate a first resin layer having a thickness such that it constitutes a levelling layer for the substrate, (b) depositing on said first resin layer, a second photosensitive film layer which comprises (1) at least one silicon-containing polymer in accordance with the formula: ##STR24## in which R 1 represents H or an alkyl radical of one to four carbon atoms, R 2 , R 3 , and R 4 , being the same or different, represent an alkyl radical of one to four carbon atoms, Z represents --O--, (CH 2 ) n --O-- with n being an integer between 1 and 4, or ##STR25## with R 5 , R 6 and R 7 , being the same or different, representing an alkyl radical of one to four carbon atoms, and m being a number between 25 and 2000, and (2) at least one salt which is converted into a Brunsted acid upon irradiation at a wavelength in the given wavelength range, (c) irradiating the zones of the second layer corresponding to the substrate zones which are not to be masked, by means of radiation with a wavelength corresponding to the photosensitivity range of the photosensitive film, and (d) eliminating the second photosensitive film layer and the first resin layer at the points corresponding to the zones of the second layer which have been irradiated.
Claim 3
Dependent Claim 40 words
A process according to claim 1, wherein in stage (d), firstly the second photosensitive film layer is eliminated by dissolving in a solvent and wherein the second resin layer is then eliminated by reactive ionic etching in a gaseous plasma.
Claim 4
Dependent Claim 34 words
A process according to claim 1, wherein in stage (d), there is a simultaneous elimination of the second photosensitive film layer and the first resin layer by reactive ionic etching in a gaseous plasma.
Claim 5
Dependent Claim 16 words
A process according to claim 1, wherein, following irradiation, the second photosensitive film layer undergoes annealing.
Claim 6
Dependent Claim 17 words
A process according to claim 1, wherein the first resin layer is constituted by phenol formaldehyde resin.
Claim 7
Dependent Claim 39 words
A process according to claims 1 or 5, wherein the photosensitive film comprises for 100 parts by weight of poly-p-trimethylsilyloxystyrene, 5 to 15 parts by weight of triphenyl sulphonium hexafluoroarsenate and 3 to 10 parts by weight of perylene.
Claim 8
Dependent Claim 18 words
A process according to claim 6, wherein irradiation takes place at a wavelength of 386 to 475 nm.

References Cited (Backward Citations)

US4442197A Cited
US4551417A Cited
EP0102450B1 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-09-13 1992-03-14 1992-09-13 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-09-13 1996-03-14 1996-09-13 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-09-13 2000-03-14 2000-09-13 $7700.00 Window Closed / Lapsed

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