US4769115A
Expired / Lapsed
US
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Process for preparing electrically conductive polymer
Assignee: Kao Corp
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Filing: 1986-07-30
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Granted: 1988-09-06
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Expires: 2006-07-30
Abstract
Abstract An electrically conductive polymer is produced by dissolving or dispersing a monomer of an aromatic compound or a derivative thereof and an electrolyte in an organic polar medium, effecting an electrochemical, anodic oxidation in the resulting solution or dispersion, in the presence of one or more metal ions, to obtain an electrically conductive polymer, and separating the obtained polymer. The metal ion is being selected from the group consisting of a copper ion, bivalent silver ion, trivalent iron ion, trivalent manganese ion, a ruthenium ion, a rhenium ion and a rhodium ion. Films of the polymer have high conductivity.
Inventors
- 👤 Masaharu Satoh
- 👤 Keiichi Kaneto
- 👤 Katsumi Yoshino
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 18:45
CPC Classifications
C; C08; C08J; C08J5/00; C08J5/18; C08G; C08G61/00; C08G61/02; C08G61/10; H; H01; H01B; H01B1/00; H01B1/06; H01B1/12; H01B1/124; H01B1/128; H01M; H01M4/00; H01M4/02; H01M4/36; H01M4/60; C08J2365/00; Y; Y02; Y02E; Y02E60/00; Y02E60/10
Claims Analysis
Total Claims: 15
Claim 1
Independent Claim
188 words
A process for producing an electrically conductive polymer having an electroconductivity of from 10 to 100 S/cm, which comprises the steps of: dissolving or dispersing a monomer selected from the group consisting of benzene, biphenyl, diphenylbenzene, dibiphenylyl, naphthalene, anthracene, and any derivative or substituted compound thereof and a compound which provides an electrolyte selected from the group consisting of iodine ion, chlorine ion, fluorine ion, BF 4 - , ClO 4 - , AsF 6 - , SO 3 - , and PF 6 - , in an organic polar medium; applying a voltage of 5 to 80 V across the resulting solution or dispersion to effect an electrochemical, anodic oxidation reaction in the resulting solution or dispersion at a temperature lower than 80° C. in an inert gas, in the presence of at least one metal ion selected from the group consisting of a copper ion, a bivalent silver ion, a trivalent iron ion, a trivalent manganese ion, a ruthenium ion, a rhenium ion, and a rhodium ion, to obtain said electrically conductive polymer having an electroconductivity of from 10 to 100 S/cm; and separating said polymer.
Claim 2
Dependent Claim
188 words
A process for producing an electrically conductive polymer having an electroconductivity of from 10 to 100 S/cm, which comprises the steps of: dissolving or dispersing a monomer selected from the group consisting of benzene, biphenyl, diphenylbenzene, dibiphenylyl, naphthalene, anthracene, and any derivative or substituted compound thereof and a compound which provides an electrolyte selected from the group consisting of iodine ion, chlorine ion, fluorine ion, BF 4 - , ClO 4 - , AsF 6 - , SO 3 - , and PF 6 - , in an organic polar medium; applying a voltage of 5 to 80 V across the resulting solution or dispersion to effect an electrochemical, anodic oxidation reaction in the resulting solution or dispersion at a temperature lower than 80° C. in an inert gas, in the presence of at least one metal ion selected from the group consisting of a copper ion, a bivalent silver ion, a trivalent iron ion, a trivalent manganese ion, a ruthenium ion, a rhenium ion, and a rhodium ion, to obtain said electrically conductive polymer having an electroconductivity of from 10 to 100 S/cm; and separating said polymer.
Claim 3
Dependent Claim
15 words
The process as claimed in claim 1, wherein said metal ion is a copper ion.
Claim 4
Dependent Claim
16 words
The process as claimed in claim 1, wherein said metal ion is a bivalent silver ion.
Claim 5
Dependent Claim
21 words
The process as claimed in claim 1, wherein said metal ion is a trivalent iron ion or a trivalent manganese ion.
Claim 6
Dependent Claim
19 words
The process as claimed in claim 1, wherein said metal ion is an ion of ruthenium, rhenium or rhodium.
Claim 7
Dependent Claim
30 words
The process as claimed in claim 1, wherein said metal ion is contained in the reaction mixture in an amount of from 0.001 mole per liter to the saturation point.
Claim 8
Dependent Claim
47 words
The process as claimed in claim 1, wherein said monomer is contained in the reaction mixture in an amount of 0.1 to 10 moles per liter and said electrolyte is contained in the reaction mixture in an amount of 0.001 mole per liter to the saturation point.
Claim 9
Dependent Claim
33 words
The process of claim 1, wherein said organic polar medium is a solvent selected from the group consisting of acetonitrile, benzonitrile, nitrobenzene, nitromethane, dimethylformamide, hexamethyl phosphoamide, pyridine, propylene carbonate, tetrahydrofuran, dimethylsulfoxide, and dioxane.
Claim 10
Dependent Claim
36 words
The process of claim 1, wherein said compound which provides said electrolyte is selected from the group consisting of anionic alkali metal salts, alkaline earth metal salts, ammonium salts, and tetraalkyl ammonium salts of halogen elements.
Claim 11
Dependent Claim
42 words
The process of claim 9, wherein said compound which provides said electrolyte is selected from the group consisting of LiAsF 6 , LiClO 4 , LiBF 4 , tetrabutyl ammonium AsF 6 , tetrabutyl ClO 4 , and tetrabutyl BF 4 .
Claim 12
Dependent Claim
27 words
The process of claim 8, wherein said solvent is nitrobenzene, a bivalent silver ion is AgO, and a compound which produces the electrolyte is LiAsF 6 .
Claim 13
Dependent Claim
29 words
The process of claim 8, wherein said solvent is nitrobenzene, a trivalent manganese ion is MnCl 3 , and the compound which produces the electrolyte is LiAsF 6 .
Claim 14
Dependent Claim
11 words
A film formed from the polymer produced according to claim 1.
Claim 15
Dependent Claim
14 words
The process of claim 1, wherein the voltage ranges from 15 to 40 V.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1991-09-06 | 1992-03-07 | 1992-09-06 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1995-09-06 | 1996-03-07 | 1996-09-06 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1999-09-06 | 2000-03-07 | 2000-09-06 | $7700.00 | Window Closed / Lapsed |