Accelerators for the cure of epoxy resins with amine curing agents

Claim 2

A rapid curing epoxy resin composition comprising a mixture of (a) a first component comprising a polyepoxide, and (b) a second component comprising a mixture of thereaction product of (1) an ammonium salt of a non-nucleophilic acid with (2) the reaction product of (a) a bicyclic amide acetal with (b) an amine, and (3) an amine curing agent.

Claim 3

The composition of claim 1 wherein the polyepoxide is a compound containing more than one group of the formula ##STR3##

Claim 4

The composition of claim 2 wherein the non-nucleophilic acid has the formula NH 4 X wherein X represents BF 4 , BPh 4 , PF 6 , SbF 6 or AsF 6 and wherein Ph represents a phenyl group (C 6 H 5 ).

Claim 5

The composition of claim 3 wherein the bicyclic amide acetal is one having the formula ##STR4## wherein R, R' and R" independently represent hydrogen, an alkyl group having from 1 to 20 carbon atoms, an alkyl ether group having from 1 to 20 carbon atoms, an aryl group having from 6 to 20 carbon atoms, an aryl ether group having from 6 to 20 carbon atoms or an alkaryl group having from 7 to 20 carbon atoms.

Claim 6

The composition of claim 4 wherein the amine [(2)(b)] is one having the formula H 2 NCH(R'")(CH 2 ) n NHY wherein R'" represents hydrogen or a methyl group, Y represents hydrogen, an alkyl group having from 1 to 20 carbon atoms, and ethylene amine group or a propylene amine group and n represents 1 or 2.

Claim 7

The composition of claim 5 wherein the amine curing agent [(3)] is selected from the group consisting of butylamines, dodecyl amines, cyclohexyl amine, ethylene diamine, diethylene triamine, triethylene tetramine, tetraethylene pentamine, propylene diamine, dipropylene triamine, cyclohexane dimethyl diamine, triethyl amine, tributyl amine, triethylene diamine, imidazolines, imidazoles, imidazines, hexamethylene diamine, isophorone diamine, aminoethyl piperazine, bis(aminopropyl) piperazine, piperidine, morpholine, dimer acid diamine, xylylene diamine, ethanolamine, diethanol amine, N-alkyl alkanolamines, poly(alkylene ether) polyamines of molecular weight up to 10,000, and amido amines formed by the reaction of polyalkylene amines with a carboxylic acid.

Claim 8

The composition of claim 6 wherein there is present from 0.2% to about 15% by weight of the reaction product [(1) and (2)].

Claim 9

The composition of claim 7 wherein there is present from 0.6:1 to 1.5:1 equivalents of polyepoxide:amine curing agent [(3)].

Claim 10

The composition of claim 8 wherein the polyepoxide is the diglycidyl ether of Bisphenol-A and the bicyclic amide acetal is one in which R and R" represent hydrogen and R' represents a methyl group.

Claim 11

The composition of claim 9 wherein the amine [(2)(b)] is 1,2-diamino propane.

Claim 12

The composition of claim 9 wherein the amine [(2)(b)] is diethylene triamine.

Claim 13

The composition of claim 10 wherein the amine curing agent [(3)] is aminoethylpiperazine.

Claim 14

The composition of claim 10 wherein the amine curing agent [(3)] is diethylene tetramine.

Claim 15

The composition of claim 10 wherein the amine curing agent [(3)] is triethylene tetramine.

Claim 16

The composition of claim 10 wherein the amine curing agent [(3)] is 1,2-diamino propane.

Claim 17

The composition of claim 10 wherein the amine curing agent [(3)] is tris(aminoethyl) amine.

Claim 18

The composition of claim 10 wherein the amine curing agent [(3)] is poly(oxypropylene) diamine.

Claim 19

The composition of claim 11 wherein the amine curing agent [(3)] is diethylene triamine.

Claim 20

The composition of claim 11 wherein the amine curing agent [(3)] is ethylene diamine.

Claim 21

An accelerator composition comprising the reaction product of (1) the ammonium salt of a non-nucleophilic acid with (2) the reaction product of (a) a bicyclic amide acetal with (b) an amine.

Claim 22

An accelerator composition comprising the reaction product of (1) the ammonium salt of a non-nucleophilic acid with (2) the reaction product of (a) a bicyclic amide acetal with (b) an amine.