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US4766055A Expired / Lapsed US ⏱️ 0.0 years remaining

Photopolymerizable composition containing a certain xanthene or thioxanthene dyestuff

Assignee: Nippon Paint Co Ltd
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Filing: 1986-08-01
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Granted: 1988-08-23
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Expires: 2006-08-01
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Abstract

Abstract Disclosed is a photopolymerizable composition which is very sensitive to visible light. The composition comprises a polymerizable compound and a photopolymerization initiator wherein the photopolymerization initiator comprises (a) a particular xanthene or thioxanthene dyestuff, (b) a photosensitizer selected from the group consisting of N-phenylglycine, 2,4,6-tris(trichloromethyl)-1,3,5-triazine, and a mixture of p-dimethylaminobenzoic acid isopentyl ester and 2,4-diisopropylthioxanthone, and (c) a peroxide.

Inventors

  • 👤 Masami Kawabata
  • 👤 Koichi Kimoto
  • 👤 Yasuyuki Takimoto

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 19:07
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/004; G03F7/027; G03F7/028; G03F7/031; C; C08; C08F; C08F2/00; C08F2/46; C08F2/48; C08F2/50; Y; Y10; Y10S; Y10S430/00; Y10S430/1053; Y10S430/1055; Y10S430/114; Y10S430/116; Y10S430/117; Y10S430/12; Y10S430/121; Y10S430/122; Y10S430/123; Y10S430/124; Y10S430/127

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 204 words
A photopolymerizable composition comprising a polymerizable compound and a photopolymerization initiator, wherein the photopolymerization initiator comprises: (a) a xanthene or thioxanthene dyestuff having the formula ##STR4## wherein A represents an oxygen atom or a sulfur atom, X represents a hydrogen atom or a halogen atom, Y represents a carbon atom or a nitrogen atom, provided that when Y represents a carbon atom the bond with the adjacent carbon atom which is shown by the dotted line is a double bond, and when Y represents a nitrogen atom the bond with the adjacent carbon atom is a single bond, Z represents an oxygen atom wherein the bond with the adjacent carbon atom is a double bond, a lower alkoxy group or a lower alkanoyloxy group, R 1 represents a lower alkyl group, a hydroxy lower alkyl group, a lower alkoxy lower alkyl group, a di- lower alkylamino lower alkyl group or an aryl group, R 2 represents a hydrogen atom, a lower alkoxy group or a di- lower alkylamino group, or Z and R 1 together represent the formula ##STR5## (b) a photosensitizer selected from the group consisting of N-phenylglycine, 2,4,6-tris(trichloromethyl)-1,3,5-triazine, and a mixture of p-dimethylaminobenzoic acid isopentyl ester and 2,4-diisopropylthioxanthone, and (c) a peroxide.
Claim 2
Dependent Claim 204 words
A photopolymerizable composition comprising a polymerizable compound and a photopolymerization initiator, wherein the photopolymerization initiator comprises: (a) a xanthene or thioxanthene dyestuff having the formula ##STR4## wherein A represents an oxygen atom or a sulfur atom, X represents a hydrogen atom or a halogen atom, Y represents a carbon atom or a nitrogen atom, provided that when Y represents a carbon atom the bond with the adjacent carbon atom which is shown by the dotted line is a double bond, and when Y represents a nitrogen atom the bond with the adjacent carbon atom is a single bond, Z represents an oxygen atom wherein the bond with the adjacent carbon atom is a double bond, a lower alkoxy group or a lower alkanoyloxy group, R 1 represents a lower alkyl group, a hydroxy lower alkyl group, a lower alkoxy lower alkyl group, a di- lower alkylamino lower alkyl group or an aryl group, R 2 represents a hydrogen atom, a lower alkoxy group or a di- lower alkylamino group, or Z and R 1 together represent the formula ##STR5## (b) a photosensitizer selected from the group consisting of N-phenylglycine, 2,4,6-tris(trichloromethyl)-1,3,5-triazine, and a mixture of p-dimethylaminobenzoic acid isopentyl ester and 2,4-diisopropylthioxanthone, and (c) a peroxide.
Claim 3
Dependent Claim 192 words
The composition of claim 1 wherein in the xanthene or thioxanthene dyestuff, A represents an oxygen atom or a sulfur atom, X represents a hydrogen atom or a halogen atom, Y represents a carbon atom or a nitrogen atom, provided that when Y represents a carbon atom the bond with the adjacent carbon atom which is shown by the dotted line is a double bond, and when Y represents a nitrogen atom the bond with the adjacent carbon atom is a single bond, Z represents an oxygen atom wherein the bond with the adjacent carbon atom is a double bond, a C 1 -C 3 alkoxy group or a C 2 -C 4 alkanoyloxy group, R 1 represents a C 1 -C 10 alkyl group, a hydroxy C 1 -C 4 alkyl group, a C 1 -C 3 alkoxy C 1 -C 4 alkyl group, a di-C 1 -C 2 alkylamino C 1 -C 4 alkyl group or an aryl group, R 2 represents a hydrogen atom, a C 1 -C 3 alkoxy group or a di-C.sub. 1 -C 2 alkylamino group, or Z and R 1 together represent the formula ##STR6##
Claim 4
Dependent Claim 10 words
The composition of claim 1 wherein the photosensitizer is N-phenylglycine.
Claim 5
Dependent Claim 10 words
The composition of claim 1 wherein the photosensitizer is 2,4,6-tris(trichloromethyl)-1,3,5-triazine.
Claim 6
Dependent Claim 18 words
The composition of claim 1 wherein the photosensitizer is a mixture of p-dimethylaminobenzoic acid isopentyl ester and 2,4-diisopropylthioxanthone.
Claim 7
Dependent Claim 33 words
The composition of claim 1 wherein the dyestuff is present in the composition in an amount of 0.005 to 0.3 part by weight based on one part by weight of the polymerizable compound.
Claim 8
Dependent Claim 33 words
The composition of claim 1 wherein the peroxide is present in the composition in an amount of 0.005 to 0.2 part by weight based on one part by weight of the polymerizable compound.
Claim 9
Dependent Claim 16 words
The composition of claim 1 wherein the polymerizable compound has two ethylenically unsaturated bonds per molecule.
Claim 10
Dependent Claim 18 words
The composition of claim 8 wherein the polymerizable compound has a boiling point of at least 100° C.
Claim 11
Dependent Claim 13 words
The composition of claim 1 wherein the composition further comprises a polymeric binder.

References Cited (Backward Citations)

JPS59189340A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-08-23 1992-02-22 1992-08-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-08-23 1996-02-22 1996-08-23 $3760.00 Window Closed / Lapsed
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