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US4764431A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for protecting and consolidating stone materials

Assignee: Consiglio Nazionale delle Richerche
•
Filing: 1986-02-21
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Granted: 1988-08-16
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Expires: 2006-02-21
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Abstract

Abstract The surface of stone materials, of tiles, of cement mixes and articles and structures manufactured therefrom are protected against atmospheric and polluting agents by superficially applying a protecting material consisting of a vinylidene fluoride polymer or copolymer comprising 55-100% by moles of vinylidene fluoride, 0-5% by moles of propene hexafluoride and 0-30% by moles of tetrafluoroethylene. Such polymers or copolymers are applied to the surface to be protected in the form of a solution in volatile solvents.

Inventors

  • 👤 Franco Piacenti
  • 👤 Adolfo Pasetti
  • 👤 Carlo Manganelli Del Fa
  • 👤 Giovanni Moggi

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 22:18
CPC Classifications
C; C04; C04B; C04B41/00; C04B41/45; C04B41/46; C04B41/48; C04B41/4838; C04B41/4842; C08; C08L; C08L27/00; C08L27/02; C08L27/12; C08L27/16; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/3154; Y10T428/31544; Y10T428/4935

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 94 words
A process for protecting and consolidating stone materials, marble, sandstone, tiles, cement mixes and articles and structures manufactured therefrom from the degrading action exerted by atmospheric and/or polluting agents, characterized in that an uncured polymeric material consisting of a vinylidene fluoride homopolymer or copolymer is applied to the surface of such materials and manufactured articles and structures, said vinylidene fluoride homopolymer or copolymer containing from about 55 to about 100% by moles of vinylidene fluoride, from 0 to about 30% by moles of tetrafluoroethylene, and from 0 to about 45% by moles of hexafluoropropene.
Claim 2
Dependent Claim 94 words
A process for protecting and consolidating stone materials, marble, sandstone, tiles, cement mixes and articles and structures manufactured therefrom from the degrading action exerted by atmospheric and/or polluting agents, characterized in that an uncured polymeric material consisting of a vinylidene fluoride homopolymer or copolymer is applied to the surface of such materials and manufactured articles and structures, said vinylidene fluoride homopolymer or copolymer containing from about 55 to about 100% by moles of vinylidene fluoride, from 0 to about 30% by moles of tetrafluoroethylene, and from 0 to about 45% by moles of hexafluoropropene.
Claim 3
Dependent Claim 17 words
The process according to claim 1, in which the homopolymer or copolymer is applied as a solution.
Claim 4
Dependent Claim 55 words
Articles and structures manufactured from stone materials, marble, sandstone, tiles, and cement mixes provided with a coat consisting of an uncured polymer or copolymer comprising from about 55 to about 100% by moles of vinylidene fluoride, from 0 to about 45% by moles of hexafluoropropene and from 0 to about 30% by moles of tetrafluoroethylene.
Claim 5
Dependent Claim 55 words
Articles and structures manufactured from stone materials, marble, sandstone, tiles, and cement mixes provided with a coat consisting of an uncured polymer or copolymer comprising from about 55 to about 100% by moles of vinylidene fluoride, from 0 to about 45% by moles of hexafluoropropene and from 0 to about 30% by moles of tetrafluoroethylene.
Claim 6
Dependent Claim 18 words
The process according to claim 2, in which the solvent for the homopolymer or copolymer is a ketone.
Claim 7
Dependent Claim 12 words
The process according to claim 4, in which the solvent is methylethylketone.
Claim 8
Dependent Claim 13 words
The process according to claim 2, in which the solvent is an ester.
Claim 9
Dependent Claim 13 words
The process according to claim 2, in which the ester is methyl acetate.
Claim 10
Dependent Claim 12 words
The process of claim 2 in which the solvent is an ether.
Claim 11
Dependent Claim 12 words
The process according to claim 2, in which the solvent is tetrahydrofuran.
Claim 12
Dependent Claim 23 words
The process of claim 2 in which the solvent for the homopolymer or copolymer has a boiling point not higher than 160° C.
Claim 13
Dependent Claim 23 words
The process of claim 2 in which the solvent for the homopolymer or copolymer has a boiling point not lower than 30° C.

References Cited (Backward Citations)

US2635093A Cited
US3988187A Cited
US4022742A Cited
US4347268A Cited
US4495248A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-08-16 1992-02-15 1992-08-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-08-16 1996-02-15 1996-08-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-08-16 2000-02-15 2000-08-16 $7700.00 Window Closed / Lapsed

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