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US4764425A Expired / Lapsed US ⏱️ 0.0 years remaining

Oriented, heat sealable multi-layered film

Assignee: Mobil Oil AS
•
Filing: 1987-01-02
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Granted: 1988-08-16
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Expires: 2007-01-02
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Abstract

Abstract An oriented, heat-sealable polypropylene film is provided which possesses a low coefficient of friction, excellent anti-static behavior and good optical clarity.

Inventors

  • 👤 Riccardo Balloni
  • 👤 Jay Keung
  • 👤 David A. Liestman
  • 👤 Michael Nahmias

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 22:41
CPC Classifications
B; B32; B32B; B32B27/00; B32B27/06; B32B27/08; B32B27/18; B32B27/32; B32B38/00; B32B38/0008; B32B2307/00; B32B2307/30; B32B2307/31; B32B2307/50; B32B2307/514; B32B2310/00; B32B2310/14; Y; Y10; Y10T; Y10T428/00; Y10T428/25; Y10T428/259; Y10T428/26; Y10T428/28; Y10T428/2813; Y10T428/2817; Y10T428/2826; Y10T428/31504; Y10T428/31652; Y10T428/31667; Y10T428/31855; Y10T428/31909; Y10T428/31913

Claims Analysis

Total Claims: 28
Claim 1
Independent Claim 246 words
A multi-layer film structure comprising coextruded, oriented heat sealable film comprising: (a) at least one heat sealable layer consisting of a random copolymer and/or a terpolymer compounded with an effective amount of a finely divided anti-blocking agent comprising particulate inorganic materials having mean particle sizes from about 0.5 to about 5 microns present in amounts from about 0.05% to about 0.5% by weight of the heat sealable layer but substantially devoid of silicone oil, the exposed suface of which is thereafter treated with a coefficient of friction reducing amount of silicone oil transferred thereto through contact of said exposed surface with a silicone oil containing heat sealable layer; (b) a core layer derived from isotactic polypropylene containing an effective amount of an anti-static agent comprising a suitable tertiary amine and/or a glyceride selected from the group consisting glyercol monostearate and/or a mixture of said amine and said glyercide and /or; (c) at least one heat sealable layer derived from a group consisting of random copolymers and/or terpolymers, said polymers being compounded with an effective amount of said anti-blocking agent and an amount of silicone oil sufficient to maintain a low coefficient of friction on layer (c) and also on the exposed surface of layer (a) following mutual contact of said surfaces whereby said film possesses a low coefficient of friction, excellent anti-static behavior and good optical clarity in comparison to film structures not having the described heat sealable layers in combination with the described additive materials.
Claim 2
Dependent Claim 246 words
A multi-layer film structure comprising coextruded, oriented heat sealable film comprising: (a) at least one heat sealable layer consisting of a random copolymer and/or a terpolymer compounded with an effective amount of a finely divided anti-blocking agent comprising particulate inorganic materials having mean particle sizes from about 0.5 to about 5 microns present in amounts from about 0.05% to about 0.5% by weight of the heat sealable layer but substantially devoid of silicone oil, the exposed suface of which is thereafter treated with a coefficient of friction reducing amount of silicone oil transferred thereto through contact of said exposed surface with a silicone oil containing heat sealable layer; (b) a core layer derived from isotactic polypropylene containing an effective amount of an anti-static agent comprising a suitable tertiary amine and/or a glyceride selected from the group consisting glyercol monostearate and/or a mixture of said amine and said glyercide and /or; (c) at least one heat sealable layer derived from a group consisting of random copolymers and/or terpolymers, said polymers being compounded with an effective amount of said anti-blocking agent and an amount of silicone oil sufficient to maintain a low coefficient of friction on layer (c) and also on the exposed surface of layer (a) following mutual contact of said surfaces whereby said film possesses a low coefficient of friction, excellent anti-static behavior and good optical clarity in comparison to film structures not having the described heat sealable layers in combination with the described additive materials.
Claim 3
Dependent Claim 35 words
The structure of claim 1 wherein said copolymers are either the same or different random copolymers of ethylene and propylene and said terpolymers are either the same or different terpolymers of ethylene, propylene and butene-1.
Claim 4
Dependent Claim 24 words
The structure of claim 2 wherein the copolymers of ethylene and propylene independently contain from about 2 to about 9% by weight of ethylene.
Claim 5
Dependent Claim 36 words
The structure of claim 2 wherein the terpolymers of ethylene, propylene and butene-1 independently contain from about 2 to about 7% by weight of ethylene and from about 4 to about 5% by weight of butene-1.
Claim 6
Dependent Claim 11 words
The structure of claim 1 wherein said anti-blocking agent is silica.
Claim 7
Dependent Claim 36 words
The structure as claim 1 wherein the tertiary amines of core layer (b) are selected from the group consisting of alkyl coco and tallow amines, N,N bis (2-hydroxyethyl) alkenyl or mixed alkenyl amine or mixtures thereof.
Claim 8
Dependent Claim 13 words
The structure of claim 6 wherein said amine is N,N bis (2-hydroxyethyl) stearylamine.
Claim 9
Dependent Claim 26 words
The structure of claim 7 wherein the core layer (b) further comprises anti-static amounts of a mixture comprising said stearyl amine, cocoamine and a glycerol monosterate.
Claim 10
Dependent Claim 25 words
The structure of claim 1 wherein heat sealable layers (a) and (c) each have a coefficient of friction varying from about 0.10 to about 0.40.
Claim 11
Dependent Claim 24 words
The structure of claim 9 wherein heat sealable layers (a) and (c) have a coefficient of friction varying from about 0.20 to about 0.30.
Claim 12
Dependent Claim 20 words
The structure of claim 1 wherein layer (c) contains from about 0.5 to about 3.0% by weight of silicone oil.
Claim 13
Dependent Claim 19 words
The structure of claim 10 wherein said layer (c) contains about 1.1 to 1.5% by weight of silicone oil.
Claim 14
Dependent Claim 24 words
The structure of claim 1 wherein each of the heat sealable layers is sealable both to itself and to the other heat sealable layer.
Claim 15
Dependent Claim 23 words
The structure of claim 1 wherein said heat sealable layer substantially devoid of silicone oil is subject to treatment to enhance surface properties.
Claim 16
Dependent Claim 16 words
The structure of claim 14 wherein the treatment means include corona discharge, chemical or flame treatment.
Claim 17
Dependent Claim 174 words
A multi-layer film structure comprising coextruded, oriented heat sealable film comprising: (a) at least one heat sealable layer consisting of a random copolymer and/or a terpolymer compounded with an effective amount of a finely divided anti-blocking agent comprising particulate inorganic materials having mean particle sizes from about 0.5 to about 5 microns and is present in amounts from about 0.05% to about 0.5% by weight of said heat sealable layer but substantially devoid of silicone oil, the exposed suface of which is thereafter treated with a coefficient of friction reducing amount of silicone oil transferred thereto through contact of said exposed surface with a silicone oil containing heat sealable layer; (b) a core layer derived from isotactic polypropylene containing an effective amount of an anti-static additive comprising a suitable teritary amine and being compounded with an effective amount of an anti-blocking agent and an amount of silicone oil sufficient to maintain a low coefficient of friction on layer (b) and also on the exposed surface of layer (a) following mutual contact of said surfaces.
Claim 18
Dependent Claim 174 words
A multi-layer film structure comprising coextruded, oriented heat sealable film comprising: (a) at least one heat sealable layer consisting of a random copolymer and/or a terpolymer compounded with an effective amount of a finely divided anti-blocking agent comprising particulate inorganic materials having mean particle sizes from about 0.5 to about 5 microns and is present in amounts from about 0.05% to about 0.5% by weight of said heat sealable layer but substantially devoid of silicone oil, the exposed suface of which is thereafter treated with a coefficient of friction reducing amount of silicone oil transferred thereto through contact of said exposed surface with a silicone oil containing heat sealable layer; (b) a core layer derived from isotactic polypropylene containing an effective amount of an anti-static additive comprising a suitable teritary amine and being compounded with an effective amount of an anti-blocking agent and an amount of silicone oil sufficient to maintain a low coefficient of friction on layer (b) and also on the exposed surface of layer (a) following mutual contact of said surfaces.
Claim 19
Dependent Claim 27 words
The structure of claim 16 wherein said copolymer is a random copolymer of ethylene and propylene and said terpolymer is a terpolymer of ethylene, propylene and butene-1.
Claim 20
Dependent Claim 23 words
The structure of claim 17 wherein the copolymer of ethylene and propylene contain from about 2 to about 9% by weight of ethylene.
Claim 21
Dependent Claim 28 words
The structure of claim 17 wherein said terpolymer contains from about 2 to about 7 wt. % ethylene and from about 4 to about 5 wt. % butene-1.
Claim 22
Dependent Claim 11 words
The structure of claim 16 wherein said core layer is homopolypropylene.
Claim 23
Dependent Claim 149 words
A multi-layer film structure comprising coextruded, oriented heat sealable film comprising: (a) a core layer derived from isotactic polypropylene containing an effective amount of an anti-static agent comprising a suitable tertiary amine and/or a glyceride selected from the group consisting glyercol monostearate, and/or a mixture of said amine and said glyercide and /or; (b) at least one heat sealable layer derived from a group consisting of random copolymers and/or terpolymers, said polymers being compounded with an effective amount of said anti-blocking agent whereby said film possesses a low coefficient of friction, excellent anti-static behavior and good optical clarity in comparison to film structures not having the described heat sealable layers in combination with the described additive materials and an amount of silicone oil sufficient to maintain a low coefficient of friction on layer (c) and also on the exposed surface of ayer (a) following mutual contact of said surfaces.
Claim 24
Dependent Claim 149 words
A multi-layer film structure comprising coextruded, oriented heat sealable film comprising: (a) a core layer derived from isotactic polypropylene containing an effective amount of an anti-static agent comprising a suitable tertiary amine and/or a glyceride selected from the group consisting glyercol monostearate, and/or a mixture of said amine and said glyercide and /or; (b) at least one heat sealable layer derived from a group consisting of random copolymers and/or terpolymers, said polymers being compounded with an effective amount of said anti-blocking agent whereby said film possesses a low coefficient of friction, excellent anti-static behavior and good optical clarity in comparison to film structures not having the described heat sealable layers in combination with the described additive materials and an amount of silicone oil sufficient to maintain a low coefficient of friction on layer (c) and also on the exposed surface of ayer (a) following mutual contact of said surfaces.
Claim 25
Dependent Claim 27 words
The structure of claim 21 wherein said copolymer is a random copolymer of ethylene and propylene and said terpolymer is a terpolymer of ethylene, propylene and butene-1.
Claim 26
Dependent Claim 23 words
The structure of claim 22 wherein the copolymer of ethylene and propylene contain from about 2 to about 7% by weight of ethylene.
Claim 27
Dependent Claim 28 words
The structure of claim 22 wherein said terpolymer contains from about 2 to about 7 wt. % ethylene and from about 4 to about 5 wt. % butene-1.
Claim 28
Dependent Claim 11 words
The structure of claim 21 wherein said core layer is homopolypropylene.

References Cited (Backward Citations)

US4439478A Cited
US4595625A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-08-16 1992-02-15 1992-08-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-08-16 1996-02-15 1996-08-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-08-16 2000-02-15 2000-08-16 $7700.00 Window Closed / Lapsed

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