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US4759874A Expired / Lapsed US ⏱️ 0.0 years remaining

Benzocyclobutene-based die attach adhesive compositions

Assignee: Dow Chemical Co
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Filing: 1987-08-03
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Granted: 1988-07-26
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Expires: 2007-08-03
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Abstract

Abstract The invention is a die attach adhesive composition comprising a homogeneous blend of an organopolysiloxane-bridged bisbenzocyclobutene monomer, an organosilane adhesion aid, and a finely divided electrically conductive metal. The composition is easy to apply, exhibits good adhesive strength and thermal stability at high temperatures, and does not require solvents, initiators, or curing agents. Weight loss on cure is minimal.

Inventors

  • 👤 William A. Gros

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 21:40
CPC Classifications
H; H01; H01B; H01B1/00; H01B1/20; H01B1/22; C; C08; C08G; C08G77/00; C08G77/04; C08G77/20; C09; C09J; C09J183/00; C09J183/04; C09J4/00; C08L; C08L2666/00; C08L2666/28; C08L2666/44; C08L2666/54

Claims Analysis

Total Claims: 19
Claim 1
Independent Claim 180 words
A die attach adhesive composition comprising a homogeneous blend of: (a) about 5 to about 30 weight percent of a bisbenzocyclobutene monomer of the formula: ##STR12## wherein: each R is independently alkyl of 1 to 6 carbon atoms, cycloalkyl, aralkyl, or phenyl; each R 1 is independently vinyl, allyl, methallyl, or styryl; each R 2 is independently substituted or unsubstituted alkyl of 1 to 6 carbon atoms, methoxy, acetate, trifluoroacetate, nitro, chloro, bromo, or iodo; each R 3 is independently chloro, bromo, iodo, nitro, substituted or unsubstituted alkyl of 1 to 6 carbon atoms, and cyano; n is an integer of 1 or more; and each q and r are independently integers of zero or 1; (b) about 1 to about 10 weight percent of an organosilane adhesion promoter of the formula: R.sub.n SiX.sub.(4-n) wherein R is a nonhydrolyzable organic radical that possesses a benzocyclobutene-reactive functionality; X is alkoxy, acyloxy, or amino; and n is an integer of 1, 2, and 3; and (c) an amount of an electrically conductive metal effective for the composition to reach the percolation threshold.
Claim 2
Dependent Claim 180 words
A die attach adhesive composition comprising a homogeneous blend of: (a) about 5 to about 30 weight percent of a bisbenzocyclobutene monomer of the formula: ##STR12## wherein: each R is independently alkyl of 1 to 6 carbon atoms, cycloalkyl, aralkyl, or phenyl; each R 1 is independently vinyl, allyl, methallyl, or styryl; each R 2 is independently substituted or unsubstituted alkyl of 1 to 6 carbon atoms, methoxy, acetate, trifluoroacetate, nitro, chloro, bromo, or iodo; each R 3 is independently chloro, bromo, iodo, nitro, substituted or unsubstituted alkyl of 1 to 6 carbon atoms, and cyano; n is an integer of 1 or more; and each q and r are independently integers of zero or 1; (b) about 1 to about 10 weight percent of an organosilane adhesion promoter of the formula: R.sub.n SiX.sub.(4-n) wherein R is a nonhydrolyzable organic radical that possesses a benzocyclobutene-reactive functionality; X is alkoxy, acyloxy, or amino; and n is an integer of 1, 2, and 3; and (c) an amount of an electrically conductive metal effective for the composition to reach the percolation threshold.
Claim 3
Dependent Claim 9 words
The composition of claim 1 wherein n is 1.
Claim 4
Dependent Claim 13 words
The composition of claim 2 wherein the bisbenzocyclobutene monomer has the formula: ##STR13##
Claim 5
Dependent Claim 9 words
The composition of claim 1 wherein n is 1.
Claim 6
Dependent Claim 11 words
The composition of claim 4 wherein R contains a benzocyclobutene group.
Claim 7
Dependent Claim 14 words
The composition of claim 5 wherein the organosilane adhesion promoter has the formula: ##STR14##
Claim 8
Dependent Claim 14 words
The composition of claim 5 wherein the organosilane adhesion promoter has the formula: ##STR15##
Claim 9
Dependent Claim 14 words
The composition of claim 5 wherein the organosilane adhesion promoter has the formula: ##STR16##
Claim 10
Dependent Claim 16 words
The composition of claim 1 wherein the electrically conductive metal is silver, gold, copper, or nickel.
Claim 11
Dependent Claim 13 words
The composition of claim 9 wherein the electrically conductive metal is silver flake.
Claim 12
Dependent Claim 51 words
The composition of claim 1 further comprising about 1 to about 20 weight percent of a second bisbenzocyclobutene monomer of any one of the formulae: ##STR17## wherein R is separately in each occurrence hydrogen, an electron-withdrawing substituent, or an electron-donating substituent; ##STR18## p is an integer of between 2 and 10.
Claim 13
Dependent Claim 20 words
The composition of claim 11 wherein the second bisbenzocyclobutene monomer has the formula: ##STR19## wherein n is 6 or 7.
Claim 14
Dependent Claim 14 words
The composition of claim 11 wherein the second bisbenzocyclobutene monomer has the formula: ##STR20##
Claim 15
Dependent Claim 14 words
The composition of claim 11 wherein the second bisbenzocyclobutene monomer has the formula: ##STR21##
Claim 16
Dependent Claim 28 words
The composition of claim 1 wherein the amount of the bisbenzocyclobutene monomer can range from about 10 percent to about 25 percent of the weight of the composition.
Claim 17
Dependent Claim 29 words
The composition of claim 1 wherein the amount of the organosilane adhesion promoter can range from about 2 percent to about 6 percent of the weight of the composition.
Claim 18
Dependent Claim 25 words
The composition of claim 11 wherein the amount of the second bisbenzocyclobutene monomer can range from 5 percent to about 15 percent of the composition.
Claim 19
Dependent Claim 28 words
The composition of claim 1 further comprising of about 1 to about 20 weight percent of a second bisbenzocyclobutene monomer of the formula: ##STR22## wherein n is 12.

References Cited (Backward Citations)

US2970077A Cited
US3347978A Cited
US3265640A Cited
US3981762A Cited
US4466850A Cited
US4661193A Cited
US4540763A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-07-26 1992-01-25 1992-07-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-07-26 1996-01-25 1996-07-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-07-26 2000-01-25 2000-07-26 $7700.00 Window Closed / Lapsed

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