Coated ophthalmic lenses and method for coating the same

Claim 2

A curved ophthalmic lens having an SEB abrasion resistance of at least 20 psi and providing refraction of light comprising an optically clear, solid, room-temperature stable substrate, and an optically clear, aberration-free, abrasion-resistant coating intimately bonded to said substrate, said coating providing essentially exactly an optical surface of desired configuration, said coating comprising the polymerization product of a composition containing reactive ethylenically unsaturated groups, wherein said coating exhibits an adhesion of at least 90% to said substrate when tested according to ASTM D-3359.

Claim 3

A lens according to claim 1 wherein said material containing reactive ethylenically unsaturated groups is selected from the group consisting of acrylates, methacrylates, acrylic anhydrides, ethylenically unsaturated anhydrides, olefinic compounds, acrylamides, ethylenically unsaturated amides and urethanes, vinyl esters, vinyl ethers, vinyl halides, vinyl epoxy resins, vinyl silanes, vinyl siloxanes, vinyl heterocycles, melamines, poly(ethylenically unsaturated alkoxyalkyl) compounds, blends, polymers, and copolymers thereof.

Claim 4

A lens according to claim 2 wherein said material containing reactive ethylenically groups is a poly(ethylenically unsaturated alkoxyalkyl) compound of the formula A 1 --Z--A 2 wherein (a) A 1 and A 2 are independently groups having terminal ethylenic unsaturation said groups having the formula: ##STR20## in which (1) R 1 is selected from hydrogen or methyl (2) R--O-- is a monovalent residue of an aliphatic terminally unsaturated primary alcohol, ROH, where R is selected from the formulae ##STR21## wherein E is selected from the formulae ##STR22## a and c are independently integers of from 1 to 6, b is zero or an integer of from 1 to 6, R 4 is selected from hydrogen or methyl, R 5 is an aliphatic group having 1 to 15 carbon atoms which may be interrupted with up to two groups selected from the class consisting of ether oxygen or ##STR23## R 5 having a valence of m+1 wherein m is an integer of 1 to 5, (3) R 2 is selected from the group of hydrogen, ##STR24## wherein R 6 is selected from alkyl and alkenyl groups having up to 5 carbon atoms, R 7 is an aliphatic group of up to 8 carbon atoms or an aromatic group of up to 8 carbon atoms, (4) R 3 is an alkylene group having 1 to 6 carbon atoms and up to one catenary oxygen in the group, and (b) Z is a heterocyclic group of the formula: ##STR25## wherein X is a divalent group required to complete a 5-membered heterocyclic ring and is selected from the group of ##STR26## wherein R 8 , R 9 , R 10 , and R 11 are independently selected from hydrogen, alkyl groups of 1 to 4 carbon atoms, cycloalkyl groups of 3 to 6 carbon atoms, and phenyl groups, and A 3 is the same as A 1 .

Claim 5

A lens according to claim 2 wherein said composition further includes a reaction initiator.

Claim 6

A lens according to claim 2 wherein said composition further includes one or more materials selected from the group consisting of polymers, stabilizers, antioxidants, flexibilizers, colorants, fillers, surfactants, flow aids, and hardness enhancers.

Claim 7

A lens according to claim 1 wherein said ophthalmic lens comprises a spectacle lens.

Claim 8

A lens according to claim 1 wherein said coating is chemically bonded to said substrate.

Claim 9

An ophthalmic lens according to claim 1 wherein said spectacle lens provides corrective refraction of light passing therethrough.

Claim 10

A lens according to claim 8 wherein said spectable lens comprises a multifocal spectacle lens.

Claim 11

A curved ophthalmic lens for correction of vision comprising an optically clear, solid, room temperature stable substrate bearing an aberration-free coating which provides an optical surface which comprises essentially exactly the positive replicate of a lens mold and which has an SEB abrasion resistance of at least 20 psi, which coating comprises the polymerization product of a composition containing reactive ethylenically unsaturated groups, and which has an adhesion of at least 90% to said substrate when tested according to ASTM D-3359.

Claim 12

A curved ophthalmic lens for correction of vision comprising an optically clear, solid, room temperature stable substrate bearing an aberration-free coating which provides an optical surface which comprises essentially exactly the positive replicate of a lens mold and which has an SEB abrasion resistance of at least 20 psi, which coating comprises the polymerization product of a composition containing reactive ethylenically unsaturated groups, and which has an adhesion of at least 90% to said substrate when tested according to ASTM D-3359.

Claim 13

A lens according to claim 9 having a segment line thereon.