US4756846A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Alkaline tin-plate degreasing detergent
Assignee: Henkel Corp
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Filing: 1987-03-09
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Granted: 1988-07-12
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Expires: 2007-03-09
Abstract
Abstract A degreasing detergent composition for tin surfaces and a method for its use, wherein the composition is an aqueous solution having a pH of 9 to 13 and containing at least one surfactant, at least one alkali metal detergent builder, and at least an alkaline earth metal salt at a concentration of at least 0.003 g/l.
Inventors
- 👤 Yasuo Matsuura
- 👤 Kiyotada Yasuhara
- 👤 Satoshi Ikeda
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 17:57
CPC Classifications
C; C11; C11D; C11D3/00; C11D3/02; C11D3/04; C11D3/046; C23; C23G; C23G1/00; C23G1/14; C23G1/20
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
131 words
In a degreasing and cleaning detergent composition for a tin surface containing at least one organic, syntactic, anionic, nonionic, cationic, or amphoteric surfactant; at least one inorganic alkali metal detergent builder; and water; the improvement comprising the incorporation of at least one inorganic alkaline earth metal salt selected from the group consisting of calcium carbonate, calcium hydroxide, calcium nitrate, magnesium carbonate, magnesium hydroxide, magnesium nitrate, and mixtures thereof in a concentration of between about 0.003 grams per liter and about 0.030 grams per liter of detergent as measured by the alkaline earth metal cations, and the adjustment of said composition to a ph of 9 to 13, said composition being effective to remove contaminant oil and oxide film from said tin surface without causing excessive dissolution of tin from said surface.
Claim 2
Dependent Claim
131 words
In a degreasing and cleaning detergent composition for a tin surface containing at least one organic, syntactic, anionic, nonionic, cationic, or amphoteric surfactant; at least one inorganic alkali metal detergent builder; and water; the improvement comprising the incorporation of at least one inorganic alkaline earth metal salt selected from the group consisting of calcium carbonate, calcium hydroxide, calcium nitrate, magnesium carbonate, magnesium hydroxide, magnesium nitrate, and mixtures thereof in a concentration of between about 0.003 grams per liter and about 0.030 grams per liter of detergent as measured by the alkaline earth metal cations, and the adjustment of said composition to a ph of 9 to 13, said composition being effective to remove contaminant oil and oxide film from said tin surface without causing excessive dissolution of tin from said surface.
Claim 3
Dependent Claim
14 words
The composition of claim 1 wherein each said at least one surfactant is nonionic.
Claim 4
Dependent Claim
14 words
The composition of claim 1 wherein said surfactant is present in about 0.1-10 g/l.
Claim 5
Dependent Claim
14 words
The composition of claim 3 wherein said surfactant is present in about 0.1-10 g/l.
Claim 6
Dependent Claim
39 words
The composition of claim 1 wherein said surfactant is at least one: polyoxyethylene alkylaryl ether, polyoxyethylene alkyl ether, block copolymer of propylene oxide and ethylene oxide, block copolymer of propylene oxide and propylene glycol, or any of their mixture.
Claim 7
Dependent Claim
14 words
The composition of claim 5 wherein said surfactant is present in about 0.5-2 g/l.
Claim 8
Dependent Claim
26 words
The composition of claim 1 wherein said alkali metal detergent builder is at least one alkali metal hydroxide, carbonate, hydrogen carbonate, silicate, phosphate, or condensed phosphate.
Claim 9
Dependent Claim
136 words
In a method for degreasing and cleaning a tin surface by applying a degreasing effective non-etching amount of a detergent composition comprising an aqueous solution of at least one organic synthetic anionic, nonionic, cationic, or amphoteric surfactant, and at least one inorganic detergent builder, the improvement comprising adding thereto at least one inorganic alkaline earth metal salt selected from the group consisting of calcium carbonate, calcium hydroxide, calcium nitrate, magnesium carbonate, magnesium hydroxide, magnesium nitrate, and mixtures thereof in a concentration of between about 0.003 grams per liter and about 0.030 grams per liter of detergent, as measured by the alkaline earth metal cations, and adjusting the ph of said composition to between 9 and 13, thereby removing contaminant oil and oxide film from said tin surface without causing excessive dissolution of tin from said surface.
Claim 10
Dependent Claim
136 words
In a method for degreasing and cleaning a tin surface by applying a degreasing effective non-etching amount of a detergent composition comprising an aqueous solution of at least one organic synthetic anionic, nonionic, cationic, or amphoteric surfactant, and at least one inorganic detergent builder, the improvement comprising adding thereto at least one inorganic alkaline earth metal salt selected from the group consisting of calcium carbonate, calcium hydroxide, calcium nitrate, magnesium carbonate, magnesium hydroxide, magnesium nitrate, and mixtures thereof in a concentration of between about 0.003 grams per liter and about 0.030 grams per liter of detergent, as measured by the alkaline earth metal cations, and adjusting the ph of said composition to between 9 and 13, thereby removing contaminant oil and oxide film from said tin surface without causing excessive dissolution of tin from said surface.
Claim 11
Dependent Claim
16 words
The method of claim 8 wherein said application is at a temperature of about 40°-80° C.
Claim 12
Dependent Claim
21 words
The method of claim 8 wherein said application is by immersion for a time of about 20 seconds to 2 minutes.
Claim 13
Dependent Claim
21 words
The method of claim 8 wherein said application is by spraying for a time of about 30 seconds to 2 minutes.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1991-07-12 | 1992-01-11 | 1992-07-12 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1995-07-12 | 1996-01-11 | 1996-07-12 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1999-07-12 | 2000-01-11 | 2000-07-12 | $7700.00 | Window Closed / Lapsed |