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US4756000A Expired / Lapsed US ⏱️ 0.0 years remaining

Discharge driven gold catalyst with application to a CO2 laser

Assignee: MACKEN LASER Inc A CA Corp
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Filing: 1987-02-18
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Granted: 1988-07-05
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Expires: 2007-02-18
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Abstract

Abstract A device and process using a gold as a catalyst for oxidizing carbon monoxide to form CO 2 at ambient temperatures. This has particular application to CO 2 lasers. In one CO 2 laser embodiment, gold is distributed on the walls of the discharge volume. The gold is divided to form electrically isolated islands to prevent interference with the discharge. Energetic forms of oxygen, such as atomic oxygen reacts with CO on the gold catalyst. In another embodiment, the gold catalyst is used in a convective flow laser.

Inventors

  • 👤 John A. Macken

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 19:06
CPC Classifications
H; H01; H01S; H01S3/00; H01S3/02; H01S3/03; H01S3/036

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 106 words
A CO 2 laser device including a closed envelope containing a CO 2 laser gas mixture and laser amplification volume, said amplification volume including an electrical discharge through said CO 2 laser gas mixture, said discharge causing decomposition of CO 2 in said mixture to form carbon monoxide, oxygen, and energetic forms of oxygen, the improved feature comprising: inside said envelope there is at least one surface coated with gold; said gold surface is positioned and configured as to promote contact with both said carbon monoxide and said energetic forms of oxygen generated in said amplification volume for purposes of catalizing formation of CO 2 .
Claim 2
Dependent Claim 106 words
A CO 2 laser device including a closed envelope containing a CO 2 laser gas mixture and laser amplification volume, said amplification volume including an electrical discharge through said CO 2 laser gas mixture, said discharge causing decomposition of CO 2 in said mixture to form carbon monoxide, oxygen, and energetic forms of oxygen, the improved feature comprising: inside said envelope there is at least one surface coated with gold; said gold surface is positioned and configured as to promote contact with both said carbon monoxide and said energetic forms of oxygen generated in said amplification volume for purposes of catalizing formation of CO 2 .
Claim 3
Dependent Claim 63 words
The combination according to claim 1 wherein the said gold catalyst is on at least a portion of the wall area facing said amplification volume, said gold is distributed over a sufficiently broad area of said well area so as to promote the catalytic formation of CO 2 in at least a substantial portion of said laser gas mixture in said amplification volume.
Claim 4
Dependent Claim 33 words
The combination according to claim 2 where said gold catalyst is supported by a dielectric material and where said gold catalyst forms multiple, generally microscopic regions which are electrically insulated from each other.
Claim 5
Dependent Claim 25 words
The combination according to claim 2 where said gold catalyst has been divided into multiple, generally macroscopic, regions which are electrically insulated from each other.
Claim 6
Dependent Claim 15 words
The combination according to claim 1 wherein said gold catalyst and said electrode are different.
Claim 7
Dependent Claim 20 words
The combination according to claim 5 wherein the said gold catalyst functions independently as part of a laser resonator reflector.
Claim 8
Dependent Claim 106 words
The combination according to claim 1 wherein said CO 2 laser device has said gas mixture rapidly flowing through said amplification volume and where said gold coated surface is a relatively large surface area structure designed to make intimate contact with said flowing gas and positioned sufficiently close to the gas exhaust end of said amplification volume to be contacted by a substantial amount of said energetic oxygen. Further, in operation, said gold catalyzes the formation of CO 2 to the extent that there is a substantial reduction in the total molecular oxygen in the amplification volume compared to the oxygen content without said gold coating.
Claim 9
Dependent Claim 64 words
In a method for converting carbon monoxide and oxygen to CO 2 the steps in no particular order comprising: provide a means for forming at least one energetic form of oxygen; provide a gold coated surface positioned so as to promote contact with both said carbon monoxide and said energetic form of oxygen for the purposes of making catalytic formation of CO 2 .
Claim 10
Dependent Claim 64 words
In a method for converting carbon monoxide and oxygen to CO 2 the steps in no particular order comprising: provide a means for forming at least one energetic form of oxygen; provide a gold coated surface positioned so as to promote contact with both said carbon monoxide and said energetic form of oxygen for the purposes of making catalytic formation of CO 2 .
Claim 11
Dependent Claim 56 words
The method of claim 8 where the step of providing a means for forming at least one energetic form of oxygen includes the step of providing energy to a source of oxygen, said energy means selected from the group consisting of: an electrical discharge, electromagnetic radiation shorter than 3000 Angstroms wavelength, or rapidly moving subatomic particles.
Claim 12
Dependent Claim 24 words
The method of claim 9 where the step of providing an energy source includes providing an electric discharge in a CO 2 laser device.
Claim 13
Dependent Claim 42 words
The method of claim 8 where the step of providing a gold coated surface includes supporting said gold surface with a dielectric material and also dividing said gold surface in such a way as to form multiple electrically insulated islands of gold.

References Cited (Backward Citations)

GB1256398A Cited
GB2028571A Cited
US4639926A Cited
GB2083944A Cited
US4651324A Cited
US4617668A Cited
US4641313A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-07-05 1992-01-04 1992-07-05 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-07-05 1996-01-04 1996-07-05 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-07-05 2000-01-04 2000-07-05 $7700.00 Window Closed / Lapsed

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