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US4752604A Expired / Lapsed US ⏱️ 0.0 years remaining

S,S-di-(tertiary alkyl) thiophosphonate insecticides

Assignee: Zeneca Inc
•
Filing: 1986-07-03
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Granted: 1988-06-21
•
Expires: 2006-07-03
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Abstract

Abstract Compounds having the formula ##STR1## in which R is methyl or ethyl, Y is sulfur or oxygen, and R 1 and R 2 are the same or different tertiary alkyl groups each having from 4 to 6 carbon atoms, are insecticides and nematicides, especially for control of soil insects and nematodes. Symmetrical compounds (R 1 ═R 2 ) may be prepared by reaction of an alkali metal mercaptide with an alkyl (thio) phosphonic dihalide. The alkali metal mercaptide may be prepared by reaction of a tertiary alkyl mercaptan with an alkali metal or alkali metal hydride.

Inventors

  • 👤 Charles G. Chavdarian
  • 👤 Lydia L. Chang
  • 👤 Bruce C. Onisko
  • 👤 Jonathan P. Earhart

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 23:35
CPC Classifications
C; C07; C07F; C07F9/00; C07F9/02; C07F9/28; C07F9/38; C07F9/40; A; A01; A01N; A01N57/00; A01N57/18; A01N57/20; C07F9/4071; C07F9/4075

Claims Analysis

Total Claims: 34
Claim 1
Independent Claim 31 words
A compound having the formula ##STR6## in which R is methyl or ethyl, and R 1 and R 2 are tertiary alkyl groups each having from 4 to 6 carbon atoms.
Claim 2
Dependent Claim 31 words
A compound having the formula ##STR6## in which R is methyl or ethyl, and R 1 and R 2 are tertiary alkyl groups each having from 4 to 6 carbon atoms.
Claim 3
Dependent Claim 30 words
A method of controlling insects comprising applying to said insect or to a locus at which control is desired an insecticidally effective amount of a compound according to claim 1.
Claim 4
Dependent Claim 25 words
A method of controlling insects according to claim 2 in which the compound is applied to soil to control insects which may be present therein.
Claim 5
Dependent Claim 32 words
A compound having the formula ##STR7## in which R is methyl or ethyl, and R 1 and R 2 are identical tertiary alkyl groups each having from 4 to 6 carbon atoms.
Claim 6
Dependent Claim 32 words
A compound having the formula ##STR7## in which R is methyl or ethyl, and R 1 and R 2 are identical tertiary alkyl groups each having from 4 to 6 carbon atoms.
Claim 7
Dependent Claim 13 words
A compound having the formula ##STR8## in which R is methyl or ethyl.
Claim 8
Dependent Claim 13 words
A compound having the formula ##STR8## in which R is methyl or ethyl.
Claim 9
Dependent Claim 6 words
A compound having the formula ##STR9##
Claim 10
Dependent Claim 6 words
A compound having the formula ##STR9##
Claim 11
Dependent Claim 6 words
A compound having the formula ##STR10##
Claim 12
Dependent Claim 6 words
A compound having the formula ##STR10##
Claim 13
Dependent Claim 31 words
A compound having the formula ##STR11## in which R is methyl or ethyl and R 1 and R 2 are tertiary alkyl groups each having from 5 to 6 carbon atoms.
Claim 14
Dependent Claim 31 words
A compound having the formula ##STR11## in which R is methyl or ethyl and R 1 and R 2 are tertiary alkyl groups each having from 5 to 6 carbon atoms.
Claim 15
Dependent Claim 30 words
A method of controlling insects comprising applying to said insect or to a locus at which control is desired an insecticidally effective amount of a compound according to claim 4.
Claim 16
Dependent Claim 25 words
A method of controlling insects according to claim 9 in which the compound is applied to soil to control insects which may be present therein.
Claim 17
Dependent Claim 30 words
A method of controlling insects comprising applying to said insect or to a locus at which control is desired as insecticidally effective amount of a compound according to claim 5.
Claim 18
Dependent Claim 25 words
A method of controlling insects according to claim 11 in which the compound is applied to soil to control insects which may be present therein.
Claim 19
Dependent Claim 30 words
A method of controlling insects comprising applying to said insect or to a locus at which control is desired an insecticidally effective amount of a compound according to claim 6.
Claim 20
Dependent Claim 25 words
A method of controlling insects according to claim 13 in which the compound is applied to soil to control insects which may be present therein.
Claim 21
Dependent Claim 30 words
A method of controlling insects comprising applying to said insect or to a locus at which control is desired an insecticidally effective amount of a compound according to claim 7.
Claim 22
Dependent Claim 25 words
A method of controlling insects according to claim 15 in which the compound is applied to soil to control insects which may be present therein.
Claim 23
Dependent Claim 30 words
A method of controlling insects comprising applying to such insect to or a locus at which control is desired an insecticidally effective amount of a compound according to claim 8.
Claim 24
Dependent Claim 25 words
A method of controlling insects according to claim 17 in which the compound is applied to soil to control insects which may be present therein.
Claim 25
Dependent Claim 32 words
A method for controlling root knot nematodes comprising applying to said nematode or to a locus at which control is desired a nematocidally effective amount of a compound according to claim 1.
Claim 26
Dependent Claim 32 words
A method for controlling root knot nematodes comprising applying to said nematode or to a locus at which control is desired a nematocidally effective amount of a compound according to claim 5.
Claim 27
Dependent Claim 32 words
A method for controlling root knot nematodes comprising applying to said nematode or to a locus at which control is desired a nematocidally effective amount of a compound according to claim 6.
Claim 28
Dependent Claim 32 words
A method for controlling root knot nematodes comprising applying to said nematode or to a locus at which control is desired a nematocidally effective amount of a compound according to claim 7.
Claim 29
Dependent Claim 32 words
An insecticidal or nematocidal composition of matter comprising: (a) an insecticidally or nematocidally effective amount of a compound according to claim 1; and (b) an insecticidally or nematocidally suitable diluent or carrier.
Claim 30
Dependent Claim 32 words
An insecticidal or nematocidal composition of matter comprising: (a) an insecticidally or nematocidally effective amount of a compound according to claim 9; and (b) an insecticidally or nematocidally suitable diluent or carrier.
Claim 31
Dependent Claim 32 words
An insecticidal or nematocidal composition of matter comprising: (a) an insecticidally or nematocidally effective amount of a compound according to claim 5; and (b) an insecticidally or nematocidally suitable diluent or carrier.
Claim 32
Dependent Claim 32 words
An insecticidal or nematocidal composition of matter comprising: (a) an insecticidally or nematocidally effective amount of a compound according to claim 6; and (b) an insecticidally or nematocidally suitable diluent or carrier.
Claim 33
Dependent Claim 32 words
An insecticidal or nematocidal composition of matter comprising: (a) an insecticidally or nematocidally effective amount of a compound according to claim 7; and (b) an insecticidally or nematocidally suitable diluent or carrier.
Claim 34
Dependent Claim 32 words
An insecticidal or nematocidal composition of matter comprising: (a) an insecticidally or nematocidally effective amount of a compound according to claim 8; and (b) an insecticidally or nematocidally suitable diluent or carrier.

References Cited (Backward Citations)

US3094405A Cited
EP0210608A1 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-06-21 1991-12-21 1992-06-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-06-21 1995-12-21 1996-06-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-06-21 1999-12-21 2000-06-21 $7700.00 Window Closed / Lapsed

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