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US4752341A Expired / Lapsed US ⏱️ 0.0 years remaining

Pigment system for paper

Assignee: PQ Corp
•
Filing: 1987-06-01
•
Granted: 1988-06-21
•
Expires: 2007-06-01
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Abstract

Abstract Zeolite of a small controlled particle size has been found to be a pigment component to be used with TiO 2 in papermaking. Zeolite A wherein the sodium has been at least partially replaced with calcium and/or hydronium ion is widely useful with TiO 2 in papermaking.

Inventors

  • 👤 Steven L. Rock

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 00:23
CPC Classifications
D; D21; D21H; D21H17/00; D21H17/63; D21H17/67; D21H17/675; D21H17/68

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 31 words
A pigment system for paper comprising: titanium dioxide (TiO 2 ) and zeolite of less than 3 micron average particle size and an average crystal size of less than 1 micron.
Claim 2
Dependent Claim 31 words
A pigment system for paper comprising: titanium dioxide (TiO 2 ) and zeolite of less than 3 micron average particle size and an average crystal size of less than 1 micron.
Claim 3
Dependent Claim 27 words
The pigment system of claim 1 wherein there is 10 to 90% by weight of the TiO 2 and 90 to 10% by weight of the zeolite.
Claim 4
Dependent Claim 29 words
The pigment system of claim 1 wherein the zeolite has an average particle size of 1.5 to 2.5 microns and an average crystal size of 0.2 to 0.8 microns.
Claim 5
Dependent Claim 33 words
The pigment system of claim 2 wherein the zeolite is Zeolite A which has an average particle size of 1.5 to 2.5 microns and an average crystal size of 0.2 to 0.8 microns.
Claim 6
Dependent Claim 33 words
The pigment system of claim 1 wherein the zeolite has the following composition: Zeolite (Ca.sub.x Na.sub.12-x/2)A zH.sub.2 O wherein x can be up to about 4.8 and z can be 20 to 27.
Claim 7
Dependent Claim 33 words
The pigment system of claim 2 wherein the zeolite has the following composition: Zeolite (Ca.sub.x Na.sub.12-x/2)A zH.sub.2 O wherein x can be about 0.3 to 3.6 and z can be 20 to 27.
Claim 8
Dependent Claim 33 words
The pigment system of claim 3 wherein the zeolite has the following composition: Zeolite (Ca.sub.x Na.sub.12-x/2)A zH.sub.2 O wherein x can be about 0.3 to 3.6 and z can be 20 to 27.
Claim 9
Dependent Claim 33 words
The pigment system of claim 4 wherein the zeolite has the following composition: Zeolite (Ca.sub.x Na.sub.12-x/2)A zH.sub.2 O wherein x can be about 0.3 to 3.6 and z can be 20 to 27.
Claim 10
Dependent Claim 39 words
The pigment system of claim 1 wherein the zeolite has the following composition: Zeolite [Ca.sub.x Na.sub.12-(x/2+y) Hy] zH.sub.2 O wherein x can be 0 to about 4.8, y is about 0.6 to 2.5 and z is 20 to 27.
Claim 11
Dependent Claim 39 words
The pigment system of claim 2 wherein the zeolite has the following composition: Zeolite [Ca.sub.x Na.sub.12-(x/2+y) Hy] zH.sub.2 O wherein x can be 0 to about 4.8, y is about 0.6 to 2.5 and z is 20 to 27.
Claim 12
Dependent Claim 39 words
The pigment system of claim 3 wherein the zeolite has the following composition: Zeolite [Ca.sub.x Na.sub.12-(x/2+y) Hy] zH.sub.2 O wherein x can be 0 to about 4.8, y is about 0.6 to 2.5 and z is 20 to 27.
Claim 13
Dependent Claim 39 words
The pigment system of claim 4 wherein the zeolite has the following composition: Zeolite [Ca.sub.x Na.sub.12-(x/2+y) Hy] zH.sub.2 O wherein x can be 0 to about 4.8, y is about 0.6 to 2.5 and z is 20 to 27.

References Cited (Backward Citations)

US3658566A Cited
US4199370A Cited
US4227935A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-06-21 1991-12-21 1992-06-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-06-21 1995-12-21 1996-06-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-06-21 1999-12-21 2000-06-21 $7700.00 Window Closed / Lapsed

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