Conversion of solid dicyclopentadiene to a liquid monomer for use in reaction injection molding

Claim 1

A method of preparing a methathesispolymerizable liquid mixture containing predominantly dicylopentadiene which comprises subjecting dicylcopentadiene to a heat treatment at about 125° C. to 250° C. in the substantial absence of air under conditions wherein pyrolysis products are prevented from escaping from the reaction and cyclopentadiene oligomers are formed, continuing the heating until the cyclopentadiene oligmer content is about 5 to 30% by weight of the total weight of dicyclopentadiene plus oligomers and spearating residual cyclopentadiene and low molecular weight pyrolysis products from the dicyclopentadiene and oligmer mixture thereby recovering dicyclopentadiene and oligomers which can be polymerized under the influence of a metathesis catalyst system in about 30 seconds or less to form a crosslinked thermoset polymer.

Claim 2

A method of preparing a methathesispolymerizable liquid mixture containing predominantly dicylopentadiene which comprises subjecting dicylcopentadiene to a heat treatment at about 125° C. to 250° C. in the substantial absence of air under conditions wherein pyrolysis products are prevented from escaping from the reaction and cyclopentadiene oligomers are formed, continuing the heating until the cyclopentadiene oligmer content is about 5 to 30% by weight of the total weight of dicyclopentadiene plus oligomers and spearating residual cyclopentadiene and low molecular weight pyrolysis products from the dicyclopentadiene and oligmer mixture thereby recovering dicyclopentadiene and oligomers which can be polymerized under the influence of a metathesis catalyst system in about 30 seconds or less to form a crosslinked thermoset polymer.