US4751273A
Expired / Lapsed
US
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Vinyl ether terminated urethane resins
Assignee: Honeywell International Inc
•
Filing: 1987-07-06
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Granted: 1988-06-14
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Expires: 2007-07-06
Abstract
Abstract Vinyl ether terminated urethane resins may be prepared by reacting the product obtained by the addition of acetylene to an organic polyol with an isocyanate-containing compound at temperatures ranging from about ambient to about 125° C. The thus prepared resin may then be cured by irradiation from an electron beam, thermally or by exposure to an ultraviolet light to cure the resin and form a coating material.
Inventors
- 👤 Stephen C. Lapin
- 👤 David W. House
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 14:00
CPC Classifications
C; C08; C08F; C08F299/00; C08F299/02; C08F299/06; C08F299/065; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/67; C08G18/671; C08G18/6715
Claims Analysis
Total Claims: 39
Claim 1
Independent Claim
43 words
A vinyl ether terminated urethane resin having the generic formula: ##STR7## in which R and R' are independently selected from the group consisting of alkyl, aryl, alkaryl, aralkyl, cycloalkyl and alkyl oxide radicals and n is an integer of from 1 to 4.
Claim 2
Dependent Claim
43 words
A vinyl ether terminated urethane resin having the generic formula: ##STR7## in which R and R' are independently selected from the group consisting of alkyl, aryl, alkaryl, aralkyl, cycloalkyl and alkyl oxide radicals and n is an integer of from 1 to 4.
Claim 3
Dependent Claim
30 words
The vinyl ether terminated urethane resin as set forth in claim 1 in which said resin possesses a molecular weight in the range of from about 240 to about 10,000.
Claim 4
Dependent Claim
21 words
The vinyl ether terminated urethane resin as set forth in claim 1 in which R is methylene and R' is tolyl.
Claim 5
Dependent Claim
21 words
The vinyl ether terminated urethane resin as set forth in claim 1 in which R is ethylene and R' is tolyl.
Claim 6
Dependent Claim
21 words
The vinyl ether terminated urethane resin as set forth in claim 1 in which R is ethylene and R' is diphenyl-methylene.
Claim 7
Dependent Claim
21 words
The vinyl ether terminated urethane resin as set forth in claim 1 in which R is n-hexylene and R' is dicyclohexylmethylene.
Claim 8
Dependent Claim
21 words
The vinyl ether terminated urethane resin as set forth in claim 1 in which R is n-butylene and R' is tolyl.
Claim 9
Dependent Claim
43 words
A process for the preparation of a vinyl ether terminated urethane resin which comprises reacting the product obtained by the addition of acetylene to an organic polyol with an isocyanate-containing compound at reaction conditions, and recovering the resultant vinyl ether terminated urethane resin.
Claim 10
Dependent Claim
43 words
A process for the preparation of a vinyl ether terminated urethane resin which comprises reacting the product obtained by the addition of acetylene to an organic polyol with an isocyanate-containing compound at reaction conditions, and recovering the resultant vinyl ether terminated urethane resin.
Claim 11
Dependent Claim
31 words
The process as set forth in claim 8 in which said reaction conditions include a temperature in the range of from about ambient to about 125° C. and about atmospheric pressure.
Claim 12
Dependent Claim
21 words
The process as set forth in claim 8 in which said reaction is effected in the presence of a tin-containing catalyst.
Claim 13
Dependent Claim
16 words
The process as set forth in claim 10 in which said tin-containing catalyst is dibutyltin dilaurate.
Claim 14
Dependent Claim
32 words
The process as set forth in claim 8 in which said organic polyol comprises triethylene glycol and said isocyanate containing compound comprises 2,4-toluene diisocyanate or a mixture of 2,4- and 2,6-toluene diisocyanate.
Claim 15
Dependent Claim
23 words
The process as set forth in claim 8 in which said organic polyol comprises triethylene glycol and said isocyanate compound is diphenylmethane diisocyanate.
Claim 16
Dependent Claim
23 words
The process as set forth in claim 8 in which said organic polyol comprises triethylene glycol and said isocyanate compound is dicyclohexylmethane diisocyanate.
Claim 17
Dependent Claim
31 words
The process as set forth in claim 8 in which said organic polyol comprises diethylene glycol and said isocyanate compound is 2,4-toluene diisocyanate or a mixture of 2,4- and 2,6-toluene diisocyanate.
Claim 18
Dependent Claim
22 words
The process as set forth in claim 8 in which said organic polyol comprises 1,6-hexanediol and said isocyanate compound is dicyclohexylmethane diisocyanate.
Claim 19
Dependent Claim
60 words
A polymeric material that results from curing a vinyl ether terminated resin having the generic formula: ##STR8## in which R and R' are independently selected from the group consisting of alkyl, aryl, alkaryl, aralkyl, cycloalkyl and alkyl oxide radicals and n is an integer of from 1 to 4 which has been cured by a curing treatment at curing conditions.
Claim 20
Dependent Claim
60 words
A polymeric material that results from curing a vinyl ether terminated resin having the generic formula: ##STR8## in which R and R' are independently selected from the group consisting of alkyl, aryl, alkaryl, aralkyl, cycloalkyl and alkyl oxide radicals and n is an integer of from 1 to 4 which has been cured by a curing treatment at curing conditions.
Claim 21
Dependent Claim
24 words
The polymeric material as set forth in claim 17 in which said curing treatment comprises an irradiation of said resin from an electron beam.
Claim 22
Dependent Claim
30 words
The polymeric material as set forth in claim 18 in which the energy dosage from said electron beam is in a range of from about 0.1 to about 10.0 Mrads.
Claim 23
Dependent Claim
22 words
The polymeric material as set forth in claim 18 in which said irradiation is effected in the presence of an onium salt.
Claim 24
Dependent Claim
21 words
The polymeric material as set forth in claim 17 in which said curing treatment comprises exposure to an ultraviolet light source.
Claim 25
Dependent Claim
27 words
The polymeric material as set forth in claim 21 in which said exposure to said ultraviolet light source is effected in the presence of an aryl-onium salt.
Claim 26
Dependent Claim
33 words
The polymeric material as set forth in claim 17 in which said curing is effected by thermal treatment at an elevated temperature in the presence of an or acid organic an onium salt.
Claim 27
Dependent Claim
18 words
The polymeric material as set forth in claim 17 in which R is methylene and R' is tolyl.
Claim 28
Dependent Claim
18 words
The polymeric material as set forth in claim 17 in which R is ethylene and R' is tolyl.
Claim 29
Dependent Claim
19 words
The polymeric material as set forth in claim 17 in which R is ethylene and R' is diphenyl methyl.
Claim 30
Dependent Claim
18 words
The polymeric material as set forth in claim 17 in which R is n-hexylene and R' is dicyclohexylmethyl.
Claim 31
Dependent Claim
18 words
The polymeric material as set forth in claim 17 in which R is n-butylene and R' is tolyl.
Claim 32
Independent Claim
66 words
A method for obtaining a tack-free coating which comprises subjecting a vinyl ether terminated urethane resin having the generic formula: ##STR9## in which R and R' are independently selected from the group consisting of alkyl, aryl, alkaryl, aralkyl, cycloalkyl and alkyl oxide radicals and n is an integer of from 1 to 4 to a curing treatment at curing conditions, and recovering the resultant tack-free coating.
Claim 33
Independent Claim
66 words
A method for obtaining a tack-free coating which comprises subjecting a vinyl ether terminated urethane resin having the generic formula: ##STR9## in which R and R' are independently selected from the group consisting of alkyl, aryl, alkaryl, aralkyl, cycloalkyl and alkyl oxide radicals and n is an integer of from 1 to 4 to a curing treatment at curing conditions, and recovering the resultant tack-free coating.
Claim 34
Dependent Claim
50 words
The method as set forth in claim 29 in which said curing treatment comprises irradiation of said resin from an electron beam in which the energy dosage from said electron beam is in a range of from about 0.1 to about 10.0 Mrads in the presence of an onium salt.
Claim 35
Dependent Claim
27 words
The method as set forth in claim 29 in which said curing treatment comprises exposure to an ultraviolet light source in the presence of an aryl-onium salt.
Claim 36
Dependent Claim
34 words
The method as set forth in claim 29 in which said curing treatment is effected by a thermal treatment at an elevated temperature in the presence of an organic acid or an onium salt.
Claim 37
Dependent Claim
15 words
The vinyl ether terminated urethane resin of claim 1 in which R is 1,4-cyclohexane dimethanol.
Claim 38
Dependent Claim
13 words
The process of claim 8 in which said organic polyol comprises 1,4-cyclohexane dimethanol.
Claim 39
Dependent Claim
12 words
The polymeric material of claim 17 in which R is 1,4-cyclohexane dimethanol.
References Cited (Backward Citations)
US3928287A
Cited
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| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1991-06-14 | 1991-12-14 | 1992-06-14 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1995-06-14 | 1995-12-14 | 1996-06-14 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1999-06-14 | 1999-12-14 | 2000-06-14 | $7700.00 | Window Closed / Lapsed |