US4749772A
Expired / Lapsed
US
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Condensation copolymers containing methine ultraviolet radiation-absorbing residues and shaped articles produced therefrom
Assignee: Eastman Chemical Co
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Filing: 1987-07-20
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Granted: 1988-06-07
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Expires: 2007-07-20
Abstract
Abstract A composition useful for molding into articles such as food containers, soft drink bottles, cured structural plastics and the like, comprising molding or fiber grade linear or unsaturated polyester or polycarbonate having copolymerized therein a total of from 1.0 to about 5,000 ppm, of the residue of one or a mixture of methine reactants of the formula <IMAGE> wherein A is an unsubstituted or substituted 2-furanyl, 2-thienyl or 3-thienyl radical; R1 is hydrogen or a unsubstituted or substituted alkyl, cycloalkyl or aryl radical; and R2 is hydrogen or an unsubstituted or substituted alkyl, alkenyl, cycloalkyl or aryl radical. The methine residues are present in the polymer as an integral part of the polymer chain and absorb ultraviolet radiation in the range of about 150 to about 390 nm. The residues are non-extractable from the polymer and stable at the conditions at which the polymers are manufactured and processed.
Inventors
- 👤 Max A. Weaver
- 👤 Wayne P. Pruett
- 👤 Samuel D. Hilbert
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-31 19:08
CPC Classifications
C; C07; C07D; C07D307/00; C07D307/02; C07D307/34; C07D307/56; C07D307/38; C07D307/54; C07D307/58; C07D307/64; C07D333/00; C07D333/02; C07D333/04; C07D333/06; C07D333/24; C07D333/26; C07D333/28; C07D333/30; C07D333/32; C07D333/34; C08; C08G; C08G63/00; C08G63/68; C08G63/685; C08G63/688; C08G63/91
Claims Analysis
Total Claims: 20
Claim 1
Independent Claim
78 words
A composition comprising molding or fiber grade condensation polymer having copolymerized therein a total of from 1.0 to abut 10,000 ppm, of the residue of one or a mixture of methine compounds of the formula ##STR21## wherein A is an unsubstituted or substituted 2-furanyl, 2-thienyl or 3-thienyl radical; R 1 is hydrogen or an unsubstituted or substituted alkyl, cycloalkyl or aryl radical; and R 2 is hydrogen or an unsubstituted or substituted alkyl, alkenyl, cycloalkyl or aryl radical.
Claim 2
Dependent Claim
78 words
A composition comprising molding or fiber grade condensation polymer having copolymerized therein a total of from 1.0 to abut 10,000 ppm, of the residue of one or a mixture of methine compounds of the formula ##STR21## wherein A is an unsubstituted or substituted 2-furanyl, 2-thienyl or 3-thienyl radical; R 1 is hydrogen or an unsubstituted or substituted alkyl, cycloalkyl or aryl radical; and R 2 is hydrogen or an unsubstituted or substituted alkyl, alkenyl, cycloalkyl or aryl radical.
Claim 3
Dependent Claim
49 words
The composition of claim 1 wherein the polymer is a linear polyester and A is a 2-furanyl radical having the structure ##STR22## wherein R 3 is alkyl, hydroxyalkyl, alkoxyalkyl, alkanoyloxyalkyl, arylalkyl, cycloalkylalkyl, aryloxyalkyl, cycloalkoxyalkyl, alkylthioalkyl, arylthioalkyl, alkenyl, alkoxy, cycloalkyl, aryl or halogen; and n is 0, 1 or 2.
Claim 4
Dependent Claim
42 words
The composition of claim 1 wherein the polymer is a linear polyester having copolymerized therein about 200 to about 800 ppm of the residue of one or a mixture of methine compounds of the formula ##STR23## wherein R 2 is lower alkyl.
Claim 5
Dependent Claim
49 words
The composition of claim 1 wherein the polymer is a linear polyester and A is a 2-thienyl radical having the structure ##STR24## wherein R 3 is alkyl, hydroxyalkyl, alkoxyalkyl, alkanoyloxyalkyl, arylalkyl, cycloalkylalkyl, aryloxyalkyl, cycloalkoxyalkyl, alkylthioalkyl, arylthioalkyl, alkenyl, alkoxy, cycloalkyl, aryl or halogen; and n is 0, 1 or 2.
Claim 6
Dependent Claim
42 words
The composition of claim 1 wherein the polymer is a linear polyester having copolymerized therein about 200 to abut 800 ppm of the residue of one or a mixture of methine compounds of the formula ##STR25## wherein R 2 is lower alkyl.
Claim 7
Dependent Claim
49 words
The composition of claim 1 wherein the polymer is a linear polyester and A is a 3-thienyl radical having the structure ##STR26## wherein R 3 is alkyl, hydroxyalkyl, alkoxyalkyl, alkanoyloxyalkyl, arylalkyl, cycloalkylalkyl, aryloxyalkyl, cycloalkoxyalkyl, alkylthioalkyl, arylthioalkyl, alkenyl, alkoxy, cycloalkyl, aryl or halogen; and n is 0, 1 or 2.
Claim 8
Dependent Claim
42 words
The composition of claim 1 wherein the polymer is a linear polyester having copolymerized therein about 200 to about 800 ppm of the residue of one or a mixture of methine compounds of the formula ##STR27## wherein R 2 is lower alkyl.
Claim 9
Dependent Claim
62 words
The composition of any of claims 1-7 wherein the polyester acid moiety is comprised of at least about 50 mol % terephthalic acid residue, and the glycol moiety at least about 50 mol % ethylene glycol or 1,4-cyclohexanedimethanol residue, and the polyester contains a total of from about 2 to about 1,500 ppm of one or a mixture of the methine residues.
Claim 10
Dependent Claim
34 words
The composition of any of claims 1-8 wherein the polyester is comprised of from about 75 to 100 mol % terephthalic acid residue and from abut 75 to 100 mol % ethylene glycol residue.
Claim 11
Dependent Claim
63 words
The composition of claim 1 wherein the polymer is unsaturated polyester having an acid moiety comprised of fumaric or maleic acid or mixtures thereof and up to abut 60 mol % of one or amixture of o-phthalic, iso-phthalic, or terephthalic acids, and having a glycol moiety comprised of one or a mixture of propylene glycol, neopentyl glycol, 2,2,4-trimethyl-1,3-pentanediol, ethylene glycol or diethylene glycol.
Claim 12
Dependent Claim
51 words
The composition of claim 10 wherein the acid moiety is comprised of from about 75 to 100 mol % o-phthalic acid and maleic acid in a mole ratio of from abut 1/2 to about 2/1, and the glycol moiety is comprised of from about 75 to 100 mol % propylene glycol.
Claim 13
Dependent Claim
14 words
The composition of claim 10 containing a curing amount of an ethylenically unsaturated monomer.
Claim 14
Dependent Claim
10 words
A cured, formed article of the composition of claim 12.
Claim 15
Dependent Claim
27 words
A fiber of the composition of claim 1 dyed with from about 0.01 to about 5.0% by weight based on weight of fiber of a disperse dye.
Claim 16
Dependent Claim
27 words
A fiber of the composition of claim 8 dyed with from abut 0.01 to about 5.0% by weight based on weight of fiber of a disperse dye.
Claim 17
Dependent Claim
9 words
A formed article of the composition of claim 1.
Claim 18
Dependent Claim
9 words
A formed article of the composition of claim 8.
Claim 19
Dependent Claim
9 words
A formed article of the composition of claim 9.
Claim 20
Dependent Claim
9 words
A formed article of the composition of claim 10.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1991-06-07 | 1991-12-07 | 1992-06-07 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1995-06-07 | 1995-12-07 | 1996-06-07 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1999-06-07 | 1999-12-07 | 2000-06-07 | $7700.00 | Window Closed / Lapsed |