US4749754A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Impact modified polyamide/polycarbonate
Assignee: General Electric Co
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Filing: 1987-07-27
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Granted: 1988-06-07
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Expires: 2007-07-27
Abstract
Abstract Thermoplastic molding composition comprising amorphous polyamide and polycarbonate resin blends exhibit improved impact resistance by addition of a polyamide-polyether block copolymer.
Inventors
- 👤 Robert R. Gallucci
- 👤 Louis M. Maresca
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 11:27
CPC Classifications
C; C08; C08L; C08L77/00; C08L67/00; C08L69/00
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
24 words
A thermoplastic blend comprising: (a) an aromaric polycarbonate resin; (b) an amorphous polyamide resin; and (c) an impact-modifying proportion of a polyamide-polyether block copolymer.
Claim 2
Dependent Claim
24 words
A thermoplastic blend comprising: (a) an aromaric polycarbonate resin; (b) an amorphous polyamide resin; and (c) an impact-modifying proportion of a polyamide-polyether block copolymer.
Claim 3
Dependent Claim
24 words
A thermoplastic blend as in claim 1 wherein the polycarbonate resin contains structural units of the formula: ##STR14## wherein D is divalent aromatic radical.
Claim 4
Dependent Claim
20 words
A thermoplastic blend as in claim 2 wherein aromatic polycarbonate resin comprises polymers selected from the group consisting of poly(ester-carbonate)polymers.
Claim 5
Dependent Claim
19 words
A thermoplastic blend as in claim 2 wherein the aromatic polycarbonate is obtained by polymerizing phosgene with 2,2-bis(4-hydroxyphenyl) propane.
Claim 6
Dependent Claim
27 words
A thermoplastic blend as in claim 4 wherein the aromatic polycarbonate is obtained by polymerizing phosgene with 2,2-bis(4-hydroxyphenol) propane and a mixture of isophthalic and terephthalic acids.
Claim 7
Dependent Claim
17 words
A thermoplastic blend as in claim 1 wherein said amorphous polyamide is substantially free of amine end-groups.
Claim 8
Dependent Claim
23 words
A thermoplastic blend as in claim 1 wherein the ratio of amorphous polyamide to polycarbonate falls within the range of 10:90 to 90:10.
Claim 9
Dependent Claim
58 words
A thermoplastic blend as in claim 1 wherein the amorphous polyamide contains structural units selected from those of the formula: ##STR15## wherein R 1 and R 2 are different divalent organic radicals selected from the group consisting of C 2 -C 15 alkylene radicals C 3 -C 18 cycloalkylene radicals and C 6 to C 20 arylene radicals.
Claim 10
Dependent Claim
72 words
A thermoplastic blend as in claim 8 wherein the amorphous polyamide is obtained by polymerization of members selected from the group consisting of (a) terephthalic acid with, trimethylhexamethylene diamine; (b) isophthalic acid with trimethylhexamethylene diamine; (c) adipic acid, azelaic acid and 2,2-bis-(p-aminocyclohexyl) propane; (d) terephthalic acid with bis (4-amino cyclohexyl) methane; (e) isophthalic acid with hexamethylenediamine; (f) terephthalic acid/isophthalic acid with hexamethylene diamine, and (g) adipic acid/azelaic acid with diphenyl methane diisocyanate.
Claim 11
Dependent Claim
77 words
A thermoplastic blend as in claim 1 wherein the polyamide-polyether block copolymer possesses recurring chain units of the formula: ##STR16## wherein PA represents a saturated amide sequence formed from a lactam or an amino acid having a hydrocarbon chain containing from 4 to 14 carbon atoms, inclusive, or from a dicarboxylic acid and a diamine wherein both can have from 4 to 40 carbon atoms, inclusive; and PE represents a polyether sequence formed from a polyoxyalkylene glycol.
Claim 12
Dependent Claim
29 words
The blend of claim 10 wherein the proportion by weight of the polyoxyalkylene glycol sequence to the total weigh of the block copolymer is from 5 to 85 percent.
Claim 13
Dependent Claim
21 words
A thermoplastic blend as in claim 1 wherein the impact-modifying proportion is from 5 to 30 weight percent of the blend.
Claim 14
Dependent Claim
9 words
An article molded from the composition of claim 1.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1991-06-07 | 1991-12-07 | 1992-06-07 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1995-06-07 | 1995-12-07 | 1996-06-07 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1999-06-07 | 1999-12-07 | 2000-06-07 | $7700.00 | Window Closed / Lapsed |