US4748262A
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(Phenyl dimethyl carbinyl) silane compound and a method for the preparation thereof
Assignee: Shin-Etsu Chemical Co Ltd
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Filing: 1987-09-01
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Granted: 1988-05-31
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Expires: 2007-09-01
Abstract
Abstract The invention provides organosilane compounds of a novel class having one or two (phenyl dimethyl carbinyl) groups bonded to the silicon atom as represented by the general formula (PhMe 2 C) p R q X r Si, in which Ph is a phenyl group, Me is a methyl group, R is a monovalent hydrocarbon group selected from the class consisting of alkyl, alkenyl and aryl groups, X is a halogen atom or an alkoxy group, p is 1 or 2, q is zero, 1 or 2 and r is zero, 1, 2 or 3 with the proviso that p+q+r=4. The compound can be prepared by the reaction of a Grignard reagent PhMe 2 C. MgY, in which Y is a halogen atom, with a silane compound represented by the general formula R q SiX 4-q in an organic solvent.
Inventors
- 👤 Toshinobu Ishihara
- 👤 Minoru Takamizawa
- 👤 Mikio Endo
- 👤 Toru Kubota
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 11:34
CPC Classifications
C; C07; C07F; C07F7/00; C07F7/02; C07F7/08; C07F7/12; C07F7/18; C07F7/1804
Claims Analysis
Total Claims: 20
Claim 1
Independent Claim
79 words
A (phenyl dimethyl carbinyl)silane compound represented by the general formula (PhMe.sub.2 C).sub.p R.sub.q X.sub.r Si, in which Ph is a phenyl group, Me is a methyl group, R is a monovalent hydrocarbon group selected from the class consisting of alkyl groups, alkenyl groups and aryl groups, X is a halogen atom or an alkoxy group, p is 1 or 2, q is zero, 1 or 2 and r is zero, 1, 2 or 3 with the proviso that p+q+r=4.
Claim 2
Dependent Claim
79 words
A (phenyl dimethyl carbinyl)silane compound represented by the general formula (PhMe.sub.2 C).sub.p R.sub.q X.sub.r Si, in which Ph is a phenyl group, Me is a methyl group, R is a monovalent hydrocarbon group selected from the class consisting of alkyl groups, alkenyl groups and aryl groups, X is a halogen atom or an alkoxy group, p is 1 or 2, q is zero, 1 or 2 and r is zero, 1, 2 or 3 with the proviso that p+q+r=4.
Claim 3
Dependent Claim
14 words
The (phenyl dimethyl carbinyl)silane compound as claimed in claim 1 wherein p is 1.
Claim 4
Dependent Claim
27 words
The (phenyl dimethyl carbinyl)silane compound as claimed in claim 1 wherein R is selected from the class consisting of methyl, ethyl, vinyl, allyl, phenyl and tolyl groups.
Claim 5
Dependent Claim
27 words
(Phenyl dimethyl carbinyl)dimethyl chlorosilane expres-sed by the structural formula (PhMe 2 C)Me 2 SiCl, in which Ph is a phenyl group and Me is a methyl group.
Claim 6
Dependent Claim
27 words
(Phenyl dimethyl carbinyl)dimethyl chlorosilane expres-sed by the structural formula (PhMe 2 C)Me 2 SiCl, in which Ph is a phenyl group and Me is a methyl group.
Claim 7
Dependent Claim
27 words
(Phenyl dimethyl carbinyl)methyl dichlorosilane expres-sed by the structural formula (PhMe 2 C)MeSiCl 2 , in which Ph is a phenyl group and Me is a methyl group.
Claim 8
Dependent Claim
27 words
(Phenyl dimethyl carbinyl)methyl dichlorosilane expres-sed by the structural formula (PhMe 2 C)MeSiCl 2 , in which Ph is a phenyl group and Me is a methyl group.
Claim 9
Dependent Claim
26 words
(Phenyl dimethyl carbinyl)methyl phenyl chlorosilane expressed by the structural formula (PhMe 2 C)MePhSiCl, in which Ph is a phenyl group and Me is a methyl group.
Claim 10
Dependent Claim
26 words
(Phenyl dimethyl carbinyl)methyl phenyl chlorosilane expressed by the structural formula (PhMe 2 C)MePhSiCl, in which Ph is a phenyl group and Me is a methyl group.
Claim 11
Dependent Claim
28 words
(Phenyl dimethyl carbinyl)methyl dimethoxy silane expressed by the structural formula (PhMe 2 C)MeSi(OMe) 2 , in which Ph is a phenyl group and Me is a methyl group.
Claim 12
Dependent Claim
28 words
(Phenyl dimethyl carbinyl)methyl dimethoxy silane expressed by the structural formula (PhMe 2 C)MeSi(OMe) 2 , in which Ph is a phenyl group and Me is a methyl group.
Claim 13
Dependent Claim
27 words
(Phenyl dimethyl carbinyl)phenyl dichlorosilane expres-sed by the structural formula (PhMe 2 C)PhSiCl 2 , in which Ph is a phenyl group and Me is a methyl group.
Claim 14
Dependent Claim
27 words
(Phenyl dimethyl carbinyl)phenyl dichlorosilane expres-sed by the structural formula (PhMe 2 C)PhSiCl 2 , in which Ph is a phenyl group and Me is a methyl group.
Claim 15
Dependent Claim
28 words
(Phenyl dimethyl carbinyl)methyl vinyl chlorosilane expressed by the structural formula (PhMe 2 C)(CH 2 ═CH)MeSiCl, in which Ph is a phenyl group and Me is a methyl group.
Claim 16
Dependent Claim
28 words
(Phenyl dimethyl carbinyl)methyl vinyl chlorosilane expressed by the structural formula (PhMe 2 C)(CH 2 ═CH)MeSiCl, in which Ph is a phenyl group and Me is a methyl group.
Claim 17
Dependent Claim
27 words
(Phenyl dimethyl carbinyl)diphenyl chlorosilane expres-sed by the structural formula (PhMe 2 C)Ph 2 SiCl, in which Ph is a phenyl group and Me is a methyl group.
Claim 18
Dependent Claim
27 words
(Phenyl dimethyl carbinyl)diphenyl chlorosilane expres-sed by the structural formula (PhMe 2 C)Ph 2 SiCl, in which Ph is a phenyl group and Me is a methyl group.
Claim 19
Independent Claim
149 words
A method for the preparation of a (phenyl dimethyl carbinyl)silane compound represented by the general formula (PhMe.sub.2 C).sub.p R.sub.q X.sub.r Si, in which Ph is a phenyl group, Me is a methyl group, R is a monovalent hydrocarbon group selected from the class consisting of alkyl groups, alkenyl groups and aryl groups, X is a halogen atom or an alkoxy group, p is 1 or 2, q is zero, 1 or 2 and r is zero, 1, 2 or 3 with the proviso that p+q+r=4, which comprises reacting a Grignard reagent of phenyl dimethyl carbinyl magnesium halide represented by the general formula PhMe.sub.2 C.MgY, in which Ph and Me each have the same meaning as defined above and Y is a halogen atom, with a silane compound represented by the general formula R.sub.q SiX.sub.4-q, in which each symbol has the same meaning as defined above, in an organic solvent.
Claim 20
Independent Claim
149 words
A method for the preparation of a (phenyl dimethyl carbinyl)silane compound represented by the general formula (PhMe.sub.2 C).sub.p R.sub.q X.sub.r Si, in which Ph is a phenyl group, Me is a methyl group, R is a monovalent hydrocarbon group selected from the class consisting of alkyl groups, alkenyl groups and aryl groups, X is a halogen atom or an alkoxy group, p is 1 or 2, q is zero, 1 or 2 and r is zero, 1, 2 or 3 with the proviso that p+q+r=4, which comprises reacting a Grignard reagent of phenyl dimethyl carbinyl magnesium halide represented by the general formula PhMe.sub.2 C.MgY, in which Ph and Me each have the same meaning as defined above and Y is a halogen atom, with a silane compound represented by the general formula R.sub.q SiX.sub.4-q, in which each symbol has the same meaning as defined above, in an organic solvent.
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