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US4748131A Expired / Lapsed US ⏱️ 0.0 years remaining

Method for increasing radiation hardness of MOS gate oxides

Assignee: Aerospace Corp
•
Filing: 1987-02-06
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Granted: 1988-05-31
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Expires: 2007-02-06
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Abstract

Abstract The resistance to radiation damage of metal-oxide-semiconductor devices is improved by the incorporation of fluorine into the gate oxide of the device by robust procedures. The introduction of fluorine into the oxide results in a significant reduction of radiation-induced interface state density. Three methods by which the fluorine is introduced into the gate oxide are: (1) silicidation of the polysilicon gate by chemical vapor deposition using tungsten hexafluoride as a source gas; (2) ion implantation of fluorine into the polysilicon layer on top of the gate oxide, followed by a high temperature anneal to allow the fluorine to migrate into the oxide; and (3) growth of the oxide in a dilute NF 3 ambient.

Inventors

  • 👤 Thomas C. Zietlow

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 11:34
CPC Classifications
H; H10; H10D; H10D64/00; H10D64/01; H10D64/013; H10D64/01302; H10D64/01332; H10D64/01336; H10D64/01338; H10D64/01304; H10D64/01306; H10D64/01308; H10D64/01312; H10D64/60; H10D64/66; H10D64/68; H10P; H10P14/00; H10P14/60; H10P14/63; H10P14/6302; H10P14/6304; H10P14/6306; H10P14/6308; H10P32/00; H10P32/30; H10P32/302; Y; Y10; Y10S; Y10S438/00; Y10S438/91; Y10S438/953

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 39 words
A method for improving the radiation damage resistance of silicon metal-oxide-semiconductor (MOS) devices by implanting fluorine atoms into a polysilicon layer above the oxide followed by a high temperature anneal thereby allowing the fluorine to migrate into the oxide.
Claim 2
Independent Claim 39 words
A method for improving the radiation damage resistance of silicon metal-oxide-semiconductor (MOS) devices by implanting fluorine atoms into a polysilicon layer above the oxide followed by a high temperature anneal thereby allowing the fluorine to migrate into the oxide.
Claim 3
Dependent Claim 37 words
The method as claimed in claim 1 further comprising the step of implanting fluorine-containing ions into the polysilicon layer above the oxide followed by a high temperature anneal thereby allowing the fluorine to migrate into the oxide.
Claim 4
Dependent Claim 19 words
The method as claimed in claim 2 wherein the fluorine-containing ions are silicon difluoride ions or silicon trifluoride ions.
Claim 5
Dependent Claim 31 words
The method as claimed in claim 1 further comprising the step of growing the oxide in an oxidation furnace with an oxygen/nitrogen trifluoride ambient thereby incorporating fluorine directly into the oxide.
Claim 6
Dependent Claim 47 words
The method as claimed in claim 1 further comprising the step of growing the polysilicon layer by chemical vapor deposition using tungsten hexafluoride as the source gas and silane as the reductant, followed by a high temperature anneal thereby allowing the fluorine to migrate into the oxide.

References Cited (Backward Citations)

US3933530A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-05-31 1991-11-30 1992-05-31 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-05-31 1995-11-30 1996-05-31 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-05-31 1999-11-30 2000-05-31 $7700.00 Window Closed / Lapsed

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