US4746751A
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Silicone reactive/fluorescent silane dye compositions
Assignee: Baxter International Inc
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Filing: 1987-05-07
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Granted: 1988-05-24
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Expires: 2007-05-07
Abstract
Abstract The preparation of particular fluorescent silane dye compositions is disclosed. These silane dye compositions have particular utility as reactants in the preparation of silicone polymeric fluorescent dyes which can be ideally used as chemical indicators in biological sensors.
Inventors
- 👤 Henry W. Oviatt, Jr.
- 👤 Cary J. Reich
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 14:38
CPC Classifications
C; C09; C09B; C09B69/00; C09B69/008; C07; C07F; C07F7/00; C07F7/02; C07F7/08; C07F7/0803; C07F7/0805; C07F7/18; C07F7/1804; C08; C08K; C08K5/00; C08K5/54
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
48 words
A silane dye composition having the formula ##STR14## wherein Q is a fluorescent dye group; Z is a C 1-30 hydrocarbon radical; R is a hydrogen atom or a C 1-12 hydrocarbon radical; and G is a functional group capable of reacting with a silicone polymer functional group.
Claim 2
Dependent Claim
48 words
A silane dye composition having the formula ##STR14## wherein Q is a fluorescent dye group; Z is a C 1-30 hydrocarbon radical; R is a hydrogen atom or a C 1-12 hydrocarbon radical; and G is a functional group capable of reacting with a silicone polymer functional group.
Claim 3
Dependent Claim
24 words
The composition of claim 1 wherein G is an unsaturated organic functional group selected from the class of vinyl, alkyl, methallyl, or butenyl radicals.
Claim 4
Dependent Claim
27 words
The composition of claim 1 wherein Q is a fluorescent dye selected from the group of polynuclear aromatic dyes composed of pyrene, perylene, benzopyrlene and derivatives thereof.
Claim 5
Dependent Claim
53 words
The dye composition of claim 1 wherein G is a radical of the formula ##STR15## where R is a hydrogen atom or a C 1-12 hydrocarbon radical; n is a whole number of from 1 to 50; and V 1 , V 2 and V 3 are independently a silicone polymer reactive substituent.
Claim 6
Dependent Claim
33 words
The composition of claim 4 wherein the V 1 , V 2 and V 3 silicone polymer reactive groups are selected from the class of radicals consisting of alkoxy, acyloxy or amine groups.
Claim 7
Dependent Claim
8 words
The composition of claim 1 comprising methyl(pyrenyl)dimethylvinyl silane.
Claim 8
Dependent Claim
7 words
The composition of claim 5 comprising methyl(pyrenyl)dimethylethyl(triethylsiloxy)silane.
Claim 9
Independent Claim
106 words
A method of preparing a dye-silane composition comprising reacting a substituted polynuclear aromatic hydrocarbon based fluorescent dye of the formula: Q-Z-M wherein Q is a polynuclear aromatic fluorescent dye moiety, Z is a C 1-30 hydrocarbon radical, and M is a silane reactive substituent selected from the group consisting of halogen, hydroxyl, carboxyl, amine, and amide groups; with an unsaturated organo functional silane having the formula: ##STR16## wherein X is selected from the group of hydrogen, hydroxyl, and halogen radicals; R is a hydrogen atom or a C 1-12 hydrocarbon radical and A is an alkenyl group to form the dye silane of the formula ##STR17##
Claim 10
Independent Claim
106 words
A method of preparing a dye-silane composition comprising reacting a substituted polynuclear aromatic hydrocarbon based fluorescent dye of the formula: Q-Z-M wherein Q is a polynuclear aromatic fluorescent dye moiety, Z is a C 1-30 hydrocarbon radical, and M is a silane reactive substituent selected from the group consisting of halogen, hydroxyl, carboxyl, amine, and amide groups; with an unsaturated organo functional silane having the formula: ##STR16## wherein X is selected from the group of hydrogen, hydroxyl, and halogen radicals; R is a hydrogen atom or a C 1-12 hydrocarbon radical and A is an alkenyl group to form the dye silane of the formula ##STR17##
Claim 11
Dependent Claim
72 words
The process of claim 8 wherein the resulting unsaturated organo silane dye is further reacted with a hydride functional silane of the formula: ##STR18## in an addition reaction with the unsaturated A group to form ##STR19## wherein n is a whole number from 1 to 50 and V 1 V 2 and V 3 are independently a silicone polymer reactive substituent selected from the class consisting of alkoxy, acyloxy and amine radicals.
Claim 12
Dependent Claim
23 words
The process of claim 8 wherein the alkenyl group A is selected from the group consisting of vinyl, allyl, methallyl, and butenyl radicals.
Claim 13
Dependent Claim
12 words
The process of claim 8 wherein the product formed is methyl(pyrenyl)dimethylvinyl silane.
Claim 14
Dependent Claim
11 words
The process of claim 9 wherein the product formed is methyl(pyrenyl)dimethylethyl(triethylsiloxy)silane.
References Cited (Backward Citations)
US3647740A
Cited
US4129585A
Cited
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| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1991-05-24 | 1991-11-23 | 1992-05-24 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1995-05-24 | 1995-11-23 | 1996-05-24 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1999-05-24 | 1999-11-23 | 2000-05-24 | $7700.00 | Window Closed / Lapsed |