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US4746601A Expired / Lapsed US ⏱️ 0.0 years remaining

Silver halide photographic light-sensitive material

Assignee: Fujifilm Holdings Corp
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Filing: 1987-03-09
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Granted: 1988-05-24
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Expires: 2007-03-09
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Abstract

Abstract A silver halide photographic light-sensitive material comprising a support having provided thereon at least one photographic layer including at least one silver halide emulsion layer, wherein at least one silver halide emulsion layer contains silver halide grains whose average value of the diameter corresponding to the projected area of a group of silver halide grains that take 40% of the total projected area of whole silver halide grains present in said silver halide emulsion layer is at least 1.5 μm and at least one photographic layer contains at least one compound capable of imagewise releasing a fogging agent or a precursor thereof or a development accelerator or a precursor thereof corresponding to a quantity of developed silver upon development, is disclosed. This material is of very high sensitivity and, furthermore, has a high developing speed and has reduced for formation irrespective of its high sensitivity.

Inventors

  • 👤 Keiji Mihayashi
  • 👤 Hidetoshi Kobayashi
  • 👤 Shunji Takada

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 20:46
CPC Classifications
G; G03; G03C; G03C7/00; G03C7/30; G03C7/3003; G03C7/3022; G03C1/00; G03C1/005; G03C1/0051; G03C1/06; G03C1/08; G03C1/10; G03C1/035; G03C2001/03594; G03C7/305; G03C7/30541; Y; Y10; Y10S; Y10S430/00; Y10S430/156

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 140 words
A silver halide photographic light-sensitive material comprising a support having provided thereon at least one photographic layer including at least one silver halide emulsion layer, wherein at least one silver halide emulsion layer contains silver halide grains whose average value of the diameter corresponding to the projected area of a group of silver halide grains that take 40% of the total projected area of whole silver halide grains present in said silver halide emulsion layer is at least 1.5 μm, and at least one photographic layer contains at least one compound capable of imagewise releasing a fogging agent or a precursor thereof or a development accelerator or a precursor thereof corresponding to a quantity of developed silver upon development, wherein said compound is present in an amount of 10 -8 to 0.5 mole per mole of said silver halide grains.
Claim 2
Dependent Claim 140 words
A silver halide photographic light-sensitive material comprising a support having provided thereon at least one photographic layer including at least one silver halide emulsion layer, wherein at least one silver halide emulsion layer contains silver halide grains whose average value of the diameter corresponding to the projected area of a group of silver halide grains that take 40% of the total projected area of whole silver halide grains present in said silver halide emulsion layer is at least 1.5 μm, and at least one photographic layer contains at least one compound capable of imagewise releasing a fogging agent or a precursor thereof or a development accelerator or a precursor thereof corresponding to a quantity of developed silver upon development, wherein said compound is present in an amount of 10 -8 to 0.5 mole per mole of said silver halide grains.
Claim 3
Dependent Claim 26 words
A silver halide photographic light-sensitive material as claimed in claim 1, wherein said silver halide emulsion layer contains both said silver halide grains and said compound.
Claim 4
Dependent Claim 136 words
A silver halide photographic light-sensitive material as claimed in claim 1, wherein at least two silver halide emulsion layers are provided on said support, said silver halide emulsion layers being sensitive to the same color but having different sensitivity from each other, and the silver halide emulsion layer other than the lowest sensitivity emulsion layer containing both silver halide grains whose average value of the diameter corresponding to the projected area of a group of silver halide grains that take 40% of the total projected area of whole silver halide grains present in said silver halide emulsion layer is at least 1.5 μm and at least one compound capable of imagewise releasing a fogging agent or a precursor thereof or a development accelerator or a precursor thereof corresponding to a quantity of developed silver upon development.
Claim 5
Dependent Claim 135 words
A silver halide photographic light-sensitive material as claimed in claim 1, wherein at least three silver halide emulsion layers are provided on said support, said silver halide emulsion layers being sensitive to the same color but having different sensitivity from each another, and the silver halide emulsion layer other than the lowest sensitivity emulsion layer containing both silver halide grains whose average value of the diameter corresponding to the projected area of a group of silver halide grains that take 40% of the total projected area of whole silver halide grains present in said silver halide emulsion layer is at least 1.5 μm and at least one compound capable of imagewise releasing a fogging agent or a precursor or a development accelerator or a precursor thereof corresponding to a quantity of developed silver upon development.
Claim 6
Dependent Claim 31 words
A silver halide photographic light-sensitive material as claimed in claims 1, 2, 3, or 4, wherein said silver halide grains are at least 1.7 μm in the average value of diameter.
Claim 7
Dependent Claim 31 words
A silver halide photographic light-sensitive material as claimed in claims 1, 2, 3, or 4, wherein said silver halide grains are at least 1.8 μm in the average value of diameter.
Claim 8
Dependent Claim 31 words
A silver halide photographic light-sensitive material as claimed in claims 1, 2, 3, or 4, wherein said silver halide grains are at least 2.0 μm in the average value of diameter.
Claim 9
Dependent Claim 67 words
A silver halide photographic light-sensitive material as claimed in claims 1, 2, 3, or 4, wherein said silver halide grains are those whose average value of the diameter corresponding to the projected area of a group of silver halide grains that take 40% or more of the total projected area of whole silver halide grains present in said silver halide emulsion layer is at least 1.5 μm.
Claim 10
Dependent Claim 67 words
A silver halide photographic light-sensitive material as claimed in claims 1, 2, 3, or 4, wherein said silver halide grains are those whose average value of the diameter corresponding to the projected area of a group of silver halide grains that take 50% or more of the total projected area of whole silver halide grains present in said silver halide emulsion layer is at least 1.5 μm.
Claim 11
Dependent Claim 67 words
A silver halide photographic light-sensitive material as claimed in claims 1, 2, 3, or 4, wherein said silver halide grains are those whose average value of the diameter corresponding to the projected area of a group of silver halide grains that take 70% or more of the total projected area of whole silver halide grains present in said silver halide emulsion layer is at least 1.5 μm.
Claim 12
Dependent Claim 37 words
A silver halide photographic light-sensitive material as claimed in claims 1, 2, 3, or 4, wherein said compound is present in an amount of 5×10 -7 to 10 -2 mole per mole of said silver halide grains.
Claim 13
Dependent Claim 258 words
A silver halide photographic light-sensitive material as claimed in claims 1, 2, 3, or 4, wherein said compound is (i) a coupler capable of realeasing a fogging agent, a development accelerator or precursors thereof upon coupling with an oxidation product of an aromatic primary amine developing agent; (ii) a coupler capable of forming a diffusible coupling product which functions as a fogging agent, a development accelerator or precursors thereof upon coupling with an oxidation product of an aromatic primary amine developing agent; or (iii) a redox compound capable of releasing a fogging agent, a development accelerator or precursors thereof upon oxidation reduction reaction with an oxidation product of an aromatic primary amine developing agent or the subsequent reaction; each is represented by the following formulae (1), (2) and (3), respectively: Cp--(TIME).sub.n --FA (1) BALL--Cp--(TIME).sub.n --FA (2) RED--(TIME).sub.n --FA (3) wherein Cp represents a coupler residue capable of coupling with an oxidation product of an aromatic primary amine developing agent; BALL represents a non-diffusible group which is eliminated from Cp upon the coupling reaction with an oxidation product of an aromatic primary amine developing agent, RED represents a residue of a compound capable of undergoing oxidation reduction reaction with an oxidation product of an aromatic primary amine developing agent; TIME represents a timing group releasable from Cp or RED upon coupling reaction or oxidation reduction reaction to release FA; n represents 0 or 1; FA represents a group releasable from Cp or RED upon coupling when n is 0, or a group releasable from TIME when n is 1.

References Cited (Backward Citations)

US4199355A Cited
US4390618A Cited
US4500633A Cited
US4482629A Cited
US4518682A Cited
US4522917A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-05-24 1991-11-23 1992-05-24 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-05-24 1995-11-23 1996-05-24 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-05-24 1999-11-23 2000-05-24 $7700.00 Window Closed / Lapsed

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