Ultrathin polyimide polymers films and their preparation

Claim 2

A process for preparing a polyimide polymer film having a thickness of about 400 angstroms or less and having no macroscopic holes, wherein the process comprises: (a) preparing a casting solution containing a polyimide polymer at about the two to about the twelve percent by weight level, based upon the total weight of the casting solution, in 1,2,3-trichloropropane; (b) depositing the casting solution on water to form a free-standing film; and (c) removing the film from the water.

Claim 3

The process of claim 1 wherein the polyimide polymer has repeating units of the formula: ##STR8## wherein R is a tetravalent organic radical selected from the group consisting of aromatic, aliphatic, cycloaliphatic, heterocyclic, combinations of aromatic and aliphatic, and substituted groups thereof and wherein R' is a divalent benzenoid radical selected from the group consisting of: ##STR9## wherein R" is selected from the group consisting of an alkylene chain having one to three carbon atoms, ##STR10## wherein R"' and R"" are selected from the group consisting of alkyl and aryl.

Claim 4

The process of claim 2 wherein R is a tetravalent aromatic radical containing at least one ring of six carbon atoms, said ring being characterized by benzenoid unsaturation and the four carbonyl groups being attached directly to separate carbon atoms in a ring of the R radical and each pair of carbonyl groups being attached to adjacent carbon atoms in a ring of the R radical.

Claim 5

The process of claim 3 wherein R is ##STR11## and R' is ##STR12##

Claim 6

The process of claim 1 wherein the casting solution contains ortho-dichlorobenzene in addition to 1,2,3-trichloropropane at about a 1:1 to about a 10:1 by volume ratio, respectively.

Claim 7

The process of claim 5 wherein the ratio is about 20:7.

Claim 8

A process for preparing a polyimide polymer film having a thickness of about 400 angstroms or less and having no macroscopic holes, wherein the process comprises: (a) preparing a casting solution containing a polyimide polymer having the repeating formula: ##STR13## at about the two to about the twelve percent by weight level based upon the total weight of the casting solution, in 1,2,3-trichloropropane: (b) depositing the casting solution on water to form a free-standing film; and (c) removing the film from the water.

Claim 9

A process for preparing a polyimide polymer film having a thickness of about 400 angstroms or less and having no macroscopic holes, wherein the process comprises: (a) preparing a casting solution containing a polyimide polymer having the repeating formula: ##STR13## at about the two to about the twelve percent by weight level based upon the total weight of the casting solution, in 1,2,3-trichloropropane: (b) depositing the casting solution on water to form a free-standing film; and (c) removing the film from the water.

Claim 10

The process of claim 7 wherein the casting solution contains ortho-dichlorobenzene in addition to 1,2,3-trichloropropane at about a 1:1 to about a 10:1 by volume ratio, respectively.

Claim 11

The process of claim 8 wherein the ratio is about a 20:7 by volume ratio of 1,2,3-trichloropropane:ortho-dichlorobenzene.

Claim 12

The process of claims 1 or 7 wherein the polyimide polymer has a molecular weight, M w , greater than about 25,000.

Claim 13

The process of claims 1, 4, 5, 6, 7, 8 or 9 wherein the polyimide polymer is present at about the four to about the eight percent by weight level in the casting solution based upon the total weight of the casting solution.

Claim 14

The process of claim 11 wherein the polymer is present at about the seven to about the eight percent by weight level.

Claim 15

The process of claims 1, 4, 7 or 9 wherein the film is crosslinked by heating the film.

Claim 16

The process of claim 13 wherein the film is heated at a temperature in the range of about 250° C. to about 350° C. to crosslink the film.

Claim 17

The process of claim 14 wherein the film is heated at a temperature of about 290° C. to crosslink the film.

Claim 18

The process of claims 1 or 7 wherein the casting solution contains a polyimide polymer at about the 80 to about the 100 percent by weight level and another polymer or polymers at about the 20 to about the 0 percent by weight level based upon the total weight of the polymers dissolved in the casting solution.