Patent US6602088B1 successfully refreshed from Google Patents.
US4744969A
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US
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Process for the conversion of coal and gypsum to valuable products
Assignee: Florida Industrial and Phosphate Research Institute
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Filing: 1986-12-10
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Granted: 1988-05-17
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Expires: 2006-12-10
Abstract
Abstract The present invention relates to the coproduction of a combustible feed gas stream useable as an energy source and a sulfur-containing second gas stream useable as a feedstock for the production of sulfuric acid. The process includes heating coal in the presence of an oxygen-lean atmosphere under partial coal gasifying conditions to produce a solid carbonaceous char and a crude coal-gas stream. Sulfur-containing compounds are removed from the coal gas stream and converted to solid sulfur-containing materials. The solid sulfur-containing materials are combined with the solid carbonaceous char and gypsum to form a feed mixture. The non-gypsum portion of the feed mixture contains sufficient reducing potential to release substantially all of the sulfur in the gypsum as gaseous compounds of sulfur in a +4 or lower oxidation state. The feed mixture is heated under reducing conditions to produce a sulfur-containing second gas stream and a solid sintered product.
Inventors
- 👤 Jerome H. Marten
- 👤 Timothy J. Kendron
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 19:42
CPC Classifications
C; C10; C10J; C10J3/00; C01; C01B; C01B17/00; C01B17/48; C01B17/50; C10J3/46; C10J3/463; C10J3/54; C10J3/72; C10J3/86; C10K; C10K1/00; C10K1/002; C10K1/003; C10K1/004; C10K1/02; C10J2200/00; C10J2200/15; C10J2200/152; C10J2300/00; C10J2300/09; C10J2300/0903; C10J2300/0906; C10J2300/0909; C10J2300/0913; C10J2300/093; C10J2300/0953; C10J2300/0956; C10J2300/0959; C10J2300/16; C10J2300/1625; C10J2300/1628; C10J2300/1687
Claims Analysis
Total Claims: 28
Claim 1
Independent Claim
170 words
A process for the coproduction of a combustible first gas stream usable as an energy source and a sulfur-containing second gas stream useable as a feedstock for the production of sulfuric acid, said process comprising the steps of: (a) heating coal in the presence of an oxygen-lean atmosphere under partial coal-gasifying conditions to produce a solid carbonaceous char and a crude gas stream containing gaseous sulfur-containing compounds; (b) separating the gaseous sulfur-containing compounds from the crude gas stream to produce a combustible first gas stream and converting the separated sulfur-containing compounds to a solid sulfur-containing material; (c) forming a feed mixture by combining the solid carbonaceous char from step (a) and the solid sulfur-containing material from step (b) with gypsum in proportions such that the non-gypsum portion of the feed mixture contains sufficient reducing potential to reduce sulfur in the gypsum to gaseous compounds of sulfur in +4 or lower oxidation state; (d) heating the feed mixture from step (c) under reducing conditions to produce a sulfur-containing second gas stream.
Claim 2
Dependent Claim
170 words
A process for the coproduction of a combustible first gas stream usable as an energy source and a sulfur-containing second gas stream useable as a feedstock for the production of sulfuric acid, said process comprising the steps of: (a) heating coal in the presence of an oxygen-lean atmosphere under partial coal-gasifying conditions to produce a solid carbonaceous char and a crude gas stream containing gaseous sulfur-containing compounds; (b) separating the gaseous sulfur-containing compounds from the crude gas stream to produce a combustible first gas stream and converting the separated sulfur-containing compounds to a solid sulfur-containing material; (c) forming a feed mixture by combining the solid carbonaceous char from step (a) and the solid sulfur-containing material from step (b) with gypsum in proportions such that the non-gypsum portion of the feed mixture contains sufficient reducing potential to reduce sulfur in the gypsum to gaseous compounds of sulfur in +4 or lower oxidation state; (d) heating the feed mixture from step (c) under reducing conditions to produce a sulfur-containing second gas stream.
Claim 3
Dependent Claim
56 words
The process of claim 1, wherein step (a) comprises heating particulate coal in the presence of an oxygen-lean atmosphere which contains up to about 50% by volume of steam, wherein the oxygen content and the feed rate of the oxygen-lean atmosphere are controlled to maintain a temperature of from about 700° C. to about 1100° C.
Claim 4
Dependent Claim
28 words
The process of claim 2, wherein the feed rate of the oxygen-lean atmosphere is controlled to maintain a temperature of from about 700° C. to about 1000° C.
Claim 5
Dependent Claim
21 words
The process of claim 3, wherein the partial coal-gasifying conditions include a pressure of from about 1.5 to about 20 atmospheres.
Claim 6
Dependent Claim
32 words
The process of claim 1, wherein the partial coal-gasifying conditions of step (a) are controlled to produce a solid carbonaceous char which contains from about 40 to about 80% by weight carbon.
Claim 7
Dependent Claim
22 words
The process of claim 1, wherein the feed mixture resulting from step (c) is pelletized prior to being subjected to step (d).
Claim 8
Dependent Claim
25 words
The process of claim 1, wherein step (c) further comprises combining pyritic material with the solid carbonaceous char, the solid sulfur-containing material and the gypsum.
Claim 9
Dependent Claim
21 words
The process of claim 7, wherein the pyritic material is pyrite, metallic iron, elemental sulfur, iron oxide or iron (II) sulfide.
Claim 10
Dependent Claim
30 words
The process of claim 8, wherein the pyritic material is pyrite and is added to the feed mixture at a concentration of from about 0 to about 20% by weight.
Claim 11
Dependent Claim
61 words
The process of 1, 4 or 7, wherein the feed mixture formed in step (c) contains from about 50 to about 80% by weight gypsum; a sufficient amount of the carbonaceous char to provide a carbon concentration in the feed mixture of from about 3 to about 11% by weight; and from about 0 to about 20% by weight pyritic material.
Claim 12
Dependent Claim
61 words
The process of 1, 4 or 7, wherein the feed mixture formed in step (c) contains from about 50 to about 80% by weight gypsum; a sufficient amount of the carbonaceous char to provide a carbon concentration in the feed mixture of from about 3 to about 11% by weight; and from about 0 to about 20% by weight pyritic material.
Claim 13
Dependent Claim
27 words
The process of claim 10, wherein the feed mixture of step (c) is formed into pellets having an average diameter of from about 1 inch or less.
Claim 14
Dependent Claim
17 words
The process of claim 1, wherein prior to the heating step (d), the feed mixture is dried.
Claim 15
Dependent Claim
39 words
The process of claim 12, wherein the feed mixture is dried by burning a portion of the combustible first gas stream to produce a hot spent combustion gas and passing the hot spent combustion gases through the feed mixture.
Claim 16
Dependent Claim
36 words
The process of claim 13, wherein at least a portion of the combustible first gas stream is used as a fuel for producing steam and the steam is directed to the oxygen-lean atmosphere of step (a).
Claim 17
Dependent Claim
92 words
The process of claim 12, wherein the heating of the feed mixture in step (d) is achieved by passing a mixture of air and a combustible gas, selected from the group consisting of the crude gas stream from step (a), the combustible first gas stream from step (b) and mixtures thereof, through said feed mixture, wherein the flow ratios of the air and the combustible gas are controlled to maintain a temperature sufficiently high to cause thermal decomposition and reduction of the gypsum, and to maintain reducing conditions within the feed mixture.
Claim 18
Dependent Claim
56 words
The process of claim 15, wherein the combustible gas used for heating the feed mixture is the combustible first gas stream from step (b) and the flow rates of the air and the combustible first gas stream are controlled to maintain a temperature of the feed mixture of from about 1100° C. to about 1500° C.
Claim 19
Dependent Claim
33 words
The process of claim 16, wherein the flow rates of the air and the combustible first gas stream are controlled to maintain a temperature of from about 1200° C. to about 1400° C.
Claim 20
Dependent Claim
23 words
The process of claim 1, wherein step (d) is conducted in a rotary kiln, a fluid bed reactor or a travelling grate reactor.
Claim 21
Dependent Claim
28 words
The process of claim 18, wherein the heating of step (d) is conducted in a rotary kiln for a period of from about 2 to about 4 hours.
Claim 22
Dependent Claim
29 words
The process of claim 18, wherein the heating of step (d) is conducted in a fluid bed reactor for a period of from about 0.25 to about 2 hours.
Claim 23
Dependent Claim
18 words
The process of claim 1, wherein the heating of step (d) is conducted in a travelling grate reactor.
Claim 24
Dependent Claim
46 words
The process of claim 21, wherein step (d) includes moving the travelling grate carrying a charge of pelletized feed mixture successively through firing and post-firing zones, and the charge is retained in the post-firing zone for a period of from about 10 to about 30 minutes.
Claim 25
Dependent Claim
23 words
The process of claim 22, wherein a portion of said sulfur-containing second gas stream is passed through the charge in the post-firing zone.
Claim 26
Dependent Claim
18 words
The process of claim 1, wherein the sulfur-containing second gas stream is passed to a sulfuric acid plant.
Claim 27
Dependent Claim
13 words
The process of claim 1, wherein the coal is lignite, subbituminous, or bituminous.
Claim 28
Dependent Claim
70 words
The process of claim 10, wherein the feed mixture comprises on a dry weight basis, (a) from about 55 to about 75 percent by weight of gypsum; (b) from about 4 to about 9 percent by weight of char as carbon; (c) from about 5 to about 15 percent by weight of pyritic material. (d) from about 0 to about 5 percent by weight of clay, lime or mixtures thereof.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1991-05-17 | 1991-11-16 | 1992-05-17 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1995-05-17 | 1995-11-16 | 1996-05-17 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1999-05-17 | 1999-11-16 | 2000-05-17 | $7700.00 | Window Closed / Lapsed |