Polyurethane foams incorporating alkoxylated aromatic diamine and acetylenic glycol

Claim 2

In a polyurethane foam formulation comprising an organic polyisocyanate, polyol, blowing agent and crosslinker system, the improvement which comprises including a crosslinker system of an alkoxylated aromatic diamine and an acetylenic glycol represented by the formula: ##STR3## wherein y and z range from 0-6 but the sum of y and z does not exceed 7; m and n combined range from 1 to 10, and R 1 , R 2 , R 3 , R 4 , R 5 and R 6 are hydrogen or methyl groups and may be like or unlike in the structure.

Claim 3

The formulation of claim 1 wherein the alkoxylated aromatic diamine is included in an amount of from 1 to 15 percent by weight of the polyol and the weight percent of alkoxylated aromatic diamine in the crosslinker system is from 40-95%.

Claim 4

The formulation of claim 2 wherein said polyol is a polymeric polyol having a molecular weight of from about 3,000 to 5,000.

Claim 5

The formulation of claim 3 wherein said alkoxylated aromatic diamine is an ethoxylated or propoxylated aromatic diamine and y and z in said acetylenic glycol are 0.

Claim 6

The formulation of claim 4 wherein said acetylenic glycol is an ethoxylated or propoxylated acetylenic glycol having from about 2-4 ethoxy or propoxy groups per molecule.

Claim 7

The formulation of claim 4 wherein said ethoxylated or propoxylated aromatic diamine is an ethoxylated or propoxylated C 1-4 alkyl derivative of toluenediamine.

Claim 8

The formulation of claim 6 wherein the ethoxylated or propoxylated alkyl derivative of toluenediamine is an ethoxylated or propoxylated diethyl toluenediamine or tertiary-butyl-toluenediamine.

Claim 9

The formulation of claim 7 wherein the average number of ethylene oxide or propylene oxide units in said ethoxylated or propoxylated diethyltoluenediamine or tertiary-butyl-toluenediamine is from 1.5-2.5.

Claim 10

The formulation of claim 8 wherein the acetylenic glycol is 2,4,7,9-tetramethyl-5-decyne-4,7-diol or 7,10-dimethyl-8-hexadecyne-7,10-diol.

Claim 11

A crosslinker system suitable for producing flexible polyurethane foams comprising an alkoxylated toluenediamine derivative and an acetylenic glycol represented by the formula: ##STR4## wherein y and z range from 0-6 and the sum of y and z does not exceed 7; m and n combined range from 1-10; and R 1 , R 2 , R 3 , R 4 , R 5 and R 6 are hydrogen or methyl groups may be like or unlike in the structure and the weight % of said alkoxylated toluenediamine is from 40-95% by weight of the crosslinker system.

Claim 12

A crosslinker system suitable for producing flexible polyurethane foams comprising an alkoxylated toluenediamine derivative and an acetylenic glycol represented by the formula: ##STR4## wherein y and z range from 0-6 and the sum of y and z does not exceed 7; m and n combined range from 1-10; and R 1 , R 2 , R 3 , R 4 , R 5 and R 6 are hydrogen or methyl groups may be like or unlike in the structure and the weight % of said alkoxylated toluenediamine is from 40-95% by weight of the crosslinker system.

Claim 13

The crosslinker system of claim 10 wherein said alkoxylated toluenediamine derivative is an alkoxylated C 2-6 alkylated derivative of toluenediamine and y and z in said acetylenic glycol are 0.

Claim 14

The crosslinker system of claim 11 wherein the weight percentage of alkoxylated alkylated toluenediamine derivative in said crosslinker system is from 85 to 95 and the weight percentage of alkoxylated acetylenic glycol is from 5 to 15%.

Claim 15

The crosslinker system of claim 12 wherein said alkoxylated alkylated toluenediamine derivative is an ethylene oxide or propylene oxide C 2-6 alkylated toluenediamine derivative.

Claim 16

The crosslinker system of claim 13 wherein in said acetylenic glycol R 1 and R 3 are H.

Claim 17

The crosslinker system of claim 10 wherein said acetylenic glycol 2,4,7,9,-tetramethyl-5-decynediol or 7,10-dimethyl-8-hexadecyne-7,10-diol and said alkoxylated alkylated toluenediamine derivative is an ethoxylated or propoxylated diethyltoluenediamine or tertiary-butyl-toluenediamine.

Claim 18

The crosslinker system of claim 13 wherein said alkoxylated alkylated toluenediamine derivative is an ethoxylated or propoxylated derivative of diethyltoluenediamine and the average number of ethylene oxide or propylene oxide units is from 1.5 to 2.5, and the acetylenic glycol is an ethylene oxide adduct of 2,4,7,9-tetramethyl-5-decyne-4,7-diol having an average of 1.5-4.5 moles ethylene oxide incorporated herein and the weight percent of alkoxylated alkylated derivative of toluenediamine is from 85-95% of the crosslinker system.

Claim 19

In a process for the manufacture of polyurethane foams which comprises reacting under foam-forming conditions an organic polyisocyanate, a polyether polyol having a molecular weight from about 3,000 to 6,000 and an aromatic diamine/alkylene oxide crosslinker, the improvement which comprises including a crosslinker system of an alkylene oxide adduct of a C 2-6 alkyl derivative of toluenediamine with the general formula: ##STR5## wherein a, b, c, and d are integers with this sum being from 1-15, R' represents CH 3 , or diorgano C 1-6 amide, R 8 represents hydrogen, or C 1-4 alkyl group, and q is 0 or 1, and an acetylenic glycol of the formula: ##STR6## wherein y and z range from 0-6 and the sum of y and z does not exceed 7; m and n combined range from 1-6; and R 1 , R 2 , R 3 , R 4 , R 5 and R 6 are hydrogen or methyl groups and may be like or unlike in the structure.

Claim 20

In a process for the manufacture of polyurethane foams which comprises reacting under foam-forming conditions an organic polyisocyanate, a polyether polyol having a molecular weight from about 3,000 to 6,000 and an aromatic diamine/alkylene oxide crosslinker, the improvement which comprises including a crosslinker system of an alkylene oxide adduct of a C 2-6 alkyl derivative of toluenediamine with the general formula: ##STR5## wherein a, b, c, and d are integers with this sum being from 1-15, R' represents CH 3 , or diorgano C 1-6 amide, R 8 represents hydrogen, or C 1-4 alkyl group, and q is 0 or 1, and an acetylenic glycol of the formula: ##STR6## wherein y and z range from 0-6 and the sum of y and z does not exceed 7; m and n combined range from 1-6; and R 1 , R 2 , R 3 , R 4 , R 5 and R 6 are hydrogen or methyl groups and may be like or unlike in the structure.

Claim 21

A process of claim 17 wherein said alkylene oxide adduct is an ethylene oxide or propylene oxide adduct of diethyltoluenediamine or tertiary-butyl-toluenediamine.

Claim 22

The process of claim 18 wherein said acetylenic glycol is 2.4,7,9-tetramethyl-5-decyne-4,7 diol.

Claim 23

The process of claim 19 wherein said crosslinker system contains from 40-95% by weight of the alkylene oxide adduct of diethyltoluenediamine or tertiary-butyl-toluenediamine.