Production of melt consistent aromatic polyesters

Claim 2

A melt-processable wholly aromatic polyester having reproducible melting and crystallization temperatures; said polyester having been made by bulk polymerization, including heat condensing wholly aromatic precursors to form a prepolymer in the presence of an alkali or alkaline earth metal salt, and advancing the prepolymer to the required degree of polymerization; said metal salt being added in an amount effective to render said melting and crystallization temperatures substantially reproducible with respect to melt processing of said polyester; and said polyester being an oxybenzoyl polyester which comprises recurrent moieties of the following formulas: ##STR7## where n is zero or one; q:r is about 10:15 to 15:10; p:(q+r) is greater than about 1:4; p+q+r is about 5 to 600; the carbonyl groups of the moiety of formula VII or VIII are linked to the oxy groups of the moiety of formula VII or IXa; and the oxy groups of the moiety of formula VII or IXa are linked to the carbonyl groups of the moiety of formula VII or VIII.

Claim 3

An injection molded article comprising the aromatic polyester of claim 1.

Claim 4

The polyester of claim 1 wherein the precursors comprise an aromatic dicarboxylic acid, a hydroxycarboxylic acid and an aromatic diol.

Claim 5

The polyester of claim 3 wherein said precursors comprise terephthalic acid, hydroxybenzoic acid and dihydroxybiphenyl.

Claim 6

The polyester of claim 3 wherein condensation of said precursors is by alkanoylation with an acid anhydride.

Claim 7

The polyester of claim 4 wherein the molar ratios of said precursors are about 1:2:1, respectively.

Claim 8

The polyester of claim 1 wherein said melting temperature is at least about 378° C.

Claim 9

The polyester of claim 1 wherein said metal salt is added in the amount of about 0.0025 to 0.05% by weight.

Claim 10

The polyester of claim 1 wherein said metal salt is added with the precursor charge.

Claim 11

The polyester of claim 1 wherein said metal salt is an inorganic salt of potassium or magnesium.

Claim 12

The polyester of claim 10 wherein said metal salt is a sulfate or chloride.

Claim 13

The polyester of claim 11 wherein said metal salt is potassium sulfate.

Claim 14

A melt-processable wholly aromatic polyester having reproducible melting and crystallization temperatures; said polyester having been made by bulk polymerization, including heat condensing wholly aromatic precursors to form a prepolymer in the presence of an alkali or alkaline earth metal salt, and advancing the prepolymer to the required degree of polymerization; said precursors being an aromatic dicarboxylic acid, a hydroxycarboxylic acid, and an aromatic diol; said metal salt being an inorganic salt of potassium or magnesium; said metal salt being added with the charge of precursors, in an amount effective to render said melting and crystallization temperatures substantially reproducible with respect to melt processing of said polyester and within the range of about 0.0025 to 0.05% by weight; and said polyester being an oxybenzoyl polyester which comprises recurrent moieties of the following formulas: ##STR8## where n is zero or one; q:r is about 10:15 to 15:10; p:(q+r) is greater than about 1:4; p+q+r is about 5 to 600; the carbonyl groups of the moiety of formula VII or VIII are linked to the oxy groups of the moiety of formula VII or IXa; and the oxy groups of the moiety of formula VII or IXa are linked to the carbonyl groups of the moiety of formula VII or VIII.

Claim 15

A melt-processable wholly aromatic polyester having reproducible melting and crystallization temperatures; said polyester having been made by bulk polymerization, including heat condensing wholly aromatic precursors to form a prepolymer in the presence of an alkali or alkaline earth metal salt, and advancing the prepolymer to the required degree of polymerization; said precursors being an aromatic dicarboxylic acid, a hydroxycarboxylic acid, and an aromatic diol; said metal salt being an inorganic salt of potassium or magnesium; said metal salt being added with the charge of precursors, in an amount effective to render said melting and crystallization temperatures substantially reproducible with respect to melt processing of said polyester and within the range of about 0.0025 to 0.05% by weight; and said polyester being an oxybenzoyl polyester which comprises recurrent moieties of the following formulas: ##STR8## where n is zero or one; q:r is about 10:15 to 15:10; p:(q+r) is greater than about 1:4; p+q+r is about 5 to 600; the carbonyl groups of the moiety of formula VII or VIII are linked to the oxy groups of the moiety of formula VII or IXa; and the oxy groups of the moiety of formula VII or IXa are linked to the carbonyl groups of the moiety of formula VII or VIII.

Claim 16

A melt-processable wholly aromatic polyester having reproducible melting and crystallization temperatures; said polyester having been made by bulk polymerization, including heat condensing wholly aromatic precursors to form a prepolymer in the presence of an alkali or alkaline earth metal salt, and advancing the prepolymer to the required degree of polymerization; said precursors being terephthalic acid, hydroxybenzoic acid and dihydroxybiphenyl; said metal salt being a sulfate or chloride of potassium or magnesium; said metal salt being added with the charge of precursors, in an amount effective to render said melting and crystallization temperatures substantially reproducible with respect to injection molding of said polyester and within the range of about 0.0025 to 0.05% by weight; said polyester having a melting temperature of at least about 378° C.; and said polyester being an oxybenzoyl polyester which comprises recurrent moieties of the following formulas: ##STR9## where q:r is about 10:15 to 15:10; p:(q+r) is greater than about 1:4; p+q+r is about 5 to 600; the carbonyl groups of the moiety of formula VII or VIIIa are linked to the oxy groups of the moiety of formula VII or IXc; and the oxy groups of the moiety of formula VII or IXc are linked to the carbonyl groups of the moiety of formula VII or VIIIa.

Claim 17

A melt-processable wholly aromatic polyester having reproducible melting and crystallization temperatures; said polyester having been made by bulk polymerization, including heat condensing wholly aromatic precursors to form a prepolymer in the presence of an alkali or alkaline earth metal salt, and advancing the prepolymer to the required degree of polymerization; said precursors being terephthalic acid, hydroxybenzoic acid and dihydroxybiphenyl; said metal salt being a sulfate or chloride of potassium or magnesium; said metal salt being added with the charge of precursors, in an amount effective to render said melting and crystallization temperatures substantially reproducible with respect to injection molding of said polyester and within the range of about 0.0025 to 0.05% by weight; said polyester having a melting temperature of at least about 378° C.; and said polyester being an oxybenzoyl polyester which comprises recurrent moieties of the following formulas: ##STR9## where q:r is about 10:15 to 15:10; p:(q+r) is greater than about 1:4; p+q+r is about 5 to 600; the carbonyl groups of the moiety of formula VII or VIIIa are linked to the oxy groups of the moiety of formula VII or IXc; and the oxy groups of the moiety of formula VII or IXc are linked to the carbonyl groups of the moiety of formula VII or VIIIa.

Claim 18

An injection molded article comprising the aromatic polyester of claim 14.

Claim 19

A process for making a melt-processable wholly aromatic polyester having reproducible melting and crystallization temperatures, comprising: heat condensing, in bulk, wholly aromatic precursors to form a prepolymer in the presence of an alkali or alkaline earth metal salt; and linked to the oxy groups of the moiety of formula VII or IXa; and the oxy groups of the moiety of formula VII or IXa are linked to the carbonyl groups of the moiety of formula VII or VIII.

Claim 20

A process for making a melt-processable wholly aromatic polyester having reproducible melting and crystallization temperatures, comprising: heat condensing, in bulk, wholly aromatic precursors to form a prepolymer in the presence of an alkali or alkaline earth metal salt; and linked to the oxy groups of the moiety of formula VII or IXa; and the oxy groups of the moiety of formula VII or IXa are linked to the carbonyl groups of the moiety of formula VII or VIII.

Claim 21

The polyester of claim 14 wherein the molar ratios of said precursors are about 1:2:1, respectively.

Claim 22

The polyester of claim 14 wherein condensation of said precursors is by alkanoylation with an acid anhydride.

Claim 23

The polyester of claim 13 wherein condensation of said precursors is by alkanoylation with an acid anhydride.