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US4742012A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of making graded junction containing amorphous semiconductor device

Assignee: Tonen General Sekiyu KK
•
Filing: 1986-12-30
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Granted: 1988-05-03
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Expires: 2006-12-30
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Abstract

Abstract This invention discloses a new semiconductor device having no step type p-i-n juctions but rather has a graded p-i-n juction. The semiconductor device shows a high photoelectric conversion efficiency, and since said device can be produced easily with good reproducibility by a plasma discharge method, it is especially suited for use as a solar battery. An apparatus for the production of said semiconductor device is also disclosed.

Inventors

  • 👤 Mitsuo Matsumura
  • 👤 Hideo Yamamoto
  • 👤 Keitaro Fukui
  • 👤 Toshihiro Yoshida
  • 👤 Yoshinobu Okayasu
  • 👤 Kunio Asai
  • 👤 Osamu Nakamura

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 23:54
CPC Classifications
H; H10; H10F; H10F10/00; H10F10/10; H10F10/17; H10F10/13; H10F71/00; H10F71/10; H10F71/107; Y; Y02; Y02E; Y02E10/00; Y02E10/50; Y02E10/548; Y02P; Y02P70/00; Y02P70/50

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 158 words
In a method to produce an amorphous P-I-N or N-I-P junction by a plasma decomposition technique, the improvement comprising using an apparatus having a single film forming chamber which is so designed that a dopant gas concentration can be controlled according to a position in the chamber and forming on a base plate a p-type layer or a n-type layer containing a dopant impurity continuously decreasing to zero, then forming an i-type layer containing no dopant impurity on said p-type layer n-type layer and then forming on the i-type layer the other of said n-type layer or p-type layer containing dopant impurity continuously increasing from zero to a predetermined amount continuously to form a graded P-I-N or N-I-P junction amorphous semiconductor device, in which process the layer is changed by controlling the concentration of each respective dopant in a raw gas, the dopant concentration in the raw material gas varying as a function of position in the chamber.
Claim 2
Dependent Claim 158 words
In a method to produce an amorphous P-I-N or N-I-P junction by a plasma decomposition technique, the improvement comprising using an apparatus having a single film forming chamber which is so designed that a dopant gas concentration can be controlled according to a position in the chamber and forming on a base plate a p-type layer or a n-type layer containing a dopant impurity continuously decreasing to zero, then forming an i-type layer containing no dopant impurity on said p-type layer n-type layer and then forming on the i-type layer the other of said n-type layer or p-type layer containing dopant impurity continuously increasing from zero to a predetermined amount continuously to form a graded P-I-N or N-I-P junction amorphous semiconductor device, in which process the layer is changed by controlling the concentration of each respective dopant in a raw gas, the dopant concentration in the raw material gas varying as a function of position in the chamber.
Claim 3
Dependent Claim 40 words
A method as claimed in claim 1, wherein said apparatus has a plurality of feedstock gas supply ports and a plurality of gas discharge ports in the film forming chamber to continuously control the distribution of the dopant gas concentration.
Claim 4
Independent Claim 32 words
A method as claimed in claims 1 or 2, wherein said apparatus has a plurality of baffle plates in the film forming chamber to control the distribution of the dopant gas concentration.
Claim 5
Dependent Claim 20 words
A method as claimed in claim 3, wherein said baffle plates are provided transverse to the direction of gas flow.
Claim 6
Dependent Claim 30 words
A method as claimed in claim 1, wherein the pressure in the chamber is maintained at a constant pressure selected from a pressure range of 0.01 torr to 10 torr.
Claim 7
Dependent Claim 17 words
A method as claimed in claim 5, wherein a hydrogen compound is used as the dopant gas.

References Cited (Backward Citations)

US4490208A Cited
JPS58132983A Cited
JPS5925278A Cited
JPS5952883A Cited
JPS59125618A Cited
JPS59229878A Cited
US4576830A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-05-03 1991-11-02 1992-05-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-05-03 1995-11-02 1996-05-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-05-03 1999-11-02 2000-05-03 $7700.00 Window Closed / Lapsed

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