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US4740550A Expired / Lapsed US ⏱️ 0.0 years remaining

Multistage copolymerization process

Assignee: Union Carbide Chemicals and Plastics Technology LLC
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Filing: 1986-06-18
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Granted: 1988-04-26
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Expires: 2006-06-18
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Abstract

Abstract The present invention relates to a multistage, continuous process for the preparation of propylene-ethylene impact copolymers comprising the use of a recirculating pipe-loop reactor for homopolymerizing propylene, a cyclone separator for removing fines, a gas-phase fluidized bed reactor for additional propylene homopolymerization, and a gas-phase fluidized bed reactor for propylene/ethylene copolymerization.

Inventors

  • 👤 E. Gordon Foster

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 08:10
CPC Classifications
C; C08; C08F; C08F297/00; C08F297/06; C08F297/08; C08F297/083; B; B01; B01J; B01J19/00; B01J19/24; B01J19/2415; B01J19/2435; B01J3/00; B01J3/008; B01J8/00; B01J8/18; B01J8/24; B01J8/26; C08F10/00; C08F10/04; C08F10/06

Claims Analysis

Total Claims: 18
Claim 1
Independent Claim 162 words
A continuous process for the preparation of propylene-ethylene impact copolymers comprising: (a) homopolymerizing propylene in one or more recirculating pipe-loop reactor(s) in the presence of a liquid medium or high density super-critical phase comprising propylene monomer as a major constituent and in the presence of magnesium chloride and titanium-containing catalyst particles, resulting in a homopolymer slurry; (b) transferring said homopolymer slurry to a separator and separating a fines stream having a particle size below about 30 times the diameter of the catalyst particles, resulting in a reduced-fines homopolymer slurry; (c) transferring said reduced-fines homopolymer slurry to a gas-phase fluidized bed homopolymer reactor and homopolymerizing additional propylene; (d) removing a stream of propylene homopolymer particles from said gas-phase fluidized bed homopolymer reactor and transferring the stream to a gas-phase fluidized bed copolymer reactor; (e) copolymerizing ethylene and propylene in said copolymer reactor, resulting in a propylene-ethylene impact copolymer; and (f) removing said propylene-ethylene impact copolymer as a product stream from said copolymer reactor.
Claim 2
Dependent Claim 162 words
A continuous process for the preparation of propylene-ethylene impact copolymers comprising: (a) homopolymerizing propylene in one or more recirculating pipe-loop reactor(s) in the presence of a liquid medium or high density super-critical phase comprising propylene monomer as a major constituent and in the presence of magnesium chloride and titanium-containing catalyst particles, resulting in a homopolymer slurry; (b) transferring said homopolymer slurry to a separator and separating a fines stream having a particle size below about 30 times the diameter of the catalyst particles, resulting in a reduced-fines homopolymer slurry; (c) transferring said reduced-fines homopolymer slurry to a gas-phase fluidized bed homopolymer reactor and homopolymerizing additional propylene; (d) removing a stream of propylene homopolymer particles from said gas-phase fluidized bed homopolymer reactor and transferring the stream to a gas-phase fluidized bed copolymer reactor; (e) copolymerizing ethylene and propylene in said copolymer reactor, resulting in a propylene-ethylene impact copolymer; and (f) removing said propylene-ethylene impact copolymer as a product stream from said copolymer reactor.
Claim 3
Dependent Claim 20 words
The process of claim 1 wherein at least a portion of said fines stream is recycled to said pipe-loop reactor(s).
Claim 4
Dependent Claim 20 words
The process of claim 1 wherein at least a portion of said fines stream is recovered as a separate stream.
Claim 5
Dependent Claim 22 words
The process of claim 1 wherein at least a portion of said fines stream is combined with said impact copolymer product stream.
Claim 6
Dependent Claim 23 words
The process of claim 1 wherein said fines stream has a particle size below about 20 times the diameter of the catalyst particles.
Claim 7
Dependent Claim 27 words
The process of claim 1 wherein 50 to 95 weight percent of the homopolymer portion of the impact copolymer product is produced in said pipe loop reactor(s).
Claim 8
Dependent Claim 13 words
The process of claim 1 wherein only one pipe loop reactor is used.
Claim 9
Dependent Claim 161 words
A continuous process for the preparation of propylene-ethylene impact copolymers comprising: (a) homopolymerizing propylene in one or more recirculating pipe-loop reactor(s) in the presence of a liquid medium or high density supercritical phase comprising propylene monomer as a major constituent and in the presence of magnesium chloride and titanium-containing catalyst particles, resulting in a homopolymer slurry; (b) transferring said homopolymer slurry to a gas-phase fluidized bed homopolymer reactor and homopolymerizing additional propylene; (c) removing a stream of propylene homopolymer particles from said gas-phase fluidized bed homopolymer reactor, transferring the stream to a separator and separating a fines stream having a particle size below about 30 times the diameter of the catalyst particles, resulting in a reduced-fines homopolymer slurry; (d) transferring said reduced-fines homopolymer slurry to a gas-phase fluidized bed copolymer reactor; (e) copolymerizing ethylene and propylene in said copolymer reactor, resulting in a propylene-ethylene impact copolymer; and (f) removing said propylene-ethylene impact copolymer as a product stream from said copolymer reactor.
Claim 10
Dependent Claim 161 words
A continuous process for the preparation of propylene-ethylene impact copolymers comprising: (a) homopolymerizing propylene in one or more recirculating pipe-loop reactor(s) in the presence of a liquid medium or high density supercritical phase comprising propylene monomer as a major constituent and in the presence of magnesium chloride and titanium-containing catalyst particles, resulting in a homopolymer slurry; (b) transferring said homopolymer slurry to a gas-phase fluidized bed homopolymer reactor and homopolymerizing additional propylene; (c) removing a stream of propylene homopolymer particles from said gas-phase fluidized bed homopolymer reactor, transferring the stream to a separator and separating a fines stream having a particle size below about 30 times the diameter of the catalyst particles, resulting in a reduced-fines homopolymer slurry; (d) transferring said reduced-fines homopolymer slurry to a gas-phase fluidized bed copolymer reactor; (e) copolymerizing ethylene and propylene in said copolymer reactor, resulting in a propylene-ethylene impact copolymer; and (f) removing said propylene-ethylene impact copolymer as a product stream from said copolymer reactor.
Claim 11
Dependent Claim 20 words
The process of claim 8 wherein at least a portion of said fines stream is recycled to said pipe-loop reactor(s).
Claim 12
Dependent Claim 23 words
The process of claim 8 wherein at least a portion of said fines stream is recycled to said gas-phase fluidized bed homopolymer reactor.
Claim 13
Dependent Claim 22 words
The process of claim 8 wherein at least a portion of said fines stream is combined with said impact copolymer product stream.
Claim 14
Dependent Claim 23 words
The process of claim 8 wherein said fines stream has a particle size below about 20 times the diameter of the catalyst particles.
Claim 15
Dependent Claim 27 words
The process of claim 8 wherein 50 to 95 weight percent of the homopolymer portion of the impact copolymer product is produced in said pipe loop reactor(s).
Claim 16
Dependent Claim 13 words
The process of claim 8 wherein only one pipe loop reactor is used.
Claim 17
Dependent Claim 28 words
The process of claim 1 wherein a portion of propylene monomer vaporized in the gas-phase fluidized bed homopolymer reactor is removed, condensed and recycled to said pipe-loop reactor(s).
Claim 18
Dependent Claim 28 words
The process of claim 8 wherein a portion of propylene monomer vaporized in the gas-phase fluidized bed homopolymer reactor is removed, condensed and recycled to said pipe-loop reactor(s).

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-04-26 1991-10-26 1992-04-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-04-26 1995-10-26 1996-04-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-04-26 1999-10-26 2000-04-26 $7700.00 Window Closed / Lapsed

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