Control of atmosphere in for example fruit stores

Claim 1

A method for controlling CO 2 build-up in an atmosphere in a closed cold storage warehouse for fresh fruit which, by respiring, is taking-up oxygen from the warehouse atmosphere and releasing CO 2 to the warehouse atmosphere, comprising: providing a container of adsorptive medium which more strongly adsorbs CO 2 than it does O 2 and N 2 , an expansible/collapsible gas reservoir at atmospheric pressure, and valved gas passages: (i) between said warehouse and said container of adsorptive medium, (ii) between said container of adsorptive medium and said gas reservoir, and (iii) between said gas reservoir and external atmosphere relative to said warehouse; and repeatedly conducting the following sequence of steps while refrigerating said atmosphere of said warehouse down to about 3.5° C. and about 90 percent relative humidity: (a) opening gas passage (i) while gas passages (ii) and (iii) remain closed, at a time when said atmosphere of said warehouse contains an excess of CO 2 and a deficit of O 2 in relation to external atmospheric air, until said adsorptive medium is substantially saturated with CO 2 ; (b) closing gas passage (i) and opening gas passage (ii) while gas passage (iii) remains closed, and evacuating the atmosphere in said container into said gas reservoir, by vacuum pumping through gas passage (ii), until the pressure in said container is about 7 kPa but the pressure in said gas reservoir remains at about 1 atmosphere, so that said gas reservoir expands and becomes filled with O 2 and N 2 substantially in the same proportions in which those gases then exist in said atmosphere of said warehouse, but CO 2 in a lower proportion than that in which CO 2 then exists in said atmosphere of said warehouse; (c) closing gas passage (ii) and opening gas passage (iii) while gas passage (i) remains closed and permitting CO 2 which has become adsorbed in said adsorptive medium to purge therefrom to atmosphere externally of said warehouse atmosphere until the amount of CO 2 present in said container at the beginning of this step has substantially diminished; (d) while gas passages (i) and (ii) remain closed, evacuating the atmosphere of said container, to waste, by vacuum pumping through gas passage (iii), until the pressure in said container is about 7 kPa, thereby removing O 2 and N 2 from said container in external atmosphere proportions; and (e) closing gas passage (iii) and opening gas passage (ii) while gas passage (i) remains closed, and thereby permitting said container to become refilled from said gas reservoir as said gas reservoir collapses, with an atmosphere which contains O 2 and N 2 in proportions approximating those then present in said warehouse atmosphere, but CO 2 in a lower proportion than that in which CO 2 then exists in said warehouse atmosphere.

Claim 2

A method for controlling CO 2 build-up in an atmosphere in a closed cold storage warehouse for fresh fruit which, by respiring, is taking-up oxygen from the warehouse atmosphere and releasing CO 2 to the warehouse atmosphere, comprising: providing a container of adsorptive medium which more strongly adsorbs CO 2 than it does O 2 and N 2 , an expansible/collapsible gas reservoir at atmospheric pressure, and valved gas passages: (i) between said warehouse and said container of adsorptive medium, (ii) between said container of adsorptive medium and said gas reservoir, and (iii) between said gas reservoir and external atmosphere relative to said warehouse; and repeatedly conducting the following sequence of steps while refrigerating said atmosphere of said warehouse down to about 3.5° C. and about 90 percent relative humidity: (a) opening gas passage (i) while gas passages (ii) and (iii) remain closed, at a time when said atmosphere of said warehouse contains an excess of CO 2 and a deficit of O 2 in relation to external atmospheric air, until said adsorptive medium is substantially saturated with CO 2 ; (b) closing gas passage (i) and opening gas passage (ii) while gas passage (iii) remains closed, and evacuating the atmosphere in said container into said gas reservoir, by vacuum pumping through gas passage (ii), until the pressure in said container is about 7 kPa but the pressure in said gas reservoir remains at about 1 atmosphere, so that said gas reservoir expands and becomes filled with O 2 and N 2 substantially in the same proportions in which those gases then exist in said atmosphere of said warehouse, but CO 2 in a lower proportion than that in which CO 2 then exists in said atmosphere of said warehouse; (c) closing gas passage (ii) and opening gas passage (iii) while gas passage (i) remains closed and permitting CO 2 which has become adsorbed in said adsorptive medium to purge therefrom to atmosphere externally of said warehouse atmosphere until the amount of CO 2 present in said container at the beginning of this step has substantially diminished; (d) while gas passages (i) and (ii) remain closed, evacuating the atmosphere of said container, to waste, by vacuum pumping through gas passage (iii), until the pressure in said container is about 7 kPa, thereby removing O 2 and N 2 from said container in external atmosphere proportions; and (e) closing gas passage (iii) and opening gas passage (ii) while gas passage (i) remains closed, and thereby permitting said container to become refilled from said gas reservoir as said gas reservoir collapses, with an atmosphere which contains O 2 and N 2 in proportions approximating those then present in said warehouse atmosphere, but CO 2 in a lower proportion than that in which CO 2 then exists in said warehouse atmosphere.

Claim 3

A method for controlling CO 2 build-up in an atmosphere in a closed cold storage warehouse for fresh fruit which, by respiring, is taking-up oxygen from the warehouse atmosphere and releasing CO 2 to the warehouse atmosphere, comprising: providing a container of adsorptive medium which more strongly adsorbs CO 2 than it does O 2 and N 2 , an expansible/collapsible gas reservoir at atmospheric pressure, and valved gas passages: (i) between said warehouse and said container of adsorptive medium, (ii) between said container of adsorptive medium and said gas reservoir, and (iii) between said gas reservoir and external atmosphere relative to said warehouse; and repeatedly conducting the following sequence of steps while refrigerating said atmosphere of said warehouse: (a) opening gas passage (i) while gas passages (ii) and (iii) remain closed, at a time when said atmosphere of said warehouse contains an excess of CO 2 and a deficit of O 2 in relation to external atmospheric air, until said absorptive medium is substantially saturated with CO 2 ; (b) closing gas passage (i) and opening gas passage (ii) while gas passage (iii) remains closed, and evacuating the atmosphere in said container into said gas reservoir, by vacuum pumping through gas passage (ii), until the pressure in said container is from 5 kPa to 10 kPa but the pressure in said gas reservoir remains at about 1 atmosphere, so that said gas reservoir expands and becomes filled with O 2 and N 2 substantially in the same proportions in which those gases then exist in said atmosphere of said warehouse, but CO 2 in a lower proportion than that in which CO 2 then exists in said atmosphere of said warehouse; (c) closing gas passage (ii) and opening gas passage (iii) while gas passage (i) remains closed and permitting CO 2 which has become absorbed in said absorptive medium to purge therefrom to atmosphere externally of said warehouse atmosphere until the amount of CO 2 present in said container at the beginning of this step has substantially diminished; (d) while gas passages (i) and (ii) remain closed, evacuating the atmosphere of said container, to waste, by vacuum pumping through gas passage (iii), until the pressure in said container is from 5 kPa to 10 kPa thereby removing O 2 and N 2 from said container in external atmosphere proportions; and (e) closing gas passage (iii) and opening gas passage (ii) while gas passage (i) remains closed, and thereby permitting said container to become refilled from said gas reservoir as said gas reservoir collapses, with an atmosphere which contains O 2 and N 2 in proportions approximating those then present in said warehouse atmosphere, but CO 2 in a lower proportion than that in which CO 2 then exists in said warehouse atmosphere.

Claim 4

A method for controlling CO 2 build-up in an atmosphere in a closed cold storage warehouse for fresh fruit which, by respiring, is taking-up oxygen from the warehouse atmosphere and releasing CO 2 to the warehouse atmosphere, comprising: providing a container of adsorptive medium which more strongly adsorbs CO 2 than it does O 2 and N 2 , an expansible/collapsible gas reservoir at atmospheric pressure, and valved gas passages: (i) between said warehouse and said container of adsorptive medium, (ii) between said container of adsorptive medium and said gas reservoir, and (iii) between said gas reservoir and external atmosphere relative to said warehouse; and repeatedly conducting the following sequence of steps while refrigerating said atmosphere of said warehouse: (a) opening gas passage (i) while gas passages (ii) and (iii) remain closed, at a time when said atmosphere of said warehouse contains an excess of CO 2 and a deficit of O 2 in relation to external atmospheric air, until said absorptive medium is substantially saturated with CO 2 ; (b) closing gas passage (i) and opening gas passage (ii) while gas passage (iii) remains closed, and evacuating the atmosphere in said container into said gas reservoir, by vacuum pumping through gas passage (ii), until the pressure in said container is from 5 kPa to 10 kPa but the pressure in said gas reservoir remains at about 1 atmosphere, so that said gas reservoir expands and becomes filled with O 2 and N 2 substantially in the same proportions in which those gases then exist in said atmosphere of said warehouse, but CO 2 in a lower proportion than that in which CO 2 then exists in said atmosphere of said warehouse; (c) closing gas passage (ii) and opening gas passage (iii) while gas passage (i) remains closed and permitting CO 2 which has become absorbed in said absorptive medium to purge therefrom to atmosphere externally of said warehouse atmosphere until the amount of CO 2 present in said container at the beginning of this step has substantially diminished; (d) while gas passages (i) and (ii) remain closed, evacuating the atmosphere of said container, to waste, by vacuum pumping through gas passage (iii), until the pressure in said container is from 5 kPa to 10 kPa thereby removing O 2 and N 2 from said container in external atmosphere proportions; and (e) closing gas passage (iii) and opening gas passage (ii) while gas passage (i) remains closed, and thereby permitting said container to become refilled from said gas reservoir as said gas reservoir collapses, with an atmosphere which contains O 2 and N 2 in proportions approximating those then present in said warehouse atmosphere, but CO 2 in a lower proportion than that in which CO 2 then exists in said warehouse atmosphere.