US4739094A — Alkoxylated aminopolyethers, a process for their …

Claim 1

Independent Claim 183 words

An alkoxylated aminopolyether of the formula (I) ##STR9## in which Q denotes a polyalkylene oxide radical which has a valency corresponding to n, which has a structure derived from an aminopolyether by removal of the terminal amino groups and which has an average molecular weight of 82 to 30,000, A 1 and A 2 denote identical or different mono- or polyalkylene oxide radicals of the type (RO) y , wherein each radical R represents an alkylene radical with 2 to 40 C atoms and y represents an integer from 1 to 200, B 1 and B 2 denote identical or different mono- or polyalkylene oxide radicals of the type (R'O) z , wherein at least 50% of the R' radicals represent a --CH 2 --CH 2 -- group, the other R' radicals which may be present each represent an alkylene radical with 3 to 40 C atoms and z represents an integer from 1 to 300, Z denotes hydrogen, ##STR10## wherein M.sup.⊕ represents one equivalent of a metal ion or represents NH 4 .sup.⊕ and n denotes an integer from 1 to 30.

Claim 2

Dependent Claim 183 words

An alkoxylated aminopolyether of the formula (I) ##STR9## in which Q denotes a polyalkylene oxide radical which has a valency corresponding to n, which has a structure derived from an aminopolyether by removal of the terminal amino groups and which has an average molecular weight of 82 to 30,000, A 1 and A 2 denote identical or different mono- or polyalkylene oxide radicals of the type (RO) y , wherein each radical R represents an alkylene radical with 2 to 40 C atoms and y represents an integer from 1 to 200, B 1 and B 2 denote identical or different mono- or polyalkylene oxide radicals of the type (R'O) z , wherein at least 50% of the R' radicals represent a --CH 2 --CH 2 -- group, the other R' radicals which may be present each represent an alkylene radical with 3 to 40 C atoms and z represents an integer from 1 to 300, Z denotes hydrogen, ##STR10## wherein M.sup.⊕ represents one equivalent of a metal ion or represents NH 4 .sup.⊕ and n denotes an integer from 1 to 30.

Claim 3

Dependent Claim 196 words

An alkoxylated aminopolyether according to claim 1, wherein in formula (1), independently of one another, Q denotes the radical of a polypropylene oxide, polyethylene/polypropylene oxide, polytetramethylene oxide or polytetramethylene oxide/polydecene oxide started from ethylene glycol, propylene glycol, trimethylolpropane, glycerol, pentaerythritol, ethylenediamine or hexamethylenediamine and in each case with an average molecular weight of 82 to 7,000, A 1 and A 2 denote identical or different mono- or polyalkylene oxide radicals of the type (RO) y , wherein each radical R represents an alkylene radical with 2 to 12 C atoms and y represents an integer from 1 to 80, B 1 and B 2 denote identical or different polyalkylene oxide radicals of the type (R'O) z , wherein 60 to 100% of the R' radicals represent a --CH 2 --CH 2 -- group, the other R' radicals which may be present each represent an alkylene radical with 3 to 12 C atoms and z represents an integer from 50 to 200, Z denotes hydrogen, ##STR11## wherein M.sup.⊕ represents one equivalent of a metal ion or represents NH 4 .sup.⊕, which forms soluble sulphonium, phosphonium or carboxyl salts, and n denotes an integer from 1 to 8.

Claim 4

Dependent Claim 20 words

An alkoxylated aminopolyether according to claim 1, wherein said alkoxylated amino polyether has a molecular weight of 10,000 to 150,000.

Claim 5

Dependent Claim 24 words

An alkoxylated aminoethyl according to claim 1, wherein M.sup.⊕ is an alkali metal ion or an alkaline earth metal ion or NH 4 .sup.⊕.

Claim 6

Dependent Claim 250 words

A process for the preparation of an alkoxylated aminopolyether of the formula (I) ##STR12## in which Q denotes a polyalkylene oxide radical which has a valency corresponding to n, which has a structure derived from an aminopolyether by removal of the terminal amino groups, and which as an average molecular weight of 82 to 30,000, A 1 and A 2 denote identical or different mono- or polyalkylene oxide radicals of the type (RO) y , wherein each radical R represents an alkylene radical with 2 to 40 C atoms and y represents an integer from 1 to 200, B 1 and B 2 denote identical or different mono- or polyalkylene oxide radicals of the type (R'O) z , wherein at least 50% of the R' radicals represent a --CH 2 --CH 2 -- group, the other R' radicals which may be present each represent an alkylene radical with 3 to 40 C atoms and z represents an integer from 1 to 300, Z denotes hydrogen, ##STR13## wherein M.sup.⊕ represents one equivalent of a metal ion or represents NH 4 .sup.⊕ and n denotes an integer from 1 to 30, said process comprising (a) adding a C 2 - to C 20 -alkylene oxide onto an aminopolyalkylene ether such that in each case at least two alkylene oxide units react with an amino group, (b) reacting the product of step (a) with ethylene oxide or a mixture of C 2 - to C 40 -epoxides, and (c) conducting neutralization or hydrolysis.

Claim 7

Dependent Claim 250 words

A process for the preparation of an alkoxylated aminopolyether of the formula (I) ##STR12## in which Q denotes a polyalkylene oxide radical which has a valency corresponding to n, which has a structure derived from an aminopolyether by removal of the terminal amino groups, and which as an average molecular weight of 82 to 30,000, A 1 and A 2 denote identical or different mono- or polyalkylene oxide radicals of the type (RO) y , wherein each radical R represents an alkylene radical with 2 to 40 C atoms and y represents an integer from 1 to 200, B 1 and B 2 denote identical or different mono- or polyalkylene oxide radicals of the type (R'O) z , wherein at least 50% of the R' radicals represent a --CH 2 --CH 2 -- group, the other R' radicals which may be present each represent an alkylene radical with 3 to 40 C atoms and z represents an integer from 1 to 300, Z denotes hydrogen, ##STR13## wherein M.sup.⊕ represents one equivalent of a metal ion or represents NH 4 .sup.⊕ and n denotes an integer from 1 to 30, said process comprising (a) adding a C 2 - to C 20 -alkylene oxide onto an aminopolyalkylene ether such that in each case at least two alkylene oxide units react with an amino group, (b) reacting the product of step (a) with ethylene oxide or a mixture of C 2 - to C 40 -epoxides, and (c) conducting neutralization or hydrolysis.

Claim 8

Dependent Claim 78 words

A process according to claim 5, wherein the reaction of an amino-polyalkylene ether with a C 2 - to C 12 -alkylene oxide is carried out at 50° to 150° C. and in the presence of a base, as a catalyst, and the reaction with ethylene oxide or a mixture of C 2 - to C 40 -epoxides is then carried out such that 50 to 200 ethylene oxide units per chain are introduced one after the other.

Claim 9

Dependent Claim 28 words

A process according to claim 5, wherein said amino-polyalkylene ether is an amino-polyalkylene ether with amino end groups and has an average molecular weight of 82 to 30,000.

Claim 10

Dependent Claim 34 words

A process according to claim 5, which further comprises reacting the product of step (b) with carboxylic acid anhydrides, amidusulphonic acids and urea, acid chlorides of sulphur or of phosphorus or chloroacetic acid esters.

Claim 11

Dependent Claim 21 words

A process according to claim 6, wherein said base is selected from the group consisting of alkali metal hydroxides and alcoholates.

Claim 12

Dependent Claim 26 words

A process according to claim 5, wherein the molar ratio of C 2 - to C 12 -alkylene oxide to amino-polyalkylene ether is 4:1 to 1,600:1.

Claim 13

Dependent Claim 25 words

An alkoylated aminopolyether according to claim 1, wherein z is 50 to 200 and Z denotes --SO 3 .sup.⊖ M.sup.⊕ or --CH 2 --COO.sup.⊖ M.sup.⊕.

Annuity Stage	Window Opens	Payment Deadline	Surcharge Period Until	Estimated Fee	Status
3.5 Years (Year 4)	1991-04-19	1991-10-19	1992-04-19	$2000.00	Window Closed / Lapsed
7.5 Years (Year 8)	1995-04-19	1995-10-19	1996-04-19	$3760.00	Window Closed / Lapsed
11.5 Years (Year 12)	1999-04-19	1999-10-19	2000-04-19	$7700.00	Window Closed / Lapsed

Alkoxylated aminopolyethers, a process for their preparation

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