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US4739012A Expired / Lapsed US ⏱️ 0.0 years remaining

Elastomer blends

Assignee: Advanced Polymer Compounding LP
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Filing: 1987-01-21
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Granted: 1988-04-19
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Expires: 2007-01-21
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Abstract

Abstract Blends of 5 to 97.5% of a segmented thermoplastic copolyester such as polybutylene terephthalate containing polybutane glycol segments with 95 to 20% of a blend of an ethylene copolymer and 5 to 75% either polyvinyl chloride or polyvinylidene chloride. The polyethylene copolymer is an elastomeric blend of polyvinyl chloride or polyvinylidene chloride with a copolymer of ethylene and esters of ethylenically unsaturated acids, vinyl esters, vinyl alkyl ethers, vinyl chloride, vinylidene chloride acrylonitrile, methacrylonitrile, norbornene, alpha-olefins of 3-12 carbon atoms and optionally ethylenically unsaturated carboxylic acids, carbon monoxide and sulfur dioxide. The blends are processable temperatures lower than either component they are prepared from.

Inventors

  • 👤 John F. Hagman

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 22:56
CPC Classifications
C; C08; C08L; C08L23/00; C08L23/02; C08L23/04; C08L23/08; C08L27/00; C08L27/02; C08L27/04; C08L27/06; C08L67/00; C08L67/02; C08L67/025; C08L73/00

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 364 words
A thermoplastic elastomeric blend having a lowered melt processing temperature comprising: (A) from 5 to 97.5 weight percent of a segmented thermoplastic copolyester composition consisting essentially of a multiplicity of recurring long-chain ester units and short-chain ester units joined head-to-tail through ester linkages, said long chain ester units being represented by the formula ##STR5## and said short-chain units being represented by the formula ##STR6## where G is a divalent radical remaining after the removal of terminal hydroxyl groups from a poly(alkylene oxide) glycol having a molecular weight of about 400-6,000 and a carbon to oxygen ratio of about 2.0-4.3; R is a divalent radical remaining after removal of carboxyl groups from one or more dicarboxylic acids having molecular weights less than about 300 and D is a divalent radical remaining after removal of hydroxyl groups from one or more diols having a molecular weight less than about 250; provided said short-chain ester units amount to about 15-95 percent by weight of said copolyester, and at least about 50 percent of said short-chain ester units are identical and (B) from 2.5 to 95 weight percent of a partially crosslinked, thermoplastic, melt-processible, elastomeric blend of (a) a copolymer of 30 to 85 weight percent repeating units derived from ethylene and the remainder repeating units derived from one or more ethylenically unsaturated organic comonomers selected from the class consisting of esters of ethylenically unsaturated C 3 -C 20 mono- or dicarboxylic acids, vinyl esters of saturated C 2 -C 18 carboxylic acids, vinyl alkyl ethers wherein the alkyl group has 1-8 carbon atoms, acrylonitrile, methacrylonitrile, norbornene, alpha-olefins of 3-12 carbon atoms, and vinyl aromatic compounds, and optionally up to 30 weight percent of an additional monomer selected from the class consisting of ethylenically unsaturated C 3 -C 20 carboxylic acids, carbon monoxide and sulfur dioxide; and (b) between 5 and 75 weight percent, based on composition (B), of a vinyl or vinylidene halide homopolymer or coolymer with a monomer selected from the group consisting of vinyl esters, acrylonitrile, esters of unsaturated carboxylic acids and vinyl ethers, wherein the comonomer content in (a) is such that the ethylene copolymer is compatible with the vinyl or vinylidene halide polymer.
Claim 2
Dependent Claim 364 words
A thermoplastic elastomeric blend having a lowered melt processing temperature comprising: (A) from 5 to 97.5 weight percent of a segmented thermoplastic copolyester composition consisting essentially of a multiplicity of recurring long-chain ester units and short-chain ester units joined head-to-tail through ester linkages, said long chain ester units being represented by the formula ##STR5## and said short-chain units being represented by the formula ##STR6## where G is a divalent radical remaining after the removal of terminal hydroxyl groups from a poly(alkylene oxide) glycol having a molecular weight of about 400-6,000 and a carbon to oxygen ratio of about 2.0-4.3; R is a divalent radical remaining after removal of carboxyl groups from one or more dicarboxylic acids having molecular weights less than about 300 and D is a divalent radical remaining after removal of hydroxyl groups from one or more diols having a molecular weight less than about 250; provided said short-chain ester units amount to about 15-95 percent by weight of said copolyester, and at least about 50 percent of said short-chain ester units are identical and (B) from 2.5 to 95 weight percent of a partially crosslinked, thermoplastic, melt-processible, elastomeric blend of (a) a copolymer of 30 to 85 weight percent repeating units derived from ethylene and the remainder repeating units derived from one or more ethylenically unsaturated organic comonomers selected from the class consisting of esters of ethylenically unsaturated C 3 -C 20 mono- or dicarboxylic acids, vinyl esters of saturated C 2 -C 18 carboxylic acids, vinyl alkyl ethers wherein the alkyl group has 1-8 carbon atoms, acrylonitrile, methacrylonitrile, norbornene, alpha-olefins of 3-12 carbon atoms, and vinyl aromatic compounds, and optionally up to 30 weight percent of an additional monomer selected from the class consisting of ethylenically unsaturated C 3 -C 20 carboxylic acids, carbon monoxide and sulfur dioxide; and (b) between 5 and 75 weight percent, based on composition (B), of a vinyl or vinylidene halide homopolymer or coolymer with a monomer selected from the group consisting of vinyl esters, acrylonitrile, esters of unsaturated carboxylic acids and vinyl ethers, wherein the comonomer content in (a) is such that the ethylene copolymer is compatible with the vinyl or vinylidene halide polymer.
Claim 3
Dependent Claim 31 words
The composition of claim 1 wherein Component A comprises from 5 to 80 weight percent of the composition and Component B comprises from 20 to 95 weight percent of the composition.
Claim 4
Dependent Claim 17 words
The blend of claim 2 wherein Component (B)(a) has a gel content of 10 to 90 percent.
Claim 5
Dependent Claim 10 words
The blend of claim 3 wherein (B)(b) is polyvinyl chloride.
Claim 6
Dependent Claim 40 words
The blend of claim 4 wherein the organic comonomers other than carbon monoxide, sulfur dioxide or ethylenically unsaturated carboxylic acid in (B)(a) are selected from the group consisting of methyl acrylate, butyl acrylate, vinyl acetate and maleic acid monoethyl ester.
Claim 7
Dependent Claim 38 words
The blend of claim 5 wherein up to 30 weight percent of the conomoner carbon monoxide, sulfur dioxide or an ethylenically unsaturated carboxylic acid and at least one percent of the monomers recited in claim 5 is present.
Claim 8
Dependent Claim 29 words
The composition of claim 6 wherein R is derived from dicarboxylic acids selected from the group consisting of phthalic acid, terephthalic acid, isophthalic acid, their esters and mixtures thereof.
Claim 9
Dependent Claim 21 words
The composition of claim 7 wherein the poly(alkylene oxide) glycol is poly(tetramethylene oxide) glycol having a molecular weight of about 600-2,000.
Claim 10
Dependent Claim 10 words
The composition of claim 8 wherein said diol is 1,4-butanediol.
Claim 11
Dependent Claim 10 words
A shaped article formed of the composition of claim 1.

References Cited (Backward Citations)

US3203937A Cited
US3718715A Cited
US4275180A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-04-19 1991-10-19 1992-04-19 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-04-19 1995-10-19 1996-04-19 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-04-19 1999-10-19 2000-04-19 $7700.00 Window Closed / Lapsed

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