Coating composition of a hydroxy group-containing modified polyester with polymerized lactone monomers

Claim 2

An organic solvent based, thermosetting coating composition comprising: (I) hydroxy functional urethane modified polyester resin having a number average molecular weight (M n ) of between about 2,000 and about 20,000, said resin being the product of polymerization of lactone monomers in the presence of hydroxy-containing urethane modified polyester precursor having reactive hydroxy groups, wherein the lactone monomers are polymerized and reacted with the hydroxy groups of the precursor to form polymeric chains attached to the precursor, said precursor (i) having a number average molecular weight (M n ) between about 1,000 and about 10,000, (ii) having a hydroxy number between about 30 and about 300, and (iii) containing between about 1 and about 10 urethane groups per molecule, wherein the polymerization reaction mixture comprises between about 10 and about 80 weight percent said hydroxy-containing urethane modified polyester precursor and between about 90 and about 20 weight percent said lactone monomers; and (II) amine-aldehyde crosslinking agent.

Claim 3

A solvent based, thermosetting coating composition in accordance with claim 1, wherein said hydroxy-containing urethane modified polyester precursor is the reaction product of: (A) urethane modified diol being the reaction product of: (a) diol and (b) diisocyanate, wherein said diol and said diisocyanate are reacted in a molar ratio from about 4:1 to about 4:3, respectively; (B) polyol comprising at least about 5 weight percent triol; and (C) acid component selected from dicarboxylic acids and anhydrides thereof.

Claim 4

A solvent based, thermosetting coating composition in accordance with claim 2, wherein said precursor has a number average molecular weight between about 2000 and about 4000.

Claim 5

A solvent based, thermosetting coating composition in accordance with claim 2, wherein said precursor has a hydroxyl number between about 30 and about 200.

Claim 6

A solvent based, thermosetting coating composition in accordance with claim 2, wherein said precursor has a hydroxyl number between about 50 and about 120.

Claim 7

A solvent based, thermosetting coating composition in accordance with claim 2, wherein said diol (a) and said diisocyanate (b) are reacted in a molar ratio of from about 2:0.8 to about 2:1.2.

Claim 8

A solvent based, thermosetting coating composition in accordance with claim 2, wherein said polyol further comprises diol.

Claim 9

A solvent based, thermosetting coating composition in accordance with claim 7, wherein said polyol comprises about 10-80 weight percent triol and about 90-20 weight percent diol.

Claim 10

A solvent based, thermosetting coating composition in accordance with claim 2, wherein said acid component is selected from C 6 -C 40 dicarboxylic acids and anhydrides thereof.

Claim 11

A solvent based, thermosetting coating composition in accordance with claim 1, wherein said hydroxy-containing urethane modified polyester precursor is the reaction product of: (A) hydroxy functional polyester resin being the reaction product of: (a) polyhydroxy material comprising diols and triols and (b) acid component selected from dicarboxylic acid and anhydrides thereof, wherein said (a) and (b) are reacted in amounts so as to provide hydroxyl groups and carboxyl groups in a ratio of from about 6:2 to about 6:5, respectively; and (B) diisocyanate. wherein said (A) and (B) are reacted in amounts so as to provide hydroxyl groups and isooyanate groups in a ratio of from about 4:1 to about 10:1, respectively.

Claim 12

A solvent based, thermosetting coating composition in accordance with claim 10, wherein said precursor has a number average molecular weight between about 2000 and about 4000.

Claim 13

A solvent based, thermosetting coating composition in accordance with claim 10, wherein said precursor has a hydroxyl number between about 50 and about 250.

Claim 14

A solvent based, thermosetting coating composition in accordance with claim 10, wherein said polyhydroxy material (a) comprises said diols and said triols in a hydroxyl equivalent ratio of from about 4:1 to about 1:4.

Claim 15

A solvent based, thermosetting coating composition in accordance with claim 10, wherein said polyhydroxy material (a) comprises said diols and said triols in a hydroxyl equivalent ratio of from about 3:1 to about 3:2.5.

Claim 16

A solvent based, thermosetting coating composition in accordance with claim 10, wherein said acid component is selected from C 6 -C 40 dicarboxylic acids and anhydrides thereof.

Claim 17

A solvent based, thermosetting coating composition in accordance with claim 1, wherein said lactone monomers are selected from those represented by the general formula: ##STR3## wherein n is at least 4, at least n+2 R's are H and the remaining R's are substituents selected from the group consisting of alkyl, cycloalkyl, alkoxy and single ring aromatic hydrocarbon radicals.

Claim 18

A solvent based, thermosetting coating composition in accordance with claim 16, wherein said lactone monomers comprise unsubstituted epsilon-caprolactone monomers.

Claim 19

A solvent based, thermosetting coating composition in accordance with claim 1, wherein said amine-aldehyde crosslinking agent is employed in an amount of from about 5 to about 50 weight percent based on the weight of said hydroxy functional urethane modified polyester resin present in said composition.

Claim 20

A solvent based, thermosetting coating composition in accordance with claim 1, wherein said amine-aldehyde crosslinking agent is selected from alkylated melamine aldehyde resins.

Claim 21

A solvent based, thermosetting coating composition in accordance with claim 1, adapted to be used as a chip resistant primer to be sprayed at elevated temperature, wherein the solids level of the composition is in the range of 60-80% by weight.

Claim 22

A solvent based, thermosetting coating composition comprising: (I) hydroxy functional urethane modified polyester resin having a number average molecular weight of between about 2,000 and about 20,000, said resin being the product of polymerization of epsilon-caprolactone monomers in the presence of hydroxy-containing urethane modified polyester precursor having reactive hydroxy groups, wherein the epsilon-caprolactone monomers being polymerized and reacted with the hydroxy groups of the precursor to form polymeric chains attached to the precursor, wherein the polymerization resin mixture comprises between about 10 and about 80 weight percent said hydroxy containing urethane modified polyester precursor and between about 90 and about 20 weight percent said epsilon-caprolactone monomers, said precursor (i) having a number average molecular weight between about 2,000 and about 4,000, (ii) having a hydroxy number between about 30 and about 200, and (iii) containing between about 1 and 10 urethane groups per molecule, said precursor being the reaction product of: (A) urethane modified diol being the reaction product of (a) diol selected from glycols, caprolactone diols, hydroxy alkylated bisphenols and polyester diols and (b) diisocyanate selected from alipahatic, cycloaliphatic and aromatic diisocyanates wherein said diol and said diisocyanate are reacted in a molar ratio from about 2:0.8 to about 2:1.8, respectively; (B) polyol comprising at least about 5 weight percent triol; and (C) acid component is selected from C 6 -C 40 dicarboxylic acid and anhydrides thereof; and (II) amine-aldehyde crosslinking agent selected from alkylated melamine aldehyde resins and employed in an amount of from about 5 to about 50 weight percent based on the weight of said hydroxy functional urethane modified polyester resin in said composition.

Claim 23

A solvent based, thermosetting coating composition comprising: (I) hydroxy functional urethane modified polyester resin having a number average molecular weight of between about 2,000 and about 20,000, said resin being the product of polymerization of epsilon-caprolactone monomers in the presence of hydroxy-containing urethane modified polyester precursor having reactive hydroxy groups, wherein the epsilon-caprolactone monomers being polymerized and reacted with the hydroxy groups of the precursor to form polymeric chains attached to the precursor, wherein the polymerization resin mixture comprises between about 10 and about 80 weight percent said hydroxy containing urethane modified polyester precursor and between about 90 and about 20 weight percent said epsilon-caprolactone monomers, said precursor (i) having a number average molecular weight between about 2,000 and about 4,000, (ii) having a hydroxy number between about 30 and about 200, and (iii) containing between about 1 and 10 urethane groups per molecule, said precursor being the reaction product of: (A) urethane modified diol being the reaction product of (a) diol selected from glycols, caprolactone diols, hydroxy alkylated bisphenols and polyester diols and (b) diisocyanate selected from alipahatic, cycloaliphatic and aromatic diisocyanates wherein said diol and said diisocyanate are reacted in a molar ratio from about 2:0.8 to about 2:1.8, respectively; (B) polyol comprising at least about 5 weight percent triol; and (C) acid component is selected from C 6 -C 40 dicarboxylic acid and anhydrides thereof; and (II) amine-aldehyde crosslinking agent selected from alkylated melamine aldehyde resins and employed in an amount of from about 5 to about 50 weight percent based on the weight of said hydroxy functional urethane modified polyester resin in said composition.