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US4735837A Expired / Lapsed US ⏱️ 0.0 years remaining

Removable adhesive sheet

Assignee: Nichiban Co Ltd
•
Filing: 1985-08-08
•
Granted: 1988-04-05
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Expires: 2005-08-08
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Abstract

Abstract A removable adhesive sheet comprising a substrate (A) and an adhesive composition layer which comprises elastic micro-balls (B) and an adhesive (C), the adhesive composition layer being formed on an adhesive layer forming surface of the substrate, wherein the mixing proportion of the elastic micro-balls (B) to the adhesive (C) in the adhesive composition layer is 1:10 to 10:1 in terms of weight ratio, and the protrusive areas of the elastic micro-balls (B) partially protruding from the surface of the adhesive composition layer is entirely covered with the adhesive (C) has an adhesion capability that is not lowered through a frequent repetition of bonding to and removing from an adherend.

Inventors

  • 👤 Hiroyasu Miyasaka
  • 👤 Yasuaki Kitazaki
  • 👤 Tetsuaki Matsuda
  • 👤 Junichi Kobayashi

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 02:07
CPC Classifications
G; G09; G09F; G09F3/00; G09F3/08; G09F3/10; C; C09; C09J; C09J7/00; C09J7/30; C09J7/38; C09J2301/00; C09J2301/20; C09J2301/204; C09J2301/40; C09J2301/412; Y; Y10; Y10T; Y10T428/00; Y10T428/14; Y10T428/1405; Y10T428/24; Y10T428/24777; Y10T428/24802; Y10T428/24826; Y10T428/249921; Y10T428/249953; Y10T428/249982; Y10T428/249984; Y10T428/249986; Y10T428/25; Y10T428/252; Y10T428/29; Y10T428/2982; Y10T428/2991; Y10T428/2993; Y10T428/2996

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 122 words
A removable adhesive sheet comprising a substrate (A) and an adhesive composition layer which comprises elastically deformable micro-balls (B), said micro-balls having a glass transition temperature ranging between -80° and 10° C., and an adhesive (C), the adhesive composition layer being formed on an adhesive layer-forming surface of the substrate, wherein (i) the mixing proportion of the elastic micro-balls (B) to the adhesive (C) in the adhesive composition layer is 1:10 to 10:1 in terms weight ratio and (ii) the protrusive areas of the elastic micro-balls (B) partially protruding form the surface of the adhesive composition layer is entirely covered with the adhesive (C), such that the adhesive sheet is repeatedly removable from contact between the adhesive composition layer and a surface.
Claim 2
Dependent Claim 122 words
A removable adhesive sheet comprising a substrate (A) and an adhesive composition layer which comprises elastically deformable micro-balls (B), said micro-balls having a glass transition temperature ranging between -80° and 10° C., and an adhesive (C), the adhesive composition layer being formed on an adhesive layer-forming surface of the substrate, wherein (i) the mixing proportion of the elastic micro-balls (B) to the adhesive (C) in the adhesive composition layer is 1:10 to 10:1 in terms weight ratio and (ii) the protrusive areas of the elastic micro-balls (B) partially protruding form the surface of the adhesive composition layer is entirely covered with the adhesive (C), such that the adhesive sheet is repeatedly removable from contact between the adhesive composition layer and a surface.
Claim 3
Dependent Claim 28 words
The removable adhesive sheet according to claim 1, wherein the particle diameter of the elastically deformable micro-balls (B) in the adhesive composition layer is 0.1 to 1,000 μm.
Claim 4
Dependent Claim 21 words
The removable adhesive sheet according to claim 1, wherein the thickness of said adhesive composition layer is 0.1 to 100 μm.
Claim 5
Dependent Claim 31 words
The removable adhesive sheet according to claim 1 wherein 100 to 1,000,000 pcs./cm 2 of the elastically deformable micro-balls (B) are distributed on the adhesive layer-forming surface of the substrate (A).
Claim 6
Dependent Claim 51 words
The removable adhesive sheet according to claim 1, wherein the adhesive composition layer is formed separately to have distributed areas on the adhesive layer forming surface of the substrate (A), and the percentage of the area of the adhesive composition layer relative to the adhesive layer-forming surface is 20 to 98%.
Claim 7
Dependent Claim 30 words
The removable adhesive sheet according to claim 1, wherein the mixing proportion of the elastic micro-balls (B) to the adhesive (C) in the adhesive composition layer is 1:5 to 5:1.
Claim 8
Dependent Claim 23 words
The removable adhesive sheet according to claim 2, wherein the particle diameter of the elastically deformable micro-balls (B) is 0.5 to 300 μm.
Claim 9
Dependent Claim 21 words
The removable adhesive sheet according to claim 3, wherein the thickness of the adhesive composition layer is 1 to 30 μm.
Claim 10
Dependent Claim 31 words
The removable adhesive sheet according to claim 4, wherein 1,000 to 150,000 pcs./cm 2 of the elastically deformable micro-balls (B) are distributed on the adhesive layer-forming surface of the substrate (A).
Claim 11
Dependent Claim 30 words
The removable adhesive sheet according to claim 5, wherein the percentage of the area of the adhesive composition layer relative to the adhesive layer-forming surface is of 20% to 90%.
Claim 12
Dependent Claim 23 words
The removable adhesive sheet according to claim 1, wherein the substrate (A) is a fibrous material or a film whose surface is smooth.
Claim 13
Dependent Claim 35 words
The removable adhesive sheet according to claim 1, wherein the elastically deformable micro-balls are comprised of high molecular polymers selected from a chain polymer, a graft polymer, a block polymer and a three-dimensional network polymer.
Claim 14
Dependent Claim 30 words
The removable adhesive sheet according to claim 1, wherein the elastically deformable micro-balls are the product of a process comprising the step of suspension polymerization of said micro-balls in water.

References Cited (Backward Citations)

US3386846A Cited
CH452479A Cited
US3691140A Cited
US3857731A Cited
US4442156A Cited
US4556595A Cited
US4415615A Cited
US4525416A Cited
US4589590A Cited
US4587152A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-04-05 1991-10-05 1992-04-05 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-04-05 1995-10-05 1996-04-05 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-04-05 1999-10-05 2000-04-05 $7700.00 Window Closed / Lapsed

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