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US4734514A Expired / Lapsed US ⏱️ 0.0 years remaining

Hydrocarbon-substituted analogs of phosphine and arsine, particularly for metal organic chemical vapor deposition

Assignee: ATK Launch Systems LLC
•
Filing: 1986-02-10
•
Granted: 1988-03-29
•
Expires: 2006-02-10
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Abstract

Abstract Organometallic compounds having the formulas: <IMAGE> wherein N is selected from phosphorus and arsenic, H is hydride, and X and Y are independently selected from hydride, lower alkyl cyclopentadienyl, and phenyl, except that Y cannot be hydrogen; and MRx wherein x is an integer from 2 to 4 inclusive, each said R substituent is independently selected from hydride, lower alkyl, phenyl, alkyl-substituted phenyl, cyclopentadienyl, and alkyl-substituted cyclopentadienyl, and M is selected from elements of Groups 2B, 2A, 3A, 5A, and 6A of the Periodic Table, except carbon, nitrogen, oxygen, and sulfur. The use of these compounds in chemical vapor deposition processes and methods for synthesizing these compounds are also disclosed.

Inventors

  • 👤 Andreas A. Melas
  • 👤 Benjamin C. Hui
  • 👤 Jorg Lorberth

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 15:22
CPC Classifications
C; C07; C07F; C07F9/00; C07F9/02; C07F9/28; C07F9/50; C07F9/505; C07C; C07C391/00; C07C395/00; C07F3/00; C07F3/02; C07F3/06; C07F3/08; C07F3/10; C07F3/12; C07F5/00; C07F5/02; C07F5/027; C07F5/06; C07F9/66; C07F9/70; C07F9/72; C07F9/90; C07F9/94; C23; C23C; C23C16/00; C23C16/06; C23C16/18; C23C16/22; C23C16/30; C23C16/301; C23C16/305; C23C16/306

Claims Analysis

Total Claims: 44
Claim 1
Independent Claim 597 words
A compound having the structure: ##STR7## wherein H is hydride and the respective identities of N, X, and Y are selected from the following table of species: ______________________________________ N X Y ______________________________________ arsenic hydride s-butyl arsenic hydride i-butyl arsenic hydride n-pentyl arsenic hydride i-pentyl arsenic hydride t-pentyl arsenic hydride neopentyl arsenic hydride cyclopentadienyl arsenic methyl i-propyl arsenic methyl n-butyl arsenic methyl s-butyl arsenic methyl i-butyl arsenic methyl t-butyl arsenic methyl n-pentyl arsenic methyl i-pentyl arsenic methyl t-pentyl arsenic methyl neopentyl arsenic methyl cyclopentadienyl arsenic ethyl n-propyl arsenic ethyl i-propyl arsenic ethyl n-butyl arsenic ethyl s-butyl arsenic ethyl i-butyl arsenic ethyl t-butyl arsenic ethyl n-pentyl arsenic ethyl i-pentyl arsenic ethyl t-pentyl arsenic ethyl neopentyl arsenic ethyl cyclopentadienyl arsenic ethyl phenyl arsenic n-propyl i-propyl arsenic n-propyl n-butyl arsenic n-propyl s-butyl arsenic n-propyl i-butyl arsenic n-propyl t-butyl arsenic n-propyl n-pentyl arsenic n-propyl i-pentyl arsenic n-propyl t-pentyl arsenic n-propyl neopentyl arsenic n-propyl cyclopentadienyl arsenic n-propyl phenyl arsenic i-propyl n-butyl arsenic i-propyl s-butyl arsenic i-propyl i-butyl arsenic i-propyl t-butyl arsenic i-propyl n-pentyl arsenic i-propyl i-pentyl arsenic i-propyl t-pentyl arsenic i-propyl neopentyl arsenic i-propyl cyclopentadienyl arsenic i-propyl phenyl arsenic n-butyl s-butyl arsenic n-butyl i-butyl arsenic n-butyl t-butyl arsenic n-butyl n-pentyl arsenic n-butyl i-pentyl arsenic n-butyl t-pentyl arsenic n-butyl neopentyl arsenic n-butyl cyclopentadienyl arsenic n-butyl phenyl arsenic s-butyl s-butyl arsenic s-butyl i-butyl arsenic s-butyl t-butyl arsenic s-butyl n-pentyl arsenic s-butyl i-pentyl arsenic s-butyl t-pentyl arsenic s-butyl neopentyl arsenic s-butyl cyclopentadienyl arsenic s-butyl phenyl arsenic i-butyl i-butyl arsenic i-butyl t-butyl arsenic i-butyl n-pentyl arsenic i-butyl i-pentyl arsenic i-butyl t-pentyl arsenic i-butyl neopentyl arsenic i-butyl cyclopentadienyl arsenic i-butyl phenyl arsenic t-butyl n-pentyl arsenic t-butyl i-pentyl arsenic t-butyl t-pentyl arsenic t-butyl neopentyl arsenic t-butyl cyclopentadienyl arsenic t-butyl phenyl arsenic n-pentyl n-pentyl arsenic n-pentyl i-pentyl arsenic n-pentyl t-pentyl arsenic n-pentyl neopentyl arsenic n-pentyl cyclopentadienyl arsenic n-pentyl phenyl arsenic i-pentyl i-pentyl arsenic i-pentyl t-pentyl arsenic i-pentyl neopentyl arsenic i-pentyl cyclopentadienyl arsenic i-pentyl phenyl arsenic t-pentyl t-pentyl arsenic t-pentyl neopentyl arsenic t-pentyl cyclopentadienyl arsenic t-pentyl phenyl arsenic neopentyl neopentyl arsenic neopentyl cyclopentadienyl arsenic neopentyl phenyl arsenic cyclopentadienyl cyclopentadienyl arsenic cyclopentadienyl phenyl phosphorus hydride t-pentyl phosphorus hydride neopentyl phosphorus methyl s-butyl phosphorus methyl i-butyl phosphorus methyl t-butyl phosphorus methyl n-pentyl phosphorus methyl i-pentyl phosphorus methyl t-pentyl phosphorus methyl neopentyl phosphorus methyl cyclopentadienyl phosphorus ethyl n-propyl phosphorus ethyl i-propyl phosphorus ethyl n-butyl phosphorus ethyl s-butyl phosphorus ethyl i-butyl phosphorus ethyl t-butyl phosphorus ethyl n-pentyl phosphorus ethyl i-pentyl phosphorus ethyl t-pentyl phosphorus ethyl neopentyl phosphorus ethyl cyclopentadienyl phosphorus n-propyl i-propyl phosphorus n-propyl n-butyl phosphorus n-propyl s-butyl phosphorus n-propyl i-butyl phosphorus n-propyl t-butyl phosphorus n-propyl n-pentyl phosphorus n-propyl i-pentyl phosphorus n-propyl t-pentyl phosphorus n-propyl neopentyl phosphorus n-propyl cyclopentadienyl phosphorus n-propyl phenyl phosphorus i-propyl n-butyl phosphorus i-propyl s-butyl phosphorus i-propyl t-butyl phosphorus i-propyl n-pentyl phosphorus i-propyl i-pentyl phosphorus i-propyl t-pentyl phosphorus i-propyl neopentyl phosphorus i-propyl cyclopentadienyl phosphorus i-propyl phenyl phosphorus n-butyl s-butyl phosphorus n-butyl i-butyl phosphorus n-butyl t-butyl phosphorus n-butyl n-pentyl phosphorus n-butyl i-pentyl phosphorus n-butyl t-pentyl phosphorus n-butyl neopentyl phosphorus n-butyl cyclopentadienyl phosphorus s-butyl i-butyl phosphorus s-butyl t-butyl phosphorus s-butyl n-pentyl phosphorus s-butyl i-pentyl phosphorus s-butyl t-pentyl phosphorus s-butyl neopentyl phosphorus s-butyl cyclopentadienyl phosphorus s-butyl phenyl phosphorus i-butyl t-butyl phosphorus i-butyl n-pentyl phosphorus i-butyl i-pentyl phosphorus i-butyl t-pentyl phosphorus i-butyl neopentyl phosphorus i-butyl cyclopentadienyl phosphorus i-butyl phenyl phosphorus t-butyl n-pentyl phosphorus t-butyl t-pentyl phosphorus t-butyl neopentyl phosphorus t-butyl cyclopentadienyl phosphorus n-pentyl n-pentyl phosphorus n-pentyl i-pentyl phosphorus n-pentyl t-pentyl phosphorus n-pentyl neopentyl phosphorus n-pentyl cyclopentadienyl phosphorus n-pentyl phenyl phosphorus i-pentyl t-pentyl phosphorus i-pentyl neopentyl phosphorus i-pentyl cyclopentadienyl phosphorus i-pentyl phenyl phosphorus t-pentyl t-pentyl phosphorus t-pentyl neopentyl phosphorus t-pentyl cyclopentadienyl phosphorus t-pentyl phenyl phosphorus neopentyl neopentyl phosphorus neopentyl cyclopentadienyl phosphorus neopentyl phenyl phosphorus cyclopentadienyl cyclopentadienyl ______________________________________
Claim 2
Dependent Claim 597 words
A compound having the structure: ##STR7## wherein H is hydride and the respective identities of N, X, and Y are selected from the following table of species: ______________________________________ N X Y ______________________________________ arsenic hydride s-butyl arsenic hydride i-butyl arsenic hydride n-pentyl arsenic hydride i-pentyl arsenic hydride t-pentyl arsenic hydride neopentyl arsenic hydride cyclopentadienyl arsenic methyl i-propyl arsenic methyl n-butyl arsenic methyl s-butyl arsenic methyl i-butyl arsenic methyl t-butyl arsenic methyl n-pentyl arsenic methyl i-pentyl arsenic methyl t-pentyl arsenic methyl neopentyl arsenic methyl cyclopentadienyl arsenic ethyl n-propyl arsenic ethyl i-propyl arsenic ethyl n-butyl arsenic ethyl s-butyl arsenic ethyl i-butyl arsenic ethyl t-butyl arsenic ethyl n-pentyl arsenic ethyl i-pentyl arsenic ethyl t-pentyl arsenic ethyl neopentyl arsenic ethyl cyclopentadienyl arsenic ethyl phenyl arsenic n-propyl i-propyl arsenic n-propyl n-butyl arsenic n-propyl s-butyl arsenic n-propyl i-butyl arsenic n-propyl t-butyl arsenic n-propyl n-pentyl arsenic n-propyl i-pentyl arsenic n-propyl t-pentyl arsenic n-propyl neopentyl arsenic n-propyl cyclopentadienyl arsenic n-propyl phenyl arsenic i-propyl n-butyl arsenic i-propyl s-butyl arsenic i-propyl i-butyl arsenic i-propyl t-butyl arsenic i-propyl n-pentyl arsenic i-propyl i-pentyl arsenic i-propyl t-pentyl arsenic i-propyl neopentyl arsenic i-propyl cyclopentadienyl arsenic i-propyl phenyl arsenic n-butyl s-butyl arsenic n-butyl i-butyl arsenic n-butyl t-butyl arsenic n-butyl n-pentyl arsenic n-butyl i-pentyl arsenic n-butyl t-pentyl arsenic n-butyl neopentyl arsenic n-butyl cyclopentadienyl arsenic n-butyl phenyl arsenic s-butyl s-butyl arsenic s-butyl i-butyl arsenic s-butyl t-butyl arsenic s-butyl n-pentyl arsenic s-butyl i-pentyl arsenic s-butyl t-pentyl arsenic s-butyl neopentyl arsenic s-butyl cyclopentadienyl arsenic s-butyl phenyl arsenic i-butyl i-butyl arsenic i-butyl t-butyl arsenic i-butyl n-pentyl arsenic i-butyl i-pentyl arsenic i-butyl t-pentyl arsenic i-butyl neopentyl arsenic i-butyl cyclopentadienyl arsenic i-butyl phenyl arsenic t-butyl n-pentyl arsenic t-butyl i-pentyl arsenic t-butyl t-pentyl arsenic t-butyl neopentyl arsenic t-butyl cyclopentadienyl arsenic t-butyl phenyl arsenic n-pentyl n-pentyl arsenic n-pentyl i-pentyl arsenic n-pentyl t-pentyl arsenic n-pentyl neopentyl arsenic n-pentyl cyclopentadienyl arsenic n-pentyl phenyl arsenic i-pentyl i-pentyl arsenic i-pentyl t-pentyl arsenic i-pentyl neopentyl arsenic i-pentyl cyclopentadienyl arsenic i-pentyl phenyl arsenic t-pentyl t-pentyl arsenic t-pentyl neopentyl arsenic t-pentyl cyclopentadienyl arsenic t-pentyl phenyl arsenic neopentyl neopentyl arsenic neopentyl cyclopentadienyl arsenic neopentyl phenyl arsenic cyclopentadienyl cyclopentadienyl arsenic cyclopentadienyl phenyl phosphorus hydride t-pentyl phosphorus hydride neopentyl phosphorus methyl s-butyl phosphorus methyl i-butyl phosphorus methyl t-butyl phosphorus methyl n-pentyl phosphorus methyl i-pentyl phosphorus methyl t-pentyl phosphorus methyl neopentyl phosphorus methyl cyclopentadienyl phosphorus ethyl n-propyl phosphorus ethyl i-propyl phosphorus ethyl n-butyl phosphorus ethyl s-butyl phosphorus ethyl i-butyl phosphorus ethyl t-butyl phosphorus ethyl n-pentyl phosphorus ethyl i-pentyl phosphorus ethyl t-pentyl phosphorus ethyl neopentyl phosphorus ethyl cyclopentadienyl phosphorus n-propyl i-propyl phosphorus n-propyl n-butyl phosphorus n-propyl s-butyl phosphorus n-propyl i-butyl phosphorus n-propyl t-butyl phosphorus n-propyl n-pentyl phosphorus n-propyl i-pentyl phosphorus n-propyl t-pentyl phosphorus n-propyl neopentyl phosphorus n-propyl cyclopentadienyl phosphorus n-propyl phenyl phosphorus i-propyl n-butyl phosphorus i-propyl s-butyl phosphorus i-propyl t-butyl phosphorus i-propyl n-pentyl phosphorus i-propyl i-pentyl phosphorus i-propyl t-pentyl phosphorus i-propyl neopentyl phosphorus i-propyl cyclopentadienyl phosphorus i-propyl phenyl phosphorus n-butyl s-butyl phosphorus n-butyl i-butyl phosphorus n-butyl t-butyl phosphorus n-butyl n-pentyl phosphorus n-butyl i-pentyl phosphorus n-butyl t-pentyl phosphorus n-butyl neopentyl phosphorus n-butyl cyclopentadienyl phosphorus s-butyl i-butyl phosphorus s-butyl t-butyl phosphorus s-butyl n-pentyl phosphorus s-butyl i-pentyl phosphorus s-butyl t-pentyl phosphorus s-butyl neopentyl phosphorus s-butyl cyclopentadienyl phosphorus s-butyl phenyl phosphorus i-butyl t-butyl phosphorus i-butyl n-pentyl phosphorus i-butyl i-pentyl phosphorus i-butyl t-pentyl phosphorus i-butyl neopentyl phosphorus i-butyl cyclopentadienyl phosphorus i-butyl phenyl phosphorus t-butyl n-pentyl phosphorus t-butyl t-pentyl phosphorus t-butyl neopentyl phosphorus t-butyl cyclopentadienyl phosphorus n-pentyl n-pentyl phosphorus n-pentyl i-pentyl phosphorus n-pentyl t-pentyl phosphorus n-pentyl neopentyl phosphorus n-pentyl cyclopentadienyl phosphorus n-pentyl phenyl phosphorus i-pentyl t-pentyl phosphorus i-pentyl neopentyl phosphorus i-pentyl cyclopentadienyl phosphorus i-pentyl phenyl phosphorus t-pentyl t-pentyl phosphorus t-pentyl neopentyl phosphorus t-pentyl cyclopentadienyl phosphorus t-pentyl phenyl phosphorus neopentyl neopentyl phosphorus neopentyl cyclopentadienyl phosphorus neopentyl phenyl phosphorus cyclopentadienyl cyclopentadienyl ______________________________________
Claim 3
Dependent Claim 19 words
The compound of claim 1, where N is arsenic, X is hydride, Y is selected from s-butyl and i-butyl.
Claim 4
Dependent Claim 15 words
The compound of claim 1, where N is arsenic, X is hydride, Y is pentyl.
Claim 5
Dependent Claim 15 words
The compound of claim 1, where N is arsenic, X is hydride, Y is cyclopentadienyl.
Claim 6
Dependent Claim 15 words
The compound of claim 1, where N is arsenic, X is methyl, Y is isopropyl.
Claim 7
Dependent Claim 15 words
The compound of claim 1, where N is arsenic, X is methyl, Y is butyl.
Claim 8
Dependent Claim 15 words
The compound of claim 1, where N is arsenic, X is methyl, Y is pentyl.
Claim 9
Dependent Claim 15 words
The compound of claim 1, where N is arsenic, X is methyl, Y is cyclopentadienyl.
Claim 10
Dependent Claim 15 words
The compound of claim 1, where N is arsenic, X is ethyl, Y is propyl.
Claim 11
Dependent Claim 15 words
The compound of claim 1, where N is arsenic, X is ethyl, Y is butyl.
Claim 12
Dependent Claim 15 words
The compound of claim 1, where N is arsenic, X is ethyl, Y is pentyl.
Claim 13
Dependent Claim 15 words
The compound of claim 1, where N is arsenic, X is ethyl, Y is cyclopentadienyl.
Claim 14
Dependent Claim 15 words
The compound of claim 1, where N is arsenic, X is ethyl, Y is phenyl.
Claim 15
Dependent Claim 15 words
The compound of claim 1, where N is arsenic, X is n-propyl, Y is isopropyl.
Claim 16
Dependent Claim 15 words
The compound of claim 1, where N is arsenic, X is propyl, Y is butyl.
Claim 17
Dependent Claim 15 words
The compound of claim 1, where N is arsenic, X is propyl, Y is pentyl.
Claim 18
Dependent Claim 15 words
The compound of claim 1, where N is arsenic, X is propyl, Y is cyclopentadienyl.
Claim 19
Dependent Claim 15 words
The compound of claim 1, where N is arsenic, X is propyl, Y is phenyl.
Claim 20
Dependent Claim 15 words
The compound of claim 1, where N is arsenic, X is butyl, Y is isobutyl.
Claim 21
Dependent Claim 15 words
The compound of claim 1, where N is arsenic, X is butyl, Y is sec-butyl.
Claim 22
Dependent Claim 15 words
The compound of claim 1, where N is arsenic, X is butyl, Y is pentyl.
Claim 23
Dependent Claim 15 words
The compound of claim 1, where N is arsenic, X is butyl, Y is cyclopentadienyl.
Claim 24
Dependent Claim 15 words
The compound of claim 1, where N is arsenic, X is butyl, Y is phenyl.
Claim 25
Dependent Claim 15 words
The compound of claim 1, where N is arsenic, X is pentyl, Y is pentyl.
Claim 26
Dependent Claim 15 words
The compound of claim 1, where N is arsenic, X is pentyl, Y is cyclopentadienyl.
Claim 27
Dependent Claim 15 words
The compound of claim 1, where N is arsenic, X is pentyl, Y is phenyl.
Claim 28
Dependent Claim 15 words
The compound of claim 1, where N is arsenic, X is cyclopentadienyl, Y is cyclopentadienyl.
Claim 29
Dependent Claim 15 words
The compound of claim 1, where N is arsenic, X is cyclopentadienyl, Y is phenyl.
Claim 30
Dependent Claim 20 words
The compound of claim 1, where N is phosphorus, X is methyl, Y is selected from s-butyl, i-butyl, and t-butyl.
Claim 31
Dependent Claim 15 words
The compound of claim 1, where N is phosphorus, X is methyl, Y is pentyl.
Claim 32
Dependent Claim 15 words
The compound of claim 1, where N is phosphorus, X is methyl, Y is cyclopentadienyl.
Claim 33
Dependent Claim 15 words
The compound of claim 1, where N is phosphorus, X is ethyl, Y is propyl.
Claim 34
Dependent Claim 15 words
The compound of claim 1, where N is phosphorus, X is ethyl, Y is butyl.
Claim 35
Dependent Claim 15 words
The compound of claim 1, where N is phosphorus, X is ethyl, Y is pentyl.
Claim 36
Dependent Claim 15 words
The compound of claim 1, where N is phosphorus, X is ethyl, Y is cyclopentadienyl.
Claim 37
Dependent Claim 15 words
The compound of claim 1, where N is phosphorus, X is propyl, Y is pentyl.
Claim 38
Dependent Claim 15 words
The compound of claim 1, where N is phosphorus, X is propyl, Y is cyclopentadienyl.
Claim 39
Dependent Claim 15 words
The compound of claim 1, where N is phosphorus, X is propyl, Y is phenyl.
Claim 40
Dependent Claim 15 words
The compound of claim 1, where N is phosphorus, X is butyl, Y is pentyl.
Claim 41
Dependent Claim 15 words
The compound of claim 1, where N is phosphorus, X is butyl, Y is cyclopentadienyl.
Claim 42
Dependent Claim 15 words
The compound of claim 1, where N is phosphorus, X is pentyl, Y is cyclopentadienyl.
Claim 43
Dependent Claim 15 words
The compound of claim 1, where N is phosphorus, X is pentyl, Y is phenyl.
Claim 44
Dependent Claim 15 words
The compound of claim 1, where N is phosporus, X is cyclopentadienyl, Y is cyclopentadienyl.

References Cited (Backward Citations)

US3657298A Cited

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