US4734459A
Expired / Lapsed
US
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Impact-resistant polypropylene compositions having improved whitening resistance
Assignee: Himont Inc
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Filing: 1986-09-15
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Granted: 1988-03-29
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Expires: 2006-09-15
Abstract
Abstract Disclosed are polypropylene compositions having high impact resistance at low temperatures, and improved whitening resistance. They comprise: (a) 60-90 parts by weight of polypropylene with an isotacticity index >90; and (b) 10-40 parts by weight of an ethylene/butene-1 polymeric mixture containing 50-95% by weight of polymerized ethylene, and consisting essentially of: 20-95% by weight of a crystalline fraction (I) with crystallinity of the polyethylene type, that is insoluble in xylene at 23° C.; and 5-80% by weight of an ethylene/butene-1 amorphous copolymeric fraction (II), that is soluble in xylene at 23° C., and contains 40-70% by weight of ethylene; and in which the weight ratio between total polymerized ethylene and the amorphous fraction (II) is 0.6-8. Such compositions are obtained by polymerization processes comprising the step of homopolymerizing propylene to stereoregular polymer, and a subsequent step of copolymerizing ethylene/butene-1 mixtures, said steps being effected by Ziegler-Natta stereospecific catalysts, which include a titanium compound carried on a magnesium halide in the active form.
Inventors
- 👤 Giuliano Cecchin
- 👤 Floriano Guglielmi
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 20:12
CPC Classifications
C; C08; C08F; C08F297/00; C08F297/06; C08F297/08; C08L; C08L23/00; C08L23/02; C08L23/10; C08L23/12; C08L23/04; C08L23/08; C08L23/0807; C08L23/0815; C08L2314/00; C08L2314/02
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
33 words
A polypropylene composition having high impact resistance at low temperatures, and improved whitening resistance, consisting essentially of 60-90 parts by weight of polypropylene, the isotacticity index of which is greater than 90, and
Claim 2
Dependent Claim
33 words
A polypropylene composition having high impact resistance at low temperatures, and improved whitening resistance, consisting essentially of 60-90 parts by weight of polypropylene, the isotacticity index of which is greater than 90, and
Claim 3
Dependent Claim
103 words
10-40 parts by weight of an ethylene-butene-1 polymeric mixture containing 50-95% by weight of polymerized ethylene, and consisting essentially of 20-95% weight of a crystalline fraction that has polyethylene-type crystallinity, and that is insoluble in xylene at room temperature, and 5-80% of an amorphous fraction that is soluble in xylene at 23° C., and that contains 40-70% by weight of polymerized ethylene. and in which mixture the weight ratio of total polymerized ethylene to the amorphous fraction is 0.6-8, said composition being obtained by the sequential polymerization of propylene to polypropylene and subsequently copolymerizing ethylene and butene-1 in the presence of said polypropylene.
Claim 4
Dependent Claim
103 words
10-40 parts by weight of an ethylene-butene-1 polymeric mixture containing 50-95% by weight of polymerized ethylene, and consisting essentially of 20-95% weight of a crystalline fraction that has polyethylene-type crystallinity, and that is insoluble in xylene at room temperature, and 5-80% of an amorphous fraction that is soluble in xylene at 23° C., and that contains 40-70% by weight of polymerized ethylene. and in which mixture the weight ratio of total polymerized ethylene to the amorphous fraction is 0.6-8, said composition being obtained by the sequential polymerization of propylene to polypropylene and subsequently copolymerizing ethylene and butene-1 in the presence of said polypropylene.
Claim 5
Dependent Claim
19 words
A polypropylene composition according to claim 1 in which the isotacticity index of said polypropylene is greater than 95.
Claim 6
Dependent Claim
136 words
A process for preparing a polypropylene composition having high impact resistance at low temperatures, and improved whitening resistance, comprising effecting sequentially the stereoregular homopolymerization of propylene to polypropylene, the isotacticity index of which is greater than 90, in an amount of 60-90 parts by weight of the final product, and in the presence of said polypropylene the copolymerization of ethylene and butene-1 to a polymeric mixture containing 50-95% by weight of polymerized ethylene and consisting of 20-95% by weight of a crystalline fraction that has polyethylene-type crystallinity and is insoluble in xylene at 23° C., and 5-80% by weight of an amorphous fraction that is soluble in xylene at 23° C. and contains 40-70% by weight of polymerized ethylene, and in which mixture the weight ratio of total polymerized ethylene to the amorphous fraction is 0.6-8.
Claim 7
Dependent Claim
136 words
A process for preparing a polypropylene composition having high impact resistance at low temperatures, and improved whitening resistance, comprising effecting sequentially the stereoregular homopolymerization of propylene to polypropylene, the isotacticity index of which is greater than 90, in an amount of 60-90 parts by weight of the final product, and in the presence of said polypropylene the copolymerization of ethylene and butene-1 to a polymeric mixture containing 50-95% by weight of polymerized ethylene and consisting of 20-95% by weight of a crystalline fraction that has polyethylene-type crystallinity and is insoluble in xylene at 23° C., and 5-80% by weight of an amorphous fraction that is soluble in xylene at 23° C. and contains 40-70% by weight of polymerized ethylene, and in which mixture the weight ratio of total polymerized ethylene to the amorphous fraction is 0.6-8.
Claim 8
Dependent Claim
70 words
A process according to claim 3 in which the polymerization is effected with a stereospecific coordination catalyst comprising a titanium compound carried on a magnesium halide in the active form having a surface area greater than 3 m 2/ g or in the X-ray spectrum of the magnesium halide the line of higher intensity appearing in the spectrum of a non-activated magnesium halide is broadened or replaced by a halo.
Claim 9
Dependent Claim
33 words
A process according to claim 4 in which the stereoregular homopolymerization of propylene is carried out in liquid propylene, and the copolymerization of ethylene and butene-1 is carried out in the gas phase.
References Cited (Backward Citations)
US3254139A
Cited
US3426105A
Cited
US3634552A
Cited
US3849520A
Cited
JPS54103478A
Cited
US4312964A
Cited
EP0010434A1
Cited
US4316966A
Cited
EP0052557A2
Cited
US4521566A
Cited
JPS5871910A
Cited
US4547552A
Cited
US4434264A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1991-03-29 | 1991-09-28 | 1992-03-29 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1995-03-29 | 1995-09-28 | 1996-03-29 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1999-03-29 | 1999-09-28 | 2000-03-29 | $7700.00 | Window Closed / Lapsed |