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US4734333A Expired / Lapsed US ⏱️ 0.0 years remaining

Postformable ultraviolet curable coatings

Assignee: Stamicarbon BV
•
Filing: 1986-12-08
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Granted: 1988-03-29
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Expires: 2006-12-08
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Abstract

Abstract A postformable ultraviolet curable primer coating composition is disclosed which consists essentially of: (A) from 10% to 80% of a linear acrylate-terminated polyurethane based on a polycarbonate diol; (B) from 2% to 35%, of acrylic acid; (C) from 15% to 65% of a monoethylenically unsaturated monomer having the rapid ultraviolet cure rate associated with acrylate monomers and having a glass transition temperature above 35 DEG C.,; (D) from 0% to 25% of a polyacrylate monomer; and (E) photoinitiator rendering the composition curable with ultraviolet light.

Inventors

  • 👤 A. Frank Leo
  • 👤 Clive J. Coady

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 21:29
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/40; C08G18/42; C08G18/44; C08F; C08F299/00; C08F299/02; C08F299/06; C08G18/67; C08G18/671; C08G18/672; Y; Y10; Y10T; Y10T428/00; Y10T428/13; Y10T428/1352; Y10T428/1355; Y10T428/31504; Y10T428/31551

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 125 words
A postformable ultraviolet curable highly adherent coating composition consisting essentially of: (A) from 15% to 30% of a linear acrylate-terminated polyurethane based on a polycarbonate diol, said polycarbonate diol having the formula: ##STR2## in which R is alkylene having from 2-20 carbon atoms; y is at least 1; and R and y are selected to provide a molecular weight for the polycarbonate diol reactant of from 300 to 3000; (B) from 10% to 20% of acrylic acid; (C) from 30% to 60% of a monoethylenically unsaturated monomer having the rapid ultraviolet cure rate associated with acrylate monomers and having a glass transition temperature above 55° C.; (D) from 8% to 25% of a triacrylate monomer; and (E) photoinitiator rendering the composition curable with ultraviolet light.
Claim 2
Dependent Claim 125 words
A postformable ultraviolet curable highly adherent coating composition consisting essentially of: (A) from 15% to 30% of a linear acrylate-terminated polyurethane based on a polycarbonate diol, said polycarbonate diol having the formula: ##STR2## in which R is alkylene having from 2-20 carbon atoms; y is at least 1; and R and y are selected to provide a molecular weight for the polycarbonate diol reactant of from 300 to 3000; (B) from 10% to 20% of acrylic acid; (C) from 30% to 60% of a monoethylenically unsaturated monomer having the rapid ultraviolet cure rate associated with acrylate monomers and having a glass transition temperature above 55° C.; (D) from 8% to 25% of a triacrylate monomer; and (E) photoinitiator rendering the composition curable with ultraviolet light.
Claim 3
Dependent Claim 29 words
A coating composition as recited in claim 1 in which R has 2-8 carbon atoms and the molecular weight of the polycarbonate diol reactant is from 600 to 1500.
Claim 4
Dependent Claim 26 words
A coating composition as recited in claim 1 in which said monoethylenically unsaturated monomer is selected from the group consisting of isobornyl acrylate and dicyclopentenyl acrylate.
Claim 5
Dependent Claim 22 words
A prime-coated galvanized steel product comprising a galvanized steel product prime coated with an ultraviolet-cured coating of the composition of claim 1.
Claim 6
Dependent Claim 22 words
A coated galvanized steel product comprising a galvanized steel product prime coated with an ultraviolet-cured coating of the composition of claim 1.
Claim 7
Dependent Claim 27 words
A coated product as recited in claim 5 in which said galvanized steel product is a tube which is formed after said coating has been cured thereon.

References Cited (Backward Citations)

US3559280A Cited
US4210713A Cited
US4303696A Cited
US4205018A Cited
EP0007265A1 Cited
US4264752A Cited
US4514037A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-03-29 1991-09-28 1992-03-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-03-29 1995-09-28 1996-03-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-03-29 1999-09-28 2000-03-29 $7700.00 Window Closed / Lapsed

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