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US4734296A Expired / Lapsed US ⏱️ 0.0 years remaining

Electroless plating of through-holes using pressure differential

Assignee: MC GEAN-ROHCO Inc
•
Filing: 1986-08-18
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Granted: 1988-03-29
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Expires: 2006-08-18
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Abstract

Abstract An apparatus and method for the electroless plating of articles. A tank is provided for sequentially containing the respective constituent baths corresponding to the steps of the electroless plating process. An article to be plated, such as a printed circuit board, is supported in the center of the tank immersed in the constituent bath container therein. A pair of inwardly facing parallel manifolds are disposed at opposite ends of the tank. The constituent solution is pumped through a nozzle matrix in the inward facing wall of a first manifold onto the article and is simultaneously sucked away from the opposing side of the article through the matrix of the nozzles defined in the inward facing wall of a second manifold. The direction of pumping is alternated for periodically reversing the direction of suction and impingement. The alternating pressure difference created across the surface of the article being plated substantially improves the rate of metal deposition over prior art systems and allows for a uniform and high quality plate over the entire surface of the article. Additionally, through-holes defined in the articles are thoroughly and uniformly deposited with electroless metal.

Inventors

  • 👤 Charles H. Schramm

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 12:32
CPC Classifications
H; H05; H05K; H05K3/00; H05K3/0085; H05K3/0088; C; C23; C23C; C23C18/00; C23C18/16; C23C18/1601; C23C18/1617; C23C18/1619; C23C18/1633; C23C18/1635; C23C18/1644; C23C18/1655; C23C18/1664; C23C18/1669; C23C18/1675; C23C18/18; C23C18/20; C23C18/2006; C23C18/2046; C23C18/2073; C23C18/208; C23C18/2086; C23C18/28; C23C18/285; C23C18/30; H05K2203/00; H05K2203/08; H05K2203/082

Claims Analysis

Total Claims: 40
Claim 1
Independent Claim 136 words
A process for electrolessly plating flat articles having apertures defined therethrough comprising the steps of: (a) treating the surface of the article to be plated by immersing said article into a solution containing a stannous salt; (b) catalyzing said article by immersing it in solution for providing catalytic nucleating centers on the surface thereof; (c) treating the catalyzed surface of said article by immersing it in an electroless solution including a salt of the metal and a reducing agent; (d) creating a pressure difference within said electroless solution such that said solution impinges against a first surface of said article and is sucked away from the opposing surface of said article; and whereby said electroless solution flows through said apertures for providing intimate contact and exposure of the walls of said apertures to said electroless solution.
Claim 2
Dependent Claim 136 words
A process for electrolessly plating flat articles having apertures defined therethrough comprising the steps of: (a) treating the surface of the article to be plated by immersing said article into a solution containing a stannous salt; (b) catalyzing said article by immersing it in solution for providing catalytic nucleating centers on the surface thereof; (c) treating the catalyzed surface of said article by immersing it in an electroless solution including a salt of the metal and a reducing agent; (d) creating a pressure difference within said electroless solution such that said solution impinges against a first surface of said article and is sucked away from the opposing surface of said article; and whereby said electroless solution flows through said apertures for providing intimate contact and exposure of the walls of said apertures to said electroless solution.
Claim 3
Dependent Claim 60 words
The process as claimed in claim 1 further comprising the step of periodically reversing the direction of said pressure difference within said solution after step (d) such that said impingement and suction of said bath alternately operates on said first surface and said opposing surface of said article, and whereby said flow of solution through said apertures periodically reverses direction.
Claim 4
Dependent Claim 26 words
The process as claimed in claim 1 further comprising the step of creating a pressure difference within said solution containing said stannous salt after step (a).
Claim 5
Dependent Claim 57 words
The process as claimed in claim 3 further comprising the step of periodically reversing the direction of said pressure difference within said solution such that said impingement and suction of said bath alternately operates on said first surface and said opposing surface of said article and whereby said flow of solution through said apertures correspondingly reverses direction.
Claim 6
Dependent Claim 22 words
The process as claimed in claim 1 further comprising the step of creating a pressure difference within said solution after step (b).
Claim 7
Dependent Claim 57 words
The process as claimed in claim 5 further comprising the step of periodically reversing the direction of said pressure difference within said solution such that said impingement and suction of said bath alternately operates on said first surface and said opposing surface of said article and whereby said flow of solution through said apertures correspondingly reverses direction.
Claim 8
Dependent Claim 137 words
A process for electrolessly plating articles comprising the steps of: (a) treating the article to be plated in a bath of hydrochloric acid; (b) activating the article by immersing it in a colloidal catalytic solution of stannous chloride and palladium chloride; (c) immersing the article in an accelerator bath of an organic material having a high molecular weight; (d) immersing the article in water; (e) immersing the article in an electroless solution that includes a water soluble metal salt, a complexing agent and a reducing agent for chemically depositing a desired metal and the surface of said article; (f) creating a pressure difference within said electroless solution such that said solution is directed in at least one impinging stream against a first surface of said article and is sucked away from the opposing surface of said article.
Claim 9
Dependent Claim 137 words
A process for electrolessly plating articles comprising the steps of: (a) treating the article to be plated in a bath of hydrochloric acid; (b) activating the article by immersing it in a colloidal catalytic solution of stannous chloride and palladium chloride; (c) immersing the article in an accelerator bath of an organic material having a high molecular weight; (d) immersing the article in water; (e) immersing the article in an electroless solution that includes a water soluble metal salt, a complexing agent and a reducing agent for chemically depositing a desired metal and the surface of said article; (f) creating a pressure difference within said electroless solution such that said solution is directed in at least one impinging stream against a first surface of said article and is sucked away from the opposing surface of said article.
Claim 10
Dependent Claim 46 words
The process according to claim 7 further comprising the step of creating a pressure difference within said colloidal catalytic solution after step (b) such that said solution impinges against a first surface of said article and is sucked away from the opposing surface of said article.
Claim 11
Dependent Claim 45 words
The process according to claim 7 further comprising the step of creating a pressure difference within said accelerator bath after step (c) such that said solution impinges against a first surface of said article and is sucked away from the opposing surface of said article.
Claim 12
Dependent Claim 59 words
The process according to claim 7 further comprising the steps of: immersing the article in water after step (a), and creating a pressure difference within said water such that said solution impinges against a first surface of said article and is sucked away from the opposing surface of said article, thereby removing the excess hydrochloric acid from said article.
Claim 13
Dependent Claim 50 words
The process according to claim 7 further comprising the steps of immersing the article in water after step (b) and creating a pressure difference within said water such that said water impinges against a first surface of said article and is sucked away from the opposing surface of said article.
Claim 14
Independent Claim 116 words
A method for treating an article with an electroless plating solution comprising: (a) at least partially immersing the article in the solution; and (b) creating a pressure difference within the solution, wherein the solution impinges onto a first surface of the article and is sucked away from a second surface of the article opposite the first surface, wherein the step of creating the pressure difference comprises: (i) from a first preselected distance away from the first surface, directing the solution toward the first surface; and (ii) at a second preselected distance away from the second surface, sucking the solution away from the second surface, whereby the first and second surfaces are thoroughly subjected to the solution.
Claim 15
Independent Claim 116 words
A method for treating an article with an electroless plating solution comprising: (a) at least partially immersing the article in the solution; and (b) creating a pressure difference within the solution, wherein the solution impinges onto a first surface of the article and is sucked away from a second surface of the article opposite the first surface, wherein the step of creating the pressure difference comprises: (i) from a first preselected distance away from the first surface, directing the solution toward the first surface; and (ii) at a second preselected distance away from the second surface, sucking the solution away from the second surface, whereby the first and second surfaces are thoroughly subjected to the solution.
Claim 16
Dependent Claim 51 words
The method as claimed in claim 12 further comprising: periodically reversing the direction of said pressure difference within said solution such that said impingement and suction of said solution alternately operate on said first surface and said opposing second surface of said article, whereby said flow of solution correspondingly reverses direction.
Claim 17
Dependent Claim 18 words
The method as claimed in claim 13 further comprising the step of introducing a gas into said solution.
Claim 18
Dependent Claim 20 words
The method as claimed in claim 14 wherein the step of introducing a gas comprises injecting air into said solution.
Claim 19
Dependent Claim 17 words
The method as claimed in claim 13 further comprising the step of removing particulates from said solution.
Claim 20
Dependent Claim 20 words
The method as claimed in claim 13 wherein the step of removing particulates comprises pumping the fluid through a filter.
Claim 21
Dependent Claim 18 words
The method as claimed in claim 13 further comprising the step of supporting the article in the solution.
Claim 22
Dependent Claim 29 words
The method as claimed in claim 18 wherein the step of supporting the article comprises positioning the article in a bracket which can be slidably translated along a track.
Claim 23
Dependent Claim 26 words
The method as claimed in claim 13 further comprising the step of oscillating said article substantially perpendicularly to the line of force of said pressure difference.
Claim 24
Dependent Claim 24 words
The method as claimed in claim 20 wherein the step of oscillating said article comprises moving a bracket back and forth along a track.
Claim 25
Dependent Claim 58 words
The method as claimed in claim 12 wherein the article contains apertures defined therethrough, such that the solution impinges onto the first surface of the article and is sucked away from the second surface of the article opposite the first surface and such that said solution flows through said apertures defined through said article and thoroughly treats them.
Claim 26
Independent Claim 117 words
A method for treating an article using a solution, by electroless plating, comprising: (a) at least partially immersing the article in the solution; and (b) creating a pressure difference within the solution, wherein the solution impinges onto a first surface of the article and is sucked away from a second surface of the article opposite the first surface, wherein the step of creating the pressure difference comprises: (i) from a first preselected distance away from the first surface, directing the solution toward the first surface; and (ii) at a second preselected distance away from the second surface, sucking the solution away from the second surface, whereby the first and second surfaces are thoroughly subjected to the solution.
Claim 27
Independent Claim 117 words
A method for treating an article using a solution, by electroless plating, comprising: (a) at least partially immersing the article in the solution; and (b) creating a pressure difference within the solution, wherein the solution impinges onto a first surface of the article and is sucked away from a second surface of the article opposite the first surface, wherein the step of creating the pressure difference comprises: (i) from a first preselected distance away from the first surface, directing the solution toward the first surface; and (ii) at a second preselected distance away from the second surface, sucking the solution away from the second surface, whereby the first and second surfaces are thoroughly subjected to the solution.
Claim 28
Independent Claim 212 words
A method for treating an article having apertures defined therethrough with an electroless plating solution comprising: (a) at least partially immersing the article in the solution; (b) supporting the article such that first and second planar surfaces of said article are substantially parallel to and between a pair of first and second facingly disposed manifolds, whereby each manifold has a matrix of closely spaced holes defined through the inward facing surface thereof, and whereby the first and second manifolds, respectively, are a preselected distance away from the first and second planar surfaces of said article; and (c) creating a pressure difference within said solution, wherein the solution impinges onto the first surface of the article and is sucked away from the second surface of the article opposite the first surface, wherein the step of creating the pressure difference comprises: (i) directing the solution through the matrix of holes of said first manifold such that the solution impinges against the first surface of said article; and (ii) sucking the solution through said apertures defined through said article such that the solution is sucked away from the second surface of said article and toward the second manifold, whereby the first and second surfaces and apertures of said article are thoroughly subjected to the solution.
Claim 29
Independent Claim 212 words
A method for treating an article having apertures defined therethrough with an electroless plating solution comprising: (a) at least partially immersing the article in the solution; (b) supporting the article such that first and second planar surfaces of said article are substantially parallel to and between a pair of first and second facingly disposed manifolds, whereby each manifold has a matrix of closely spaced holes defined through the inward facing surface thereof, and whereby the first and second manifolds, respectively, are a preselected distance away from the first and second planar surfaces of said article; and (c) creating a pressure difference within said solution, wherein the solution impinges onto the first surface of the article and is sucked away from the second surface of the article opposite the first surface, wherein the step of creating the pressure difference comprises: (i) directing the solution through the matrix of holes of said first manifold such that the solution impinges against the first surface of said article; and (ii) sucking the solution through said apertures defined through said article such that the solution is sucked away from the second surface of said article and toward the second manifold, whereby the first and second surfaces and apertures of said article are thoroughly subjected to the solution.
Claim 30
Dependent Claim 51 words
The method as claimed in claim 24 further comprising: periodically reversing the direction of said pressure difference within said solution such that said impingement and suction of said solution alternately operate on said first surface and said opposing second surface of said article, whereby said flow of solution correspondingly reverses direction.
Claim 31
Dependent Claim 18 words
The method as claimed in claim 25 further comprising the step of introducing a gas into said solution.
Claim 32
Dependent Claim 20 words
The method as claimed in claim 26 wherein the step of introducing a gas comprises injecting air into said solution.
Claim 33
Dependent Claim 17 words
The method as claimed in claim 25 further comprising the step of removing particulates from said solution.
Claim 34
Dependent Claim 20 words
The method as claimed in claim 28 wherein the step of removing particulates comprises pumping the fluid through a filter.
Claim 35
Dependent Claim 29 words
The method as claimed in claim 28 wherein the step of supporting the article comprises positioning the article in a bracket which can be slidably translated along a track.
Claim 36
Dependent Claim 26 words
The method as claimed in claim 25 further comprising the step of oscillating said article substantially perpendicularly to the line of force of said pressure difference.
Claim 37
Dependent Claim 24 words
The method as claimed in claim 31 wherein the step of oscillating said article comprises moving a bracket back and forth along a track.
Claim 38
Dependent Claim 21 words
The method as claimed in claim 24 wherein the method for treating an article comprises treating the article by electroless plating.
Claim 39
Independent Claim 337 words
A method for treating a substantially planar article having apertures defined therethrough with an electroless plating solution comprising: (a) at least partially immersing the article in the solution; (b) supporting the article such that first and second planar surfaces of said article are substantially parallel to and between a pair of first and second facingly disposed manifolds, whereby each manifold has a matrix of closely spaced holes defined through the inward facing surface thereof, and whereby first and second manifolds, respectively, are a preselected distance away from the first and second planar surfaces of said article; (c) creating a pressure difference within said solution, wherein the solution impinges onto the first surface of the article and is sucked away from the second surface of the article opposite the first surface, wherein the step of creating the pressure difference comprises: (i) directing the solution through the matrix of holes of said first manifold such that the solution impinges against the first surface of said article; (ii) sucking the solution through said apertures defined through said article such that the solution is sucked away from the second surface of said article and toward the second manifold, whereby the first and second surfaces and apertures of said article are thoroughly subjected to the solution; (d) periodically reversing the direction of said pressure difference within said solution such that said impingement and suction of said solution alternately operate on said first surface and said opposing second surface of said article, whereby said flow of solution correspondingly reverses direction; (e) injecting air into said solution; (f) pumping said solution between said first manifold and said second manifold by means of a pair of oppositely directed centrifugal pumps each independently interconnecting said first manifold and said second manifold; (g) pumping said solution through a filter such that particulates are removed from said solution; and (h) directing a bracket supporting said article back and forth along a track, whereby the article is oscillated substantially perpendicularly to the line of force of said pressure difference.
Claim 40
Independent Claim 337 words
A method for treating a substantially planar article having apertures defined therethrough with an electroless plating solution comprising: (a) at least partially immersing the article in the solution; (b) supporting the article such that first and second planar surfaces of said article are substantially parallel to and between a pair of first and second facingly disposed manifolds, whereby each manifold has a matrix of closely spaced holes defined through the inward facing surface thereof, and whereby first and second manifolds, respectively, are a preselected distance away from the first and second planar surfaces of said article; (c) creating a pressure difference within said solution, wherein the solution impinges onto the first surface of the article and is sucked away from the second surface of the article opposite the first surface, wherein the step of creating the pressure difference comprises: (i) directing the solution through the matrix of holes of said first manifold such that the solution impinges against the first surface of said article; (ii) sucking the solution through said apertures defined through said article such that the solution is sucked away from the second surface of said article and toward the second manifold, whereby the first and second surfaces and apertures of said article are thoroughly subjected to the solution; (d) periodically reversing the direction of said pressure difference within said solution such that said impingement and suction of said solution alternately operate on said first surface and said opposing second surface of said article, whereby said flow of solution correspondingly reverses direction; (e) injecting air into said solution; (f) pumping said solution between said first manifold and said second manifold by means of a pair of oppositely directed centrifugal pumps each independently interconnecting said first manifold and said second manifold; (g) pumping said solution through a filter such that particulates are removed from said solution; and (h) directing a bracket supporting said article back and forth along a track, whereby the article is oscillated substantially perpendicularly to the line of force of said pressure difference.

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-03-29 1991-09-28 1992-03-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-03-29 1995-09-28 1996-03-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-03-29 1999-09-28 2000-03-29 $7700.00 Window Closed / Lapsed

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