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US4731347A Expired / Lapsed US ⏱️ 0.0 years remaining

Glass frit composition

Assignee: Solar Turbines Inc
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Filing: 1986-03-21
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Granted: 1988-03-15
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Expires: 2006-03-21
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Abstract

Abstract A glass frit comprising about 60% by weight of glass formers, 30% by weight of monovalent fluxes and 10% by weight of divalent fluxes; the glass formers consisting essentially of SiO 2 and B 2 O 3 ; the monovalent fluxes consisting essentially of Li 2 O, Na 2 O and K 2 O; the divalent fluxes being selected from the group consisting of CaO, SrO, BaO and PbO; and trace elements not exceeding 10% by weight. Preferably the glass frit has the following composition, in terms of oxides: ______________________________________ SiO 2 49% B 2 O 3 12% Li 2 O 3.6% Na 2 O 14.4% K 2 O 11.4% CaO 5% SrO 1.85% BaO 2.75% ______________________________________ The glass frit has a coefficient of thermal expansion of 7.2×10 -6 /° F. (13×10 -6 /° C.) over the range from room temperature to 600° F. (316° C.). It is useable to make a slip where it can be fired at temperatures around 950° F. (510° C.) and applied to a suitable substrate in accordance with existing practices to provide a high quality coating or a viscous damper. Suitable substrates include many nickel-base alloys and stainless steels.

Inventors

  • 👤 Alvin R. Stetson

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 16:38
CPC Classifications
C; C03; C03C; C03C8/00; C03C8/02

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 102 words
A glass frit having a firing temperature of less than about 1100° F. and a coefficient of thermal expansion approximating that of stainless steel and many nickel-base alloys comprising about 60% by weight of glass formers, 30% by weight of monovalent fluxes and 10% by weight of divalent fluxes; the glass formers consisting essentially of SiO 2 and B 2 O 3 ; the monovalent fluxes consisting essentially of Li 2 O, Na 2 O and K 2 O; the divalent fluxes being selected from the group consisting of CaO, SrO, and BaO; and additional trace elements not exceeding 10% by weight.
Claim 2
Dependent Claim 102 words
A glass frit having a firing temperature of less than about 1100° F. and a coefficient of thermal expansion approximating that of stainless steel and many nickel-base alloys comprising about 60% by weight of glass formers, 30% by weight of monovalent fluxes and 10% by weight of divalent fluxes; the glass formers consisting essentially of SiO 2 and B 2 O 3 ; the monovalent fluxes consisting essentially of Li 2 O, Na 2 O and K 2 O; the divalent fluxes being selected from the group consisting of CaO, SrO, and BaO; and additional trace elements not exceeding 10% by weight.
Claim 3
Dependent Claim 27 words
A glass frit as set forth in claim 1, wherein the amount of SiO 2 is about four times the amount of B 2 O 3 .
Claim 4
Dependent Claim 28 words
A glass frit as set forth in claim 1, wherein the ratio of the weights of the various monovalent fluxes to each other is not greater than 4:1.
Claim 5
Dependent Claim 42 words
A glass frit as set forth in claim 3, wherein on a molecular equivalent basis, the amount of Na 2 O is present in an amount about equal to the sum of the amounts of Li 2 O and K 2 O.
Claim 6
Dependent Claim 28 words
A glass frit as set forth in claim 3, wherein on a molecular equivalent basis, Li 2 O and K 2 O are present in approximately like amounts.
Claim 7
Dependent Claim 20 words
A glass frit as set forth in claim 1, wherein the divalent fluxes consist essentially of CaO, SrO and BaO.
Claim 8
Dependent Claim 72 words
A glass frit capable of being fired at less than 1100° F. and having the following composition, in terms of oxides: ______________________________________ Oxide Percent by weight ______________________________________ SiO.sub.2 44 to 54 B.sub.2 O.sub.3 10 to 14 Li.sub.2 O 3 to 4 Na.sub.2 O 13 to 16 K.sub.2 O 10 to 13 CaO 4 to 6 SrO 1 to 2 BaO 2 to 3 ______________________________________ and other elements not exceeding 10% by weight.
Claim 9
Dependent Claim 72 words
A glass frit capable of being fired at less than 1100° F. and having the following composition, in terms of oxides: ______________________________________ Oxide Percent by weight ______________________________________ SiO.sub.2 44 to 54 B.sub.2 O.sub.3 10 to 14 Li.sub.2 O 3 to 4 Na.sub.2 O 13 to 16 K.sub.2 O 10 to 13 CaO 4 to 6 SrO 1 to 2 BaO 2 to 3 ______________________________________ and other elements not exceeding 10% by weight.
Claim 10
Dependent Claim 39 words
A glass frit as set forth in claim 7, wherein the percent by weight is as follows: ______________________________________ SiO.sub.2 49% B.sub.2 O.sub.3 12% Li.sub.2 O 3.6% Na.sub.2 O 14.4% K.sub.2 O 11.4% CaO 5% SrO 1.85% BaO 2.75% ______________________________________

References Cited (Backward Citations)

US1693130A Cited
US2662020A Cited
US2753271A Cited
US2925351A Cited
US4361654A Cited
JPS60108345A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-03-15 1991-09-14 1992-03-15 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-03-15 1995-09-14 1996-03-15 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-03-15 1999-09-14 2000-03-15 $7700.00 Window Closed / Lapsed

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