US4731315A
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Electrophotographic photoreceptor containing a trisazo compound and a charge transport material
Assignee: Fujifilm Holdings Corp
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Filing: 1986-08-08
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Granted: 1988-03-15
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Expires: 2006-08-08
Abstract
Abstract An electrophotographic photoreceptor is disclosed, comprising a conductive support having provided thereon a light-sensitive layer, wherein said light-sensitive layer contains a specific trisazo compound as a charge generating material and at least one of specific charge transporting materials. The photoreceptor exhibits high sensitivity and durability.
Inventors
- 👤 Seiji Horie
- 👤 Naonori Makino
- 👤 Hideo Sato
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-09 16:23
CPC Classifications
G; G03; G03G; G03G5/00; G03G5/02; G03G5/04; G03G5/06; G03G5/0601; G03G5/0612; G03G5/0616; C; C09; C09B; C09B35/00; C09B35/378; G03G5/0614; G03G5/06142; G03G5/06144; G03G5/061443; G03G5/06147; G03G5/0622; G03G5/0624; G03G5/0627; G03G5/0629; G03G5/0631; G03G5/0633; G03G5/0635; G03G5/0638; G03G5/0644; G03G5/0661; G03G5/0664; G03G5/0666; G03G5/0668; G03G5/067; G03G5/0675; G03G5/0687; G03G5/0688
Claims Analysis
Total Claims: 18
Claim 1
Independent Claim
434 words
An electrophotographic photoreceptor comprising a conductive support having provided thereon a light-sensitive layer, wherein said light-sensitive layer contains as a charge generating material a trisazo compound represented by formula (I) ##STR64## wherein Cp represents a coupler residue; Z 1 represents ##STR65## --O--, --S--, or --Se--, wherein R 6 represents a hydrogen atom, a substituted or unsubstituted lower alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted alkoxycarbonyl group, a substituted or unsubstituted aryloxycarbonyl group, or a substituted or unsubstituted acyl group; and B 1 , B 2 , and B 3 each represents a hydrogen atom, a halogen atom, a substituted or unsubstituted lower alkyl group, a substituted or unsubstituted lower alkoxy group, a substituted or unsubstituted lower alkoxycarbonyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted aryloxy group, or a substituted or unsubstituted aryloxycarbonyl group; and contains as a charge transporting material at least one compound represented by one of formulae (II) to (VI) ##STR66## wherein R 7 , R 8 , R 14 , and R 15 each represents a substituted or unsubstituted alkyl group, a substituted or unsubstituted aralkyl group, or a substituted or unsubstituted aryl group; or R 7 and R 8 together form a heterocyclic ring, or R 14 and R 15 together form an N-containing heterocyclic ring; R 9 represents a hydrogen atom, a substituted or unsubstituted alkyl group, or a substituted or unsubstituted aryl group; B 1 and B 2 are the same as defined above; R 1 represents a substituted or unsubstituted alkyl group, or a substituted or unsubstituted phenyl group; R 10 and R 11 each represents a hydrogen atom, a halogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted aralkoxy group, or a substituted or unsubstituted amino group; R 16 , R 17 , R 18 , and R 19 each represents a hydrogen atom, a halogen atom, or an alkyl group; Ar represents a substituted or unsubstituted aryl group, or a substituted or unsubstituted heterocyclic group; Z 2 represents ##STR67## --O--, --S--, --Se--, or a substituted or unsubstituted methine group; Z 3 represents an atomic group forming a benzene ring or a naphthalene ring; n represents 0 or 1; and A represents a group of the formula ##STR68## wherein l and m represent 0 or an integer of from 1 to 6; n represents 0 or 1; and B 1 and B 2 are the same as defined above, or B 1 and B 2 together form a condensed polycyclic aromatic ring.
Claim 2
Dependent Claim
434 words
An electrophotographic photoreceptor comprising a conductive support having provided thereon a light-sensitive layer, wherein said light-sensitive layer contains as a charge generating material a trisazo compound represented by formula (I) ##STR64## wherein Cp represents a coupler residue; Z 1 represents ##STR65## --O--, --S--, or --Se--, wherein R 6 represents a hydrogen atom, a substituted or unsubstituted lower alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted alkoxycarbonyl group, a substituted or unsubstituted aryloxycarbonyl group, or a substituted or unsubstituted acyl group; and B 1 , B 2 , and B 3 each represents a hydrogen atom, a halogen atom, a substituted or unsubstituted lower alkyl group, a substituted or unsubstituted lower alkoxy group, a substituted or unsubstituted lower alkoxycarbonyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted aryloxy group, or a substituted or unsubstituted aryloxycarbonyl group; and contains as a charge transporting material at least one compound represented by one of formulae (II) to (VI) ##STR66## wherein R 7 , R 8 , R 14 , and R 15 each represents a substituted or unsubstituted alkyl group, a substituted or unsubstituted aralkyl group, or a substituted or unsubstituted aryl group; or R 7 and R 8 together form a heterocyclic ring, or R 14 and R 15 together form an N-containing heterocyclic ring; R 9 represents a hydrogen atom, a substituted or unsubstituted alkyl group, or a substituted or unsubstituted aryl group; B 1 and B 2 are the same as defined above; R 1 represents a substituted or unsubstituted alkyl group, or a substituted or unsubstituted phenyl group; R 10 and R 11 each represents a hydrogen atom, a halogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted aralkoxy group, or a substituted or unsubstituted amino group; R 16 , R 17 , R 18 , and R 19 each represents a hydrogen atom, a halogen atom, or an alkyl group; Ar represents a substituted or unsubstituted aryl group, or a substituted or unsubstituted heterocyclic group; Z 2 represents ##STR67## --O--, --S--, --Se--, or a substituted or unsubstituted methine group; Z 3 represents an atomic group forming a benzene ring or a naphthalene ring; n represents 0 or 1; and A represents a group of the formula ##STR68## wherein l and m represent 0 or an integer of from 1 to 6; n represents 0 or 1; and B 1 and B 2 are the same as defined above, or B 1 and B 2 together form a condensed polycyclic aromatic ring.
Claim 3
Dependent Claim
186 words
An electrophotographic photoreceptor as in claim 1, wherein Cp in formula (I) is selected from coupler residues represented by the formulae ##STR69## wherein X represents an atomic group forming a substituted or unsubstituted aromatic or heterocyclic ring which is condensed to the benzene ring; Y represents a hydrogen atom, --CONR 4 R 5 , --COOR 4 , --CONHNR 4 R 5 , --CONHN═CH--R 4 , or ##STR70## R 1 represents a substituted or unsubstituted alkyl group, or a substituted or unsubstituted phenyl group; R 2 represents a hydrogen atom, a lower alkyl group, a carbamoyl group, a carboxyl group, an alkoxycarbonyl group, an aryloxycarbonyl group, or a substituted or unsubstituted amino group; R 3 represents a substituted or unsubstituted alkyl group, a substituted or unsubstituted aromatic group, or a substituted or unsubstituted heterocyclic aromatic group; and R 4 and R 5 each represents a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aromatic group, or a substituted or unsubstituted heterocyclic aromatic group, or R 4 and R 5 in ##STR71## taken together with the adjacent nitrogen or carbon atom form a ring.
Claim 4
Dependent Claim
63 words
An electrophotographic photoreceptor as in claim 2, wherein Cp is represented by the formula ##STR72## wherein X represents an atomic group forming a benzene ring, a carbazole ring, or a dibenzofuran ring which is condensed to the benzene ring; and Y represents ##STR73## wherein one of R 4 and R 5 represents a hydrogen atom and the other represents a substituted phenyl group.
Claim 5
Dependent Claim
34 words
An electrophotographic photoreceptor as in claim 3, wherein said substituted phenyl group is a phenyl group substituted with a trifluoromethyl group or a phenyl group substituted with a trifluoromethyl group and a halogen atom.
Claim 6
Dependent Claim
44 words
An electrophotographic photoreceptor as in claim 1, wherein one of R 7 and R 8 in formulae (II) and (IV) represents a phenyl group, and the other represents a methyl group, an ethyl group, a benzyl group, a phenyl group, or a naphthyl group.
Claim 7
Dependent Claim
24 words
An electrophotographic photoreceptor as in claim 1, wherein Ar in formulae (I) and (II) represents a phenyl group substituted with a substituted amino group.
Claim 8
Dependent Claim
29 words
An electrophotographic photoreceptor as in claim 6, wherein said substituted phenyl group is a p-dimethylaminophenyl group, a p-diethylaminophenyl group, a p-diphenylaminophenyl group, a p-(N-methyl-N-phenyl)aminophenyl group, or a p-(N-ethyl-N-phenyl)aminophenyl group.
Claim 9
Dependent Claim
36 words
An electrophotographic photoreceptor as in claim 1, wherein the alkyl group as represented by R 16 , R 17 , R 18 , and R 19 in formula (VI) contains from 1 to 4 carbon atoms.
Claim 10
Dependent Claim
32 words
An electrophotographic photoreceptor as in claim 1, wherein said light-sensitive layer comprises a charge transporting medium comprising the charge transporting compound and a binder, said medium having dispersed therein the trisazo compound.
Claim 11
Dependent Claim
40 words
An electrophotographic photoreceptor as in claim 9, wherein the weight ratio of the trisazo compound to the binder is from 0.01/1 to 2/1, and the weight ratio of the charge transporting compound to the binder is from 0.1/1 to 2/1.
Claim 12
Dependent Claim
40 words
An electrophotographic photoreceptor as in claim 10, wherein the weight ratio of the trisazo compound to the binder is from 0.05/1 to 1/1, and the weight ratio of the charge transporting compound to the binder is from 0.3/1 to 1.3/1.
Claim 13
Dependent Claim
20 words
An electrophotographic photoreceptor as in claim 9, wherein said light-sensitive layer has a thickness of from 3 to 30 μm.
Claim 14
Dependent Claim
37 words
An electrophotographic photoreceptor as in claim 1, wherein said light-sensitive layer comprises a charge generating layer containing the trisazo compound as a main component and a charge transporting layer containing the charge transporting compound and a binder.
Claim 15
Dependent Claim
32 words
An electrophotographic photoreceptor as in claim 13, wherein said charge generating layer further contains a binder, and the weight ratio of the trisazo compound to said binder is from 0.1/1 to 50/1.
Claim 16
Dependent Claim
24 words
An electrophotographic photoreceptor as in claim 13, wherein the weight ratio of the charge transporting compound to the binder is from 0.1/1 to 10/1.
Claim 17
Dependent Claim
24 words
An electrophotographic photoreceptor as in claim 13, wherein the weight ratio of the charge transporting compound to the binder is from 0.2/1 to 2.0/1.
Claim 18
Dependent Claim
35 words
An electrophotographic photoreceptor as in claim 13, wherein said charge generating layer has a thickness of not more than 4 μm, and said charge transporting layer has a thickness of from 3 to 30 μm.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1991-03-15 | 1991-09-14 | 1992-03-15 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1995-03-15 | 1995-09-14 | 1996-03-15 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1999-03-15 | 1999-09-14 | 2000-03-15 | $7700.00 | Window Closed / Lapsed |