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US4728456A Expired / Lapsed US ⏱️ 0.0 years remaining

Aluminum surface cleaning agent

Assignee: Henkel Corp
•
Filing: 1985-10-30
•
Granted: 1988-03-01
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Expires: 2005-10-30
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Abstract

Abstract Chromium free cleaning compositions for cleaning aluminum and aluminum alloy surfaces comprising A. from 0.2-4 g/l ferric ion and B. sufficient sulfuric and/or nitric acid to produce a pH of 2 or less. The invention also relates to compositions containing from 0.001-0.5 g/l of fluoride ions.

Inventors

  • 👤 Katsuyoshi Yamasoe
  • 👤 Kiyotado Yasuhara
  • 👤 Satoshi Ikeda

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 16:29
CPC Classifications
C; C23; C23G; C23G1/00; C23G1/02; C23G1/12; C23G1/125

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 57 words
An aqueous chromium free cleaning composition for aluminum and aluminum alloy surfaces consisting of: A. from about 0.2 to about 4 g/l of ferric ions; B. a sufficient quantity of sulfuric and/or nitric acid to produce a pH of 2 or less for the composition; and C. from about 0.001 to about 0.5 g/l of fluoride ions.
Claim 2
Dependent Claim 57 words
An aqueous chromium free cleaning composition for aluminum and aluminum alloy surfaces consisting of: A. from about 0.2 to about 4 g/l of ferric ions; B. a sufficient quantity of sulfuric and/or nitric acid to produce a pH of 2 or less for the composition; and C. from about 0.001 to about 0.5 g/l of fluoride ions.
Claim 3
Dependent Claim 13 words
A composition in accordance with claim 1 wherein component B is sulfuric acid.
Claim 4
Dependent Claim 24 words
A composition in accordance with claim 1 wherein the pH of the composition is in the range of from about 0.6 to about 2.0.
Claim 5
Dependent Claim 15 words
A composition in accordance with claim 1 wherein the fluoride ion is the F.sup.⊖ ion.
Claim 6
Dependent Claim 16 words
A composition in accordance with claim 1 wherein the fluoride ion is a complex fluoride ion.
Claim 7
Dependent Claim 101 words
A process for cleaning aluminum and aluminum alloy surfaces comprising the steps of I. treating an aluminum or aluminum alloy surface at a temperature in the range of about 20 C. to about 80 C. with an aqueous chromium free cleaning solution consisting of: A. from about 0.2 to about 4 g/l of ferric ions; B. a sufficient quantity of sulfuric and/or nitric acid to produce a pH of 2 or less for the composition; and C. from about 0.001 to about 0.5 g/l of fluoride ions; and II. removing the aqueous cleaning solution from the aluminum or aluminum alloy surface.
Claim 8
Dependent Claim 101 words
A process for cleaning aluminum and aluminum alloy surfaces comprising the steps of I. treating an aluminum or aluminum alloy surface at a temperature in the range of about 20 C. to about 80 C. with an aqueous chromium free cleaning solution consisting of: A. from about 0.2 to about 4 g/l of ferric ions; B. a sufficient quantity of sulfuric and/or nitric acid to produce a pH of 2 or less for the composition; and C. from about 0.001 to about 0.5 g/l of fluoride ions; and II. removing the aqueous cleaning solution from the aluminum or aluminum alloy surface.
Claim 9
Dependent Claim 13 words
A process in accordance with claim 6 wherein component I.B. is sulfuric acid.
Claim 10
Dependent Claim 25 words
A process in accordance with claim 6 wherein the pH of the cleaning solution is in the range of from about 0.6 to about 2.0.
Claim 11
Dependent Claim 17 words
A process in accordance with claim 6 wherein in I.C. the fluoride ion is the F.sup.⊖ ion.
Claim 12
Dependent Claim 18 words
A process in accordance with claim 6 wherein in I.C. the fluoride ion is a complex fluoride ion.
Claim 13
Dependent Claim 55 words
A concentrated composition for dilution with water in accordance with the composition of claim 1 wherein the concentrated composition contains in excess of 4 g/l of ferric ions, and proportional quantities of sulfuric acid and/or nitric acid and fluoride ions so as to result in the composition of claim 5 upon said dilution with water.

References Cited (Backward Citations)

FR1565017A Cited
US3728188A Cited
FR2159488A1 Cited
GB1454974A Cited
US4032359A Cited
US4089736A Cited
US4100015A Cited
US4212701A Cited
US4339282A Cited
US4435223A Cited
US4425185A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-03-01 1991-08-31 1992-03-01 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-03-01 1995-08-31 1996-03-01 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-03-01 1999-08-31 2000-03-01 $7700.00 Window Closed / Lapsed

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