US4728345A
Expired / Lapsed
US
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Multicomponent gas separation membranes having polyphosphazene coatings
Assignee: Permea Inc
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Filing: 1983-12-28
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Granted: 1988-03-01
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Expires: 2003-12-28
Abstract
Abstract Multicomponent membranes for gas separation having polyphosphazene coatings in occluding contact with a porous separation membrane are disclosed which are effective for separating at least one gas from gaseous mixtures and which exhibit improved stability when exposed to aromatic and aliphatic hydrocarbons contained in the gaseous mixtures. In addition multicomponent membranes for gas separations having a polyphosphazene coating in occluding contact with a porous separation membrane of polar material are disclosed which exhibit relative preferential permeation of polar gases from mixtures containing polar and non-polar gases.
Inventors
- 👤 Milton K. Murphy
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 17:42
CPC Classifications
C; C09; C09D; C09D185/00; C09D185/02; B; B01; B01D; B01D71/00; B01D71/06; B01D71/72; C08; C08L; C08L85/00; C08L85/02
Claims Analysis
Total Claims: 15
Claim 1
Independent Claim
177 words
In a multicomponent membrane for gas separation comprising a coating in occluding contact with a porous separation membrane of material, which material exhibits selective permeation of at least one gas of a gaseous mixture over that of one or more remaining gases of a gaseous mixture, said porous separation membrane having a substantial void volume, wherein, with respect to one pair of gases, the material of the porous separation membrane exhibits a determined intrinsic separation factor greater than the determined intrinsic separation factor of the material of said coating, and the multicomponent membrane exhibits a separation factor significantly greater than the determined intrinsic separation factor of material of said coating and greater than the separation factor exhibited by the porous separation membrane; the improvement comprising a polyphosphazene coating material having the formula: ##STR6## where R and R' are the same or different organic substituents and n is an integer of two or more, said polyphosphazene coating material swells no more than about 25% by volume when exposed to aliphatic and aromatic hydrocarbons contained in said gaseous mixture.
Claim 2
Dependent Claim
177 words
In a multicomponent membrane for gas separation comprising a coating in occluding contact with a porous separation membrane of material, which material exhibits selective permeation of at least one gas of a gaseous mixture over that of one or more remaining gases of a gaseous mixture, said porous separation membrane having a substantial void volume, wherein, with respect to one pair of gases, the material of the porous separation membrane exhibits a determined intrinsic separation factor greater than the determined intrinsic separation factor of the material of said coating, and the multicomponent membrane exhibits a separation factor significantly greater than the determined intrinsic separation factor of material of said coating and greater than the separation factor exhibited by the porous separation membrane; the improvement comprising a polyphosphazene coating material having the formula: ##STR6## where R and R' are the same or different organic substituents and n is an integer of two or more, said polyphosphazene coating material swells no more than about 25% by volume when exposed to aliphatic and aromatic hydrocarbons contained in said gaseous mixture.
Claim 3
Dependent Claim
79 words
The improved multicomponent membrane for gas separation according to claim 1 wherein the coating material is comprised of polyphosphazenes having a repeating structural unit of the formula: ##STR7## where Y and Y' can be the same or different and are selected from oxygen, nitrogen or sulfur and R and R' can be the same or different and are selected from alkyl, aryl, substituted alkyl and substituted aryl with n being an integer of from about 100 to about 70,000.
Claim 4
Dependent Claim
19 words
The improved multicomponent membrane for gas separation according to claim 2 wherein the Y and Y' are both oxygen.
Claim 5
Dependent Claim
36 words
The improved multicomponent membrane for gas separation according to claim 3 wherein the polyphosphazene coating material swells no more than about 15% by volume when exposed to aliphatic and aromatic hydrocarbons contained in the gas mixture.
Claim 6
Dependent Claim
19 words
The improved multicomponent membrane for gas separation according to claim 3 wherein R and R' are substituted with halogens.
Claim 7
Dependent Claim
17 words
The improved multicomponent membrane according to claim 5 wherein the R and R' are substituted with fluorine.
Claim 8
Dependent Claim
74 words
The improved multicomponent membrane for gas separation according to claim 1 wherein with respect to at least one pair of gases consisting of one of hydrogen, helium, ammonia, carbon dioxide and hydrogen sulfide and one of carbon monoxide, nitrogen, argon, methane, ethane and propane, the multicomponent membrane exhibits a separation factor significantly greater than the determined intrinsic separation factor of the polyphosphazenes and greater than the separation factor exhibited by the porous separation membrane.
Claim 9
Dependent Claim
113 words
A multicomponent membrane for polar gas separations comprising a halogenated polyphosphazene coating in occluding contact with a porous separation membrane of polar material, said polar material exhibiting selective permeation for polar gases from gaseous mixtures, said polar porous separation membrane having a substantial void volume, wherein with respect to the polar gases of the porous separation membrane exhibits a determined intrinsic separation factor greater than the determined intrinsic separation factor of the halogenated polyphosphazene coating material, and the multicomponent membrane exhibits a separation factor significantly greater than the determined intrinsic separation factor of the polyphosphazene coating material and greater than the separation factor exhibited by the polar, porous separation membrane for polar gases.
Claim 10
Dependent Claim
113 words
A multicomponent membrane for polar gas separations comprising a halogenated polyphosphazene coating in occluding contact with a porous separation membrane of polar material, said polar material exhibiting selective permeation for polar gases from gaseous mixtures, said polar porous separation membrane having a substantial void volume, wherein with respect to the polar gases of the porous separation membrane exhibits a determined intrinsic separation factor greater than the determined intrinsic separation factor of the halogenated polyphosphazene coating material, and the multicomponent membrane exhibits a separation factor significantly greater than the determined intrinsic separation factor of the polyphosphazene coating material and greater than the separation factor exhibited by the polar, porous separation membrane for polar gases.
Claim 11
Dependent Claim
30 words
The multicomponent membrane for polar gas separations according to claim 8 wherein the porous separation membrane is contacted with a polar solvent prior to or during coating with the polyphosphazenes.
Claim 12
Dependent Claim
23 words
The multicomponent membrane for polar gas separations according to claim 8 wherein the material of the porous separation membrane is comprised of polyamides.
Claim 13
Dependent Claim
20 words
The multicomponent membrane according to claim 8 wherein the porous separation membrane is comprised of polar material which is crosslinked.
Claim 14
Dependent Claim
50 words
The multicomponent membrane for polar gas separations according to claim 8 wherein with respect to polar gases selected from carbon dioxide and hydrogen sulfide in a feed gas mixture with C 1 to C 3 hydrocarbon gases, the multicomponent membrane preferentially permeates the polar gases, carbon dioxide and hydrogen sulfide.
Claim 15
Dependent Claim
37 words
The multicomponent membrane for polar gas separations according to claim 8 wherein the polyphosphazene coating material swells no more than about 15% by volume when exposed to aliphatic and aromatic hydrocarbons contained in the feed gas mixture.
References Cited (Backward Citations)
US4214020A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1991-03-01 | 1991-08-31 | 1992-03-01 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1995-03-01 | 1995-08-31 | 1996-03-01 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1999-03-01 | 1999-08-31 | 2000-03-01 | $7700.00 | Window Closed / Lapsed |