Abstract The invention provides an efficient method for improving the adhesive bonding strength of various types of rubbery sealant compositions, e.g. room temperature curable silicone rubber composition, to the substrate surface on which it has been cured. The method comprises coating the substrate surface with or admixing the sealant composition before application to the substrate surface with an adhesion promotor which is a reaction product of a reaction mixture comprising: (a) 1 mole of an organic amine compound having at least one active hydrogen atom in a molecule or an aminoalkyl alkoxysilane compound; (b) from 0.5 to 4 moles of an organic compound having at least one epoxy group in a molecule or an epoxyalkyl alkoxysilane; and (c) from 0.5 to 12 moles of an alkoxysilane represented by the general formula R1aSi(OR2)4-a, in which R1 is a hydrogen atom or a monovalent hydrocarbon group having 1 to 4 carbon atoms, R2 is a monovalent hydrocarbon group having 1 to 4 carbon atoms or an alkoxy-substituted alkyl group and a is a number of zero, 1, 2 or 3, or a partial hydrolysis product thereof, at least one of the components (a) and (b) being an aminoalkyl alkoxysilane or an epoxyalkyl alkoxysilane, respectively.
An adhesion promotor for a rubbery sealant composition which is a reaction product of a reaction mixture comprising: (a) 1 mole of an organic amine compound having at least one active hydrogen atom in a molecule or an aminoalkyl alkoxysilane compound; (b) from 0.5 to 4 moles of an organic compound having at least one epoxy group in a molecule or an epoxyalkyl alkoxysilane compound; and (c) from 0.5 to 12 moles of an alkoxysilane represented by the general formula R 1 a Si(OR 2 ) 4-a , in which R 1 is a hydrogen atom or a monovalent hydrocarbon group having 1 to 4 carbon atoms, R 2 is a monovalent hydrocarbon group having 1 to 4 carbon atoms or an alkoxy-substituted alkyl group and a is a number of zero, 1, 2 or 3, or a partial hydrolysis product thereof, at least one of the components (a) and (b) being an aminoalkyl alkoxysilane or an epoxyalkyl alkoxysilane, respectively.
Claim 2
Dependent Claim
160 words
An adhesion promotor for a rubbery sealant composition which is a reaction product of a reaction mixture comprising: (a) 1 mole of an organic amine compound having at least one active hydrogen atom in a molecule or an aminoalkyl alkoxysilane compound; (b) from 0.5 to 4 moles of an organic compound having at least one epoxy group in a molecule or an epoxyalkyl alkoxysilane compound; and (c) from 0.5 to 12 moles of an alkoxysilane represented by the general formula R 1 a Si(OR 2 ) 4-a , in which R 1 is a hydrogen atom or a monovalent hydrocarbon group having 1 to 4 carbon atoms, R 2 is a monovalent hydrocarbon group having 1 to 4 carbon atoms or an alkoxy-substituted alkyl group and a is a number of zero, 1, 2 or 3, or a partial hydrolysis product thereof, at least one of the components (a) and (b) being an aminoalkyl alkoxysilane or an epoxyalkyl alkoxysilane, respectively.