US4724271A
Expired / Lapsed
US
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Regeneration of dehydrocyclodimerization catalyst
Assignee: Honeywell UOP LLC
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Filing: 1987-03-31
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Granted: 1988-02-09
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Expires: 2007-03-31
Abstract
Abstract A process for catalytic dehydrocyclodimerization and regeneration of the catalyst. C2 to C5 aliphatic hydrocarbons are reacted to produce aromatics, using a water-sensitive catalyst of a composition especially adapted to minimize deposition of coke on the catalyst. The catalyst is comprised of alumina which contains phosphorus, gallium, and a crystalline aluminosilicate having a silica to alumina ratio of at least 12. The use of this catalyst has resulted in a five-fold reduction in the rate of coke deposition, compared to a conventional dehydrocyclodimerization catalyst. However, the activity of this catalyst is significantly reduced by exposure to water at the temperatures normally used in removing the coke, which is accomplished by burning the coke in a combustion zone in the presence of oxygen, producing carbon dioxide and water. At least a portion of the gas leaving the combustion zone catalyst bed is combined with air and recycled back to the combustion zone. This mode of operation causes the concentration of water in the recycled stream to increase to an unacceptable value. Therefore, to obtain the benefit of this superior catalyst, it is necessary to utilize water removal steps in the catalyst regeneration procedure.
Inventors
- 👤 David C. Martindale
- 👤 Joseph A. Kocal
- 👤 Tai-Hsiang Chao
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 20:27
CPC Classifications
C; C07; C07C; C07C5/00; C07C5/22; C07C5/27; C07C5/2702; C07C5/2724; B; B01; B01J; B01J29/00; B01J29/04; B01J29/06; B01J29/40; B01J29/405; B01J29/90; C07C2/00; C07C2/76; B01J2229/00; B01J2229/10; B01J2229/26; B01J2229/30; B01J2229/36; B01J2229/42; B01J29/65; B01J29/70; C07C2521/00; C07C2521/02; C07C2521/04; C07C2523/00; C07C2523/08; C07C2527/00; C07C2527/14; C07C2529/00; C07C2529/04; C07C2529/06; C07C2529/40; Y; Y02; Y02P; Y02P20/00; Y02P20/50; Y02P20/584
Claims Analysis
Total Claims: 6
Claim 1
Independent Claim
170 words
A process for the dehydrocyclodimerization of hydrocarbons which comprises contacting a feed stream containing aliphatic hydrocarbons with a catalyst, under dehydrocyclodimerization conditions, where said catalyst is comprised of phosphorus-containing alumina, a gallium component, and a crystalline aluminosilicate having a silica to alumina ratio of at least 12, where said catalyst becomes deactivated as a result of the dehydrocyclodimerization reaction, and where water is excluded from contact with said catalyst during catalyst regeneration, the catalyst regeneration procedure being comprised of the steps of: (a) passing spent catalyst through a combustion zone which is maintained at a coke-oxidizing temperature, wherein said spent catalyst is contacted with a dry recycle gas comprising oxygen; (b) withdrawing a flue gas stream from the combustion zone; (c) mixing an air stream with said flue gas stream to form said recycle gas stream; (d) passing the recycle gas stream through a drying zone wherein water is removed from the recycle gas stream; and, (e) passing the dry recycle gas stream through the catalyst in the combustion zone.
Claim 2
Dependent Claim
170 words
A process for the dehydrocyclodimerization of hydrocarbons which comprises contacting a feed stream containing aliphatic hydrocarbons with a catalyst, under dehydrocyclodimerization conditions, where said catalyst is comprised of phosphorus-containing alumina, a gallium component, and a crystalline aluminosilicate having a silica to alumina ratio of at least 12, where said catalyst becomes deactivated as a result of the dehydrocyclodimerization reaction, and where water is excluded from contact with said catalyst during catalyst regeneration, the catalyst regeneration procedure being comprised of the steps of: (a) passing spent catalyst through a combustion zone which is maintained at a coke-oxidizing temperature, wherein said spent catalyst is contacted with a dry recycle gas comprising oxygen; (b) withdrawing a flue gas stream from the combustion zone; (c) mixing an air stream with said flue gas stream to form said recycle gas stream; (d) passing the recycle gas stream through a drying zone wherein water is removed from the recycle gas stream; and, (e) passing the dry recycle gas stream through the catalyst in the combustion zone.
Claim 3
Dependent Claim
268 words
A process for the dehydrocyclodimerization of hydrocarbons which comprises contacting a feed stream containing aliphatic hydrocarbons with a catalyst, under dehydrocyclodimerization conditions, where said catalyst is comprised of phosphorus-containing alumina, a gallium component, and a crystalline aluminosilicate having a silica to alumina ratio of at least 12, where said catalyst becomes deactivated as a result of the dehydrocyclodimerization reaction, and where water is excluded from contact with said catalyst during catalyst regeneration, the catalyst regeneration procedure being comprised of the steps of: (a) passing spent catalyst through a combustion zone which is maintained at a coke-oxidizing temperature, wherein said spent catalyst is contacted with a dry recycle gas comprising oxygen; (b) passing catalyst leaving said combustion zone through a catalyst drying zone wherein water is removed from the catalyst; (c) passing a first air stream through an air drying zone wherein water is removed from said first air stream and heating said first air stream; (d) passing at least a portion of said heated and dried first air stream through said catalyst drying zone in contact with catalyst, thereby removing water from the catalyst; (e) mixing at least a portion of the air stream leaving the catalyst drying zone with a gas stream leaving the catalyst bed in the combustion zone to form a flue gas stream; (f) mixing a second air stream with said flue gas stream to form said recycle gas stream; (g) passing the recycle gas stream through a drying zone wherein water is removed from the recycle gas stream; and, (h) passing the dry recycle gas stream through the catalyst in the combustion zone.
Claim 4
Dependent Claim
268 words
A process for the dehydrocyclodimerization of hydrocarbons which comprises contacting a feed stream containing aliphatic hydrocarbons with a catalyst, under dehydrocyclodimerization conditions, where said catalyst is comprised of phosphorus-containing alumina, a gallium component, and a crystalline aluminosilicate having a silica to alumina ratio of at least 12, where said catalyst becomes deactivated as a result of the dehydrocyclodimerization reaction, and where water is excluded from contact with said catalyst during catalyst regeneration, the catalyst regeneration procedure being comprised of the steps of: (a) passing spent catalyst through a combustion zone which is maintained at a coke-oxidizing temperature, wherein said spent catalyst is contacted with a dry recycle gas comprising oxygen; (b) passing catalyst leaving said combustion zone through a catalyst drying zone wherein water is removed from the catalyst; (c) passing a first air stream through an air drying zone wherein water is removed from said first air stream and heating said first air stream; (d) passing at least a portion of said heated and dried first air stream through said catalyst drying zone in contact with catalyst, thereby removing water from the catalyst; (e) mixing at least a portion of the air stream leaving the catalyst drying zone with a gas stream leaving the catalyst bed in the combustion zone to form a flue gas stream; (f) mixing a second air stream with said flue gas stream to form said recycle gas stream; (g) passing the recycle gas stream through a drying zone wherein water is removed from the recycle gas stream; and, (h) passing the dry recycle gas stream through the catalyst in the combustion zone.
Claim 5
Dependent Claim
17 words
The process of claim 2 wherein a portion of said flue gas stream is vented to atmosphere.
Claim 6
Dependent Claim
21 words
The process of claim 2 wherein said second air stream is a portion of said heated and dried first air stream.
References Cited (Backward Citations)
US3386801A
Cited
US3507778A
Cited
US4225419A
Cited
US4463209A
Cited
US4350835A
Cited
US4477582A
Cited
GB2117367A
Cited
US4642407A
Cited
US4567152A
Cited
US4600700A
Cited
US4590323A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1991-02-08 | 1991-08-10 | 1992-02-09 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1995-02-08 | 1995-08-10 | 1996-02-09 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1999-02-08 | 1999-08-10 | 2000-02-09 | $7700.00 | Window Closed / Lapsed |